AIEEE 2011 — 1 May Offline Set Q (Previous Year Paper)
JEE Main · 2011 · with answers and explanations
- questions
- 87
- Total marks
- 348
- Duration
- 180 minutes
- Negative marking
- −1
Subjects: Physics · Mathematics · Chemistry
Question 1
Physics · 4 marks · −1The transverse displacement y(x, t) of a wave on a string is given by . This represents a
- A.wave moving in direction with speed
- B.standing wave of frequency
- C.standing wave of frequency
- D.wave moving in direction with
Correct answer: A
Explanation: : travels along at .
Question 2
Physics · 4 marks · −1A screw gauge gives the following reading when used to measure the diameter of a wire. Main scale reading : 0 mm. Circular scale reading : 52 divisions. Given that 1 mm on main scale corresponds to 100 divisions of the circular scale. The diameter of wire from the above data is :
- A.0.052 cm
- B.0.026 cm
- C.0.005 cm
- D.0.52 cm
Correct answer: A
Explanation: LC 0.01 mm; mm cm.
Question 3
Physics · 4 marks · −1A mass m hangs with the help of a string wrapped around a pulley on a frictionless bearing. The pulley has mass m and radius R. Assuming pulley to be a perfect uniform circular disc, the acceleration of the mass m, if the string does not slip on the pulley, is
- A.g
- B.
- C.
- D.
Correct answer: B
Explanation: .
Question 4
Physics · 4 marks · −1Work done in increasing the size of a soap bubble from a radius of 3 cm to 5 cm is nearly (Surface tension of soap solution = 0.03 Nm):
- A. mJ
- B. mJ
- C. mJ
- D. mJ
Correct answer: C
Explanation: Two surfaces: mJ.
Question 5
Physics · 4 marks · −1A thin horizontal circular disc is rotating about a vertical axis passing through its centre. An insect is at rest at a point near the rim of the disc. The insect now moves along a diameter of the disc to reach its other end. During the journey of the insect, the angular speed of the disc:
- A.continuously decreases
- B.continuously increases
- C.first increases and then decreases
- D.remains unchanged
Correct answer: C
Explanation: Angular momentum is conserved; I first decreases (insect nears the axis) then increases.
Question 6
Physics · 4 marks · −1Two bodies of masses m and 4 m are placed at a distance r. The gravitational potential at a point on the line joining them where the gravitational field is zero is:
- A.
- B.
- C.
- D.zero
Correct answer: C
Explanation: Null point at from m: .
Question 7
Physics · 4 marks · −1Two identical charged spheres suspended from a common point by two massless strings of length l are initially a distance d apart because of their mutual repulsion. The charge begins to leak from both the spheres at a constant rate. As a result the charges approach each other with a velocity v. Then as a function of distance x between them,
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Equilibrium: . constant gives const, so .
Question 8
Physics · 4 marks · −1A boat is moving due east in a region where the earth's magnetic field is NAm due north and horizontal. The boat carries a vertical aerial 2m long. If the speed of the boat is 1.50 ms, the magnitude of the induced emf in the wire of aerial is :
- A.0.75 mV
- B.0.50 mV
- C.0.15 mV
- D.1 mV
Correct answer: C
Explanation: mV.
Question 9
Physics · 4 marks · −1An object, moving with a speed of 6.25 m/s, is decelerated at a rate given by : where v is the instantaneous speed. The time taken by the object, to come to rest, would be :
- A.2 s
- B.4 s
- C.8 s
- D.1 s
Correct answer: A
Explanation: s.
Question 10
Physics · 4 marks · −1A fully charged capacitor C with initial charge is connected to a coil of self inductance L at . The time at which the energy is stored equally between the electric and the magnetic field is :
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: first at .
Question 11
Physics · 4 marks · −1Let the x - z plane be the boundary between two transparent media. Medium 1 in has a refractive index of and medium 2 with has a refractive index of . A ray of light in medium 1 given by the vector is incident on the plane of separation. The angle of refraction in medium 2 is
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: The media are separated by (normal along z): , ; .
Question 12
Physics · 4 marks · −1A current I flows in an infinitely long wire with cross section in the form of a semicircular ring of radius R. The magnitude of the magnetic induction along its axis is
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Strips , each giving ; integrating the non-cancelling component: .
Question 13
Physics · 4 marks · −1A thermally insulated vessel contains an ideal gas of molecular mass M and ratio of specific heats . It is moving with speed v and is suddenly brought to rest. Assuming no heat is lost to the surroundings, its temperature increases by :
- A. K
- B. K
- C. K
- D. K
Correct answer: C
Explanation: per mole.
Question 14
Physics · 4 marks · −1A mass M, attached to a horizontal spring, executes S.H.M. with amplitude . When the mass M passes through its mean position then a smaller mass m is placed over it and both of them move together with amplitude . The ratio of is :
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Momentum conserved: with .
Question 15
Physics · 4 marks · −1Water is flowing continuously from a tap having an internal diameter m. The water velocity as it leaves the tap is 0.4 ms. The diameter of the water stream at a distance m below the tap is close to :
- A. m
- B. m
- C. m
- D. m
Correct answer: C
Explanation: m/s; m.
Question 16
Physics · 4 marks · −1Statement-1 : Sky wave signals are used for long distance radio communication. These signals are in general, less stable than ground wave signals. Statement-2 : The state of ionosphere varies from hour to hour, day to day and season to season.
- A.Statement-1 is true, Statement-2 is true; Statement-2 is the correct explanation of Statement-1.
- B.Statement-1 is true, Statement-2 is true; Statement-2 is not the correct explanation of Statement-1.
- C.Statement-1 is false, Statement-2 is true.
- D.Statement-1 is true, Statement-2 is false.
Correct answer: A
Explanation: Sky waves depend on ionospheric reflection, which fluctuates, explaining their instability.
Question 17
Physics · 4 marks · −1Three perfect gases at absolute temperatures , and are mixed. The masses of molecules are , and and the number of molecules are , and respectively. Assuming no loss of energy, the final temperature of the mixture is :
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Total translational KE conserved: (same degrees of freedom assumed).
Question 18
Physics · 4 marks · −1A pulley of radius 2 m is rotated about its axis by a force Newton (where t is measured in seconds) applied tangentially. If the moment of inertia of the pulley about its axis of rotation is 10 kg m, the number of rotations made by the pulley before its direction of motion is reversed, is :
- A.more than 3 but less than 6
- B.more than 6 but less than 9
- C.more than 9
- D.less than 3
Correct answer: A
Explanation: ; at s; rad rotations.
Question 19
Physics · 4 marks · −1A resistor R and F capacitor in series is connected through a switch to 200 V direct supply. Across the capacitor is a neon bulb that lights up at 120 V. Calculate the value of R to make the bulb light up 5 s after the switch has been closed. ()
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: ; .
Question 20
Physics · 4 marks · −1A Carnot engine operating between temperatures and has efficiency . When is lowered by 62 K, its efficiency increases to . Then and are, respectively :
- A.372 K and 330 K
- B.330 K and 268 K
- C.310 K and 248 K
- D.372 K and 310 K
Correct answer: D
Explanation: K, K.
Question 21
Physics · 4 marks · −1If a wire is stretched to make it 0.1% longer, its resistance will :
- A.increase by 0.2%
- B.decrease by 0.2%
- C.decrease by 0.05%
- D.increases by 0.05%
Correct answer: A
Explanation: Volume constant: , so .
Question 22
Physics · 4 marks · −1A car is fitted with a convex side-view mirror of focal length 20cm. A second car 2.8 m behind the first car is overtaking the first car at relative speed of 15 m/s. The speed of the image of the second car as seen in the mirror of the first one is :
- A. m/s
- B.10 m/s
- C.15 m/s
- D. m/s
Correct answer: A
Explanation: cm; image speed m/s.
Question 23
Physics · 4 marks · −1Energy required for the electron excitation in from the first to the third Bohr orbit is :
- A.36.3 eV
- B.108.8 eV
- C.122.4 eV
- D.12.1 eV
Correct answer: B
Explanation: eV.
Question 24
Physics · 4 marks · −1The electrostatic potential inside a charged spherical ball is given by where is the distance from the centre; a, b are constants. Then the charge density inside ball is :
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: ; Gauss: .
Question 25
Physics · 4 marks · −1A water fountain on the ground sprinkles water all around it. If the speed of water coming out of the fountain is v, the total area around the fountain that gets wet is :
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Maximum range ; area .
Question 26
Physics · 4 marks · −1100g of water is heated from C to C. Ignoring the slight expansion of the water, the change in its internal energy is (specific heat of water is 4148 J/kg/K):
- A.8.4 kJ
- B.84 kJ
- C.2.1 kJ
- D.4.2 kJ
Correct answer: A
Explanation: kJ.
Question 27
Physics · 4 marks · −1The half life of a radioactive substance is 20 minutes. The approximate time interval between the time when of it has decayed and time when of it had decayed is :
- A.14 min
- B.20 min
- C.28 min
- D.7 min
Correct answer: B
Explanation: Remaining at and at : ratio 2, i.e. one half-life, 20 min.
Question 28
Physics · 4 marks · −1Statement-1 : A metallic surface is irradiated by a monochromatic light of frequency (the threshold frequency). The maximum kinetic energy and the stopping potential are and respectively. If the frequency incident on the surface doubled, both the and are also doubled. Statement-2 : The maximum kinetic energy and the stopping potential of photoelectrons emitted from a surface are linearly dependent on the frequency of incident light.
- A.Statement-1 is true, Statement-2 is true; Statement-2 is the correct explanation of Statement-1.
- B.Statement-1 is true, Statement-2 is true; Statement-2 is not the correct explanation of Statement-1.
- C.Statement-1 is false, Statement-2 is true.
- D.Statement-1 is true, Statement-2 is false.
Correct answer: C
Explanation: is linear but not proportional, so doubling more than doubles .
Question 29
Mathematics · 4 marks · −1The lines and intersect the line at P and Q respectively. The bisector of the acute angle between and intersect at R. Statement-1 : The ratio PR : RQ equals . Statement-2 : In any triangle, bisector of an angle divides the triangle into two similar triangles.
- A.Statement-1 is true, Statement-2 is true; Statement-2 is not a correct explanation for Statement-1
- B.Statement-1 is true, Statement-2 is false.
- C.Statement-1 is false, Statement-2 is true.
- D.Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for Statement-1
Correct answer: B
Explanation: , ; bisector theorem: . Statement-2 is false in general.
Question 30
Mathematics · 4 marks · −1If , then for all real x
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: .
Question 31
Mathematics · 4 marks · −1The coefficient of in the expansion of is
- A.
- B.
- C.132
- D.144
Correct answer: B
Explanation: ; from : .
Question 32
Mathematics · 4 marks · −1- A.equals
- B.equals
- C.equals
- D.does not exist
Correct answer: D
Explanation: : limits from the two sides.
Question 33
Mathematics · 4 marks · −1Statement-1 : The number of ways of distributing 10 identical balls in 4 distinct boxes such that no box is empty is . Statement-2 : The number of ways of choosing any 3 places from 9 different places is .
- A.Statement-1 is true, Statement-2 is true; Statement-2 is not a correct explanation for Statement-1
- B.Statement-1 is true, Statement-2 is false.
- C.Statement-1 is false, Statement-2 is true.
- D.Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for Statement-1
Correct answer: D
Explanation: Place separators in 3 of the 9 gaps between the 10 balls: exactly the choice described in Statement-2.
Question 34
Mathematics · 4 marks · −1equals
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: .
Question 35
Mathematics · 4 marks · −1If and , then is equal to
- A.5
- B.13
- C.
- D.7
Correct answer: D
Explanation: ; .
Question 36
Mathematics · 4 marks · −1Let R be the set of real numbers. Statement-1 : is an equivalence relation on R. Statement-2 : is an equivalence relation on R.
- A.Statement-1 is true, Statement-2 is true; Statement-2 is not a correct explanation for Statement-1
- B.Statement-1 is true, Statement-2 is false.
- C.Statement-1 is false, Statement-2 is true.
- D.Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for Statement-1
Correct answer: B
Explanation: A is reflexive, symmetric, transitive. B is not symmetric: () but .
Question 37
Mathematics · 4 marks · −1The value of is
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: With : .
Question 38
Mathematics · 4 marks · −1Let be real and z be a complex number. If has two distinct roots on the line , then it is necessary that
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Roots () give .
Question 39
Mathematics · 4 marks · −1Consider 5 independent Bernoulli's trials each with probability of success p. If the probability of at least one failure is greater than or equal to , then p lies in the interval
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: .
Question 40
Mathematics · 4 marks · −1A man saves Rs. 200 in each of the first three months of his service. In each of the subsequent months his saving increases by Rs. 40 more than the saving of immediately previous month. His total saving from the start of service will be Rs. 11040 after
- A.19 months
- B.20 months
- C.21 months
- D.18 months
Correct answer: C
Explanation: .
Question 41
Mathematics · 4 marks · −1The domain of the function is
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: .
Question 42
Mathematics · 4 marks · −1If the angle between the line and the plane is , then equals
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: .
Question 43
Mathematics · 4 marks · −1If and , then the value of is
- A.
- B.5
- C.3
- D.
Correct answer: D
Explanation: are orthogonal unit vectors; , so the value is .
Question 44
Mathematics · 4 marks · −1Equation of the ellipse whose axes are the axes of coordinates and which passes through the point and has eccentricity is
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: ; : .
Question 45
Mathematics · 4 marks · −1Let I be the purchase value of an equipment and V(t) be the value after it has been used for t years. The value V(t) depreciates at a rate given by differential equation , where is a constant and T is the total life in years of the equipment. Then the scrap value V(T) of the equipment is
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: ; at : .
Question 46
Mathematics · 4 marks · −1The vector and are not perpendicular and and are two vectors satisfying: and . Then the vector is equal to
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: ; .
Question 47
Mathematics · 4 marks · −1The two circles and touch each other if
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: First circle: centre , radius , passing through the origin; internal tangency needs .
Question 48
Mathematics · 4 marks · −1If C and D are two events such that and , then the correct statement among the following is
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: .
Question 49
Mathematics · 4 marks · −1The number of values of k for which the linear equations ; ; possess a non-zero solution is
- A.2
- B.1
- C.zero
- D.3
Correct answer: A
Explanation: Determinant .
Question 50
Mathematics · 4 marks · −1Consider the following statements P : Suman is brilliant, Q : Suman is rich, R : Suman is honest. The negation of the statement 'Suman is brilliant and dishonest if and only if Suman is rich' can be expressed as
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: The statement is ; its negation is option 1.
Question 51
Mathematics · 4 marks · −1The shortest distance between line and curve is
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Distance from : , minimum .
Question 52
Mathematics · 4 marks · −1If the mean deviation about the median of the numbers a, 2a, ..., 50a is 50, then |a| equals
- A.3
- B.4
- C.5
- D.2
Correct answer: B
Explanation: Median ; mean deviation .
Question 53
Mathematics · 4 marks · −1Statement-1 : The point A(1, 0, 7) is the mirror image of the point B(1, 6, 3) in the line . Statement-2 : The line bisects the line segment joining A(1, 0, 7) and B(1, 6, 3).
- A.Statement-1 is true, Statement-2 is true; Statement-2 is not a correct explanation for Statement-1
- B.Statement-1 is true, Statement-2 is false.
- C.Statement-1 is false, Statement-2 is true.
- D.Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for Statement-1
Correct answer: A
Explanation: Midpoint lies on the line and the line, so S1 is true; S2 is true but bisection alone does not establish the mirror image.
Question 54
Mathematics · 4 marks · −1Let A and B be two symmetric matrices of order 3. Statement-1 : A(BA) and (AB)A are symmetric matrices. Statement-2 : AB is symmetric matrix if matrix multiplication of A and B is commutative.
- A.Statement-1 is true, Statement-2 is true; Statement-2 is not a correct explanation for Statement-1
- B.Statement-1 is true, Statement-2 is false.
- C.Statement-1 is false, Statement-2 is true.
- D.Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for Statement-1
Correct answer: A
Explanation: ; S2 also true but not the reason.
Question 55
Mathematics · 4 marks · −1If is a cube root of unity, and . Then (A, B) equals
- A.(1, 1)
- B.(1, 0)
- C.
- D.(0, 1)
Correct answer: A
Explanation: .
Question 56
Mathematics · 4 marks · −1The value of p and q for which the function is continuous for all x in R, is
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: Right limit ; left limit .
Question 57
Mathematics · 4 marks · −1The area of the region enclosed by the curves , , and the positive x-axis is
- A.1 square units
- B. square units
- C. square units
- D. square units
Correct answer: B
Explanation: .
Question 58
Mathematics · 4 marks · −1For , define . Then f has
- A.local minimum at and
- B.local minimum at and local maximum at
- C.local maximum at and local minimum at
- D.local maximum at and
Correct answer: C
Explanation: changes + to - at and - to + at .
Question 59
Chemistry · 4 marks · −1Among the following the maximum covalent character is shown by the compound :
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: Small, highly charged polarises most (Fajans' rules).
Question 60
Chemistry · 4 marks · −1The presence or absence of hydroxyl group on which carbon atom of sugar differentiates RNA and DNA ?
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: DNA contains 2-deoxyribose.
Question 61
Chemistry · 4 marks · −1Trichloroacetaldehyde was subjected to Cannizzaro's reaction by using NaOH. The mixture of the products contains sodium trichloroacetate and another compound. The other compound is :
- A.Trichloromethanol
- B.2, 2, 2-Trichloropropanol
- C.Chloroform
- D.2, 2, 2-Trichloroethanol
Correct answer: D
Explanation: Disproportionation: one aldehyde is reduced to .
Question 62
Chemistry · 4 marks · −1Sodium ethoxide has reacted with ethanoyl chloride. The compound that is produced in the above reaction is :
- A.2-Butanone
- B.Ethyl chloride
- C.Ethyl ethanoate
- D.Diethyl ether
Correct answer: C
Explanation: .
Question 63
Chemistry · 4 marks · −1The reduction potential of hydrogen half cell will be negative if :
- A. atm and M
- B. atm and M
- C. atm and M
- D. atm and M
Correct answer: B
Explanation: requires : only option 2.
Question 64
Chemistry · 4 marks · −1The strongest acid amongst the following compounds is :
- A.HCOOH
- B.
- C.
- D.
Correct answer: B
Explanation: The -chloro (-I close to COOH) acid is strongest.
Question 65
Chemistry · 4 marks · −1The degree of dissociation of a weak electrolyte, is related to van't Hoff factor (i) by the expression :
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: .
Question 66
Chemistry · 4 marks · −1'a' and 'b' are van der Waals' constants for gases. Chlorine is more easily liquefied than ethane because
- A.a and b for < a and b for
- B.a for < a for but b for > b for
- C.a for > a for but b for < b for
- D.a and b for > a and b for
Correct answer: C
Explanation: Larger a (attraction) and smaller b favour liquefaction (: a 6.49, b 0.0562; : 5.49, 0.0638).
Question 67
Chemistry · 4 marks · −1A vessel at 1000 K contains with a pressure of 0.5 atm. Some of the is converted into CO on the addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is
- A.3 atm
- B.0.3 atm
- C.0.18 atm
- D.1.8 atm
Correct answer: D
Explanation: : ; atm.
Question 68
Chemistry · 4 marks · −1Boron cannot form which one of the following anions ?
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Boron has no d orbitals; maximum covalency 4.
Question 69
Chemistry · 4 marks · −1Which of the following facts about the complex is wrong ?
- A.The complex is paramagnetic
- B.The complex is an outer orbital complex
- C.The complex gives white precipitate with silver nitrate solution
- D.The complex involves hybridization and is octahedral in shape.
Correct answer: B
Explanation: () uses inner 3d orbitals: , inner-orbital.
Question 70
Chemistry · 4 marks · −1Ethylene glycol is used as an antifreeze in a cold climate. Mass of ethylene glycol which should be added to 4 kg of water to prevent it from freezing at C will be : ( for water = 1.86 K kg mol, and molar mass of ethylene glycol = 62g mol)
- A.204.30g
- B.400.00 g
- C.304.60 g
- D.804.32g
Correct answer: D
Explanation: g g (option 4).
Question 71
Chemistry · 4 marks · −1Which one of the following order represents the correct sequence of the increasing basic nature of the given oxides ?
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Basicity rises with metallic character.
Question 72
Chemistry · 4 marks · −1The rate of a chemical reaction doubles for every C rise of temperature. If the temperature is raised by C, the rate of the reaction increases by about :
- A.24 times
- B.32 times
- C.64 times
- D.10 times
Correct answer: B
Explanation: .
Question 73
Chemistry · 4 marks · −1The magnetic moment (spin only) of is
- A.5.46 BM
- B.2.83 BM
- C.1.41 BM
- D.1.82 BM
Correct answer: B
Explanation: Tetrahedral (), 2 unpaired: BM.
Question 74
Chemistry · 4 marks · −1The hybridization of orbitals of N atom in , and are respectively :
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Trigonal planar, linear, tetrahedral.
Question 75
Chemistry · 4 marks · −1In context of the lanthanoids, which of the following statements is not correct ?
- A.All the members exhibit +3 oxidation state
- B.Because of similar properties the separation of lanthanoids is not easy.
- C.Availability of 4f electrons results in the formation of compounds in +4 state for all the members of the series.
- D.There is a gradual decrease in the radii of the members with increasing atomic number in the series.
Correct answer: C
Explanation: Only a few lanthanoids (e.g. Ce) show +4.
Question 76
Chemistry · 4 marks · −1A 5.2 molal aqueous solution of methyl alcohol, , is supplied. What is the mole fraction of methyl alcohol in the solution ?
- A.0.190
- B.0.086
- C.0.050
- D.0.100
Correct answer: B
Explanation: .
Question 77
Chemistry · 4 marks · −1Which of the following statement is wrong ?
- A.Nitrogen cannot form bond.
- B.Single N - N bond is weaker than the single P - P bond.
- C. has two resonance structures
- D.The stability of hydrides increases from to in group 15 of the periodic table
Correct answer: D
Explanation: Hydride stability decreases down group 15.
Question 78
Chemistry · 4 marks · −1The outer electron configuration of Gd (Atomic No : 64) is :
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Half-filled 4f stability: .
Question 79
Chemistry · 4 marks · −1Which of the following statements regarding sulphur is incorrect ?
- A.The vapour at C consists mostly of rings
- B.At C the gas mainly consists of molecules
- C.The oxidation state of sulphur is never less than +4 in its compounds
- D. molecule is paramagnetic.
Correct answer: C
Explanation: Sulphur shows (e.g. ).
Question 80
Chemistry · 4 marks · −1The structure of is :
- A.trigonal bipyramid
- B.octahedral
- C.pentagonal bipyramid
- D.square pyramid
Correct answer: C
Explanation: : pentagonal bipyramid.
Question 81
Chemistry · 4 marks · −1Ozonolysis of an organic compound gives formaldehyde as one of the products. This confirms the presence of :
- A.a vinyl group
- B.an isopropyl group
- C.an acetylenic triple bond
- D.two ethylenic double bonds
Correct answer: A
Explanation: A terminal (vinyl) gives HCHO.
Question 82
Chemistry · 4 marks · −1A gas absorbs a photon of 355 nm and emits at two wavelengths. If one of the emissions is at 680 nm, the other is at :
- A.325 nm
- B.743 nm
- C.518 nm
- D.1035 nm
Correct answer: B
Explanation: nm.
Question 83
Chemistry · 4 marks · −1Which of the following reagents may be used to distinguish between phenol and benzoic acid ?
- A.Tollen's reagent
- B.Molisch reagent
- C.Neutral
- D.Aqueous NaOH
Correct answer: C
Explanation: Phenol gives a violet colour with neutral ; benzoic acid a buff precipitate.
Question 84
Chemistry · 4 marks · −1Phenol is heated with a solution of mixture of KBr and . The major product obtained in the above reaction is
- A.3-Bromophenol
- B.4-Bromophenol
- C.2, 4, 6- Tribromophenol
- D.2-Bromophenol
Correct answer: C
Explanation: in acid liberates (aq), giving 2,4,6-tribromophenol.
Question 85
Chemistry · 4 marks · −1In a face centred cubic lattice, atom A occupies the corner positions and atom B occupies the face centre positions. If one atom of B is missing from one of the face centred points, the formula of the compound is :
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: A: 1; B: ; formula .
Question 86
Chemistry · 4 marks · −1The entropy change involved in the isothermal reversible expansion of 2 moles of an ideal gas from a volume of 10 dm to a volume of 100 dm at C is :
- A.35.8J molK
- B.32.3J molK
- C.42.3J molK
- D.38.3J molK
Correct answer: D
Explanation: J/K.
Question 87
Chemistry · 4 marks · −1Identify the compound that exhibits tautomerism.
- A.Lactic acid
- B.2-Pentanone
- C.Phenol
- D.2- Butene
Correct answer: B
Explanation: 2-Pentanone has -hydrogens and shows keto-enol tautomerism.