JEE Main 2014 — 6 Apr Offline Set H (Previous Year Paper)
JEE Main · 2014 · with answers and explanations
- questions
- 89
- Total marks
- 356
- Duration
- 180 minutes
- Negative marking
- −1
Subjects: Physics · Mathematics · Chemistry
Question 1
Physics · 4 marks · −1The pressure that has to be applied to the ends of a steel wire of length 10 cm to keep its length constant when its temperature is raised by C is : (For steel Young's modulus is N m and coefficient of thermal expansion is K)
- A. Pa
- B. Pa
- C. Pa
- D. Pa
Correct answer: C
Explanation: Thermal stress Pa.
Question 2
Physics · 4 marks · −1A conductor lies along the z-axis at m and carries a fixed current of 10.0 A in direction (see figure). For a field T, find the power required to move the conductor at constant speed to m, m in s. Assume parallel motion along the x-axis

- A.14.85 W
- B.29.7 W
- C.1.57 W
- D.2.97 W
Correct answer: D
Explanation: J; W.
Question 3
Physics · 4 marks · −1A bob of mass m attached to an inextensible string of length is suspended from a vertical support. The bob rotates in a horizontal circle with an angular speed rad/s about the vertical. About the point of suspension :
- A.angular momentum changes in direction but not in magnitude.
- B.angular momentum changes both in direction and magnitude.
- C.angular momentum is conserved.
- D.angular momentum changes in magnitude but not in direction.
Correct answer: A
Explanation: For a conical pendulum, about the suspension point has constant magnitude but precesses about the vertical.
Question 4
Physics · 4 marks · −1The current voltage relation of diode is given by mA, where the applied voltage V is in volts and the temperature T is in degree Kelvin. If a student makes an error measuring V while measuring the current of 5 mA at 300 K, what will be the error in the value of current in mA ?
- A.0.5 mA
- B.0.05 mA
- C.0.2 mA
- D.0.02 mA
Correct answer: C
Explanation: ; mA.
Question 5
Physics · 4 marks · −1An open glass tube is immersed in mercury in such a way that a length of 8 cm extends above the mercury level. The open end of the tube is then closed and sealed and the tube is raised vertically up by additional 46 cm. What will be length of the air column above mercury in the tube now? (Atmospheric pressure = 76 cm of Hg)
- A.38 cm
- B.6 cm
- C.16 cm
- D.22 cm
Correct answer: C
Explanation: Boyle: where x is the mercury rise; cm, so the air column is cm.
Question 6
Physics · 4 marks · −1Match List-I (Electromagnetic wave type) with List-II (Its association/application): (a) Infrared waves, (b) Radio waves, (c) X-rays, (d) Ultraviolet rays; (i) To treat muscular strain, (ii) For broadcasting, (iii) To detect fracture of bones, (iv) Absorbed by the ozone layer of the atmosphere
- A.(a)-(iii), (b)-(ii), (c)-(i), (d)-(iv)
- B.(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)
- C.(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)
- D.(a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)
Correct answer: B
Explanation: IR: muscular strain; radio: broadcasting; X-rays: bone fractures; UV: absorbed by ozone.
Question 7
Physics · 4 marks · −1A parallel plate capacitor is made of two circular plates separated by a distance of 5 mm and with a dielectric of dielectric constant 2.2 between them. When the electric field in the dielectric is V/m, the charge density of the positive plate will be close to :
- A. C/m
- B. C/m
- C. C/m
- D. C/m
Correct answer: C
Explanation: C/m.
Question 8
Physics · 4 marks · −1A student measured the length of a rod and wrote it as 3.50 cm. Which instrument did he use to measure it?
- A.A screw gauge having 100 divisions in the circular scale and pitch as 1 mm.
- B.A screw gauge having 50 divisions in the circular scale and pitch as 1 mm.
- C.A meter scale.
- D.A vernier calliper where the 10 divisions in vernier scale matches with 9 division in main scale and main scale has 10 divisions in 1 cm.
Correct answer: D
Explanation: 3.50 cm implies a least count of 0.01 cm = 0.1 mm, which is that vernier calliper's least count.
Question 9
Physics · 4 marks · −1Four particles, each of mass M and equidistant from each other, move along a circle of radius R under the action of their mutual gravitational attraction. The speed of each particle is :
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: Net inward force .
Question 10
Physics · 4 marks · −1In a large building, there are 15 bulbs of 40 W, 5 bulbs of 100 W, 5 fans of 80 W and 1 heater of 1kW. The voltage of the electric mains is 220 V. The minimum capacity of the main fuse of the building will be :
- A.12 A
- B.14 A
- C.8 A
- D.10 A
Correct answer: A
Explanation: Total 2500 W; A, so a 12 A fuse.
Question 11
Physics · 4 marks · −1A particle moves with simple harmonic motion in a straight line. In first s, after starting from rest it travels a distance a, and in next s it travels 2a, in same direction, then :
- A.amplitude of motion is 4a
- B.time period of oscillations is
- C.amplitude of motion is 3a
- D.time period of oscillations is
Correct answer: B
Explanation: , give , , so .
Question 12
Physics · 4 marks · −1The coercivity of a small magnet where the ferromagnet gets demagnetized is Am. The current required to be passed in a solenoid of length 10 cm and number of turns 100, so that the magnet gets demagnetized when inside the solenoid, is:
- A.3A
- B.6A
- C.30 mA
- D.60 mA
Correct answer: A
Explanation: A.
Question 13
Physics · 4 marks · −1The forward biased diode connection is:

- A.Anode at 2V, cathode side (through resistor) at 4V
- B.Anode at V, cathode side at V
- C.Anode at V, cathode side at V
- D.Anode at V, cathode side at V
Correct answer: C
Explanation: Forward bias needs the p side (anode) at higher potential than the n side: V to V.
Question 14
Physics · 4 marks · −1During the propagation of electromagnetic waves in a medium:
- A.Electric energy density is equal to the magnetic energy density.
- B.Both electric and magnetic energy densities are zero.
- C.Electric energy density is double of the magnetic energy density.
- D.Electric energy density is half of the magnetic energy density.
Correct answer: A
Explanation: In an EM wave the average electric and magnetic energy densities are equal.
Question 15
Physics · 4 marks · −1In the circuit shown here, the point 'C' is kept connected to point 'A' till the current flowing through the circuit becomes constant. Afterward, suddenly, point 'C' is disconnected from point 'A' and connected to point 'B' at time . Ratio of the voltage across resistance and the inductor at will be equal to :

- A.
- B.
- C.
- D.1
Correct answer: A
Explanation: After switching, R and L form a closed loop with no source: at every instant, so .
Question 16
Physics · 4 marks · −1A mass 'm' is supported by a massless string wound around a uniform hollow cylinder of mass m and radius R. If the string does not slip on the cylinder, with what acceleration will the mass fall on release?

- A.
- B.g
- C.
- D.
Correct answer: D
Explanation: , ; so .
Question 17
Physics · 4 marks · −1One mole of diatomic ideal gas undergoes a cyclic process ABC as shown in figure. The process BC is adiabatic. The temperatures at A, B and C are 400 K, 800 K and 600 K respectively. Choose the correct statement:

- A.The change in internal energy in the process AB is R.
- B.The change in internal energy in the process BC is R.
- C.The change in internal energy in whole cyclic process is 250R.
- D.The change in internal energy in the process CA is 700R.
Correct answer: B
Explanation: .
Question 18
Physics · 4 marks · −1From a tower of height H, a particle is thrown vertically upwards with a speed u. The time taken by the particle, to hit the ground, is n times that taken by it to reach the highest point of its path. The relation between H, u and n is:
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: .
Question 19
Physics · 4 marks · −1A thin convex lens made from crown glass has focal length f. When it is measured in two different liquids having refractive indices and , it has the focal lengths and respectively. The correct relation between the focal lengths is:
- A. and becomes negative
- B. and both become negative
- C.
- D. and becomes negative
Correct answer: D
Explanation: : , .
Question 20
Physics · 4 marks · −1Three rods of Copper, Brass and Steel are welded together to form a Y-shaped structure. Area of cross-section of each rod = 4 cm. End of copper rod is maintained at C where as ends of brass and steel are kept at C. Lengths of the copper, brass and steel rods are 46, 13 and 12 cms respectively. The rods are thermally insulated from surroundings except at ends. Thermal conductivities of copper, brass and steel are 0.92, 0.26 and 0.12 CGS units respectively. Rate of heat flow through copper rod is :
- A.4.8 cal/s
- B.6.0 cal/s
- C.1.2 cal/s
- D.2.4 cal/s
Correct answer: A
Explanation: Junction temperature T: C; cal/s.
Question 21
Physics · 4 marks · −1A pipe of length 85 cm is closed from one end. Find the number of possible natural oscillations of air column in the pipe whose frequencies lie below 1250 Hz. The velocity of sound in air is 340 m/s.
- A.6
- B.4
- C.12
- D.8
Correct answer: A
Explanation: Fundamental Hz; odd harmonics 100, 300, ..., 1100 Hz: 6 modes.
Question 22
Physics · 4 marks · −1There is a circular tube in a vertical plane. Two liquids which do not mix and of densities and are filled in the tube. Each liquid subtends angle at centre. Radius joining their interface makes an angle with vertical. Ratio is

- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Balancing pressures at the bottom of the tube through the two liquid columns gives for the geometry shown, i.e. .
Question 23
Physics · 4 marks · −1A green light is incident from the water to the air - water interface at the critical angle . Select the correct statement
- A.The spectrum of visible light whose frequency is more than that of green light will come out to the air medium.
- B.The entire spectrum of visible light will come out of the water at various angles to the normal.
- C.The entire spectrum of visible light will come out of the water at an angle of to the normal.
- D.The spectrum of visible light whose frequency is less than that of green light will come out to the air medium.
Correct answer: D
Explanation: Lower-frequency colours have smaller refractive index and larger critical angle, so they escape; higher frequencies are totally reflected.
Question 24
Physics · 4 marks · −1Hydrogen , Deuterium , singly ionised Helium and doubly ionised lithium all have one electron around the nucleus. Consider an electron transition from n = 2 to n = 1. If the wave lengths of emitted radiation are , , and respectively then approximately which one of the following is correct?
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: : Z = 1, 1, 2, 3.
Question 25
Physics · 4 marks · −1The radiation corresponding to transition of hydrogen atom falls on a metal surface to produce photoelectrons. These electrons are made to enter a magnetic field of T. If the radius of the largest circular path followed by these electrons is 10.0 mm, the work function of the metal is close to :
- A.0.8 eV
- B.1.6 eV
- C.1.8 eV
- D.1.1 eV
Correct answer: D
Explanation: eV; photon eV; eV.
Question 26
Physics · 4 marks · −1A block of mass m is placed on a surface with a vertical cross section given by . If the coefficient of friction is 0.5, the maximum height above the ground at which the block can be placed without slipping is :
- A. m
- B. m
- C. m
- D. m
Correct answer: C
Explanation: Limiting: , m.
Question 27
Physics · 4 marks · −1When a rubber-band is stretched by a distance x, it exerts a restoring force of magnitude where a and b are constants. The work done in stretching the unstretched rubber band by L is :
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: .
Question 28
Physics · 4 marks · −1On heating water, bubbles being formed at the bottom of the vessel detach and rise. Take the bubbles to be spheres of radius R and making a circular contact of radius r with the bottom of the vessel. If , and the surface tension of water is T, value of r just before bubbles detach is : (density of water is )

- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Balancing the vertical surface-tension force on the contact circle ( with ) against buoyancy gives ; the official key accepts option 3.
Question 29
Physics · 4 marks · −1Two beams, A and B, of plane polarized light with mutually perpendicular planes of polarization are seen through a polaroid. From the position when the beam A has maximum intensity (and beam B has zero intensity), a rotation of Polaroid through makes the two beams appear equally bright. If the initial intensities of the two beams are and respectively, then equals :
- A.1
- B.
- C.3
- D.
Correct answer: B
Explanation: .
Question 30
Physics · 4 marks · −1Assume that an electric field exists in space. Then the potential difference , where is the potential at the origin and the potential at m is :
- A. J
- B.80 J
- C.120 J
- D. J
Correct answer: A
Explanation: V (options are printed in J).
Question 31
Mathematics · 4 marks · −1The image of the line in the plane is the line
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: The line is parallel to the plane (); image of is , same direction ratios.
Question 32
Mathematics · 4 marks · −1If the coefficients of and in the expansion of in powers of x are both zero, then is equal to
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Setting the and coefficients to zero gives two linear equations in a, b; solving, , .
Question 33
Mathematics · 4 marks · −1If and the equation (where [x] denotes the greatest integer ) has no integral solution, then all possible values of a lie in the interval
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: With : ; a non-integral solution needs , i.e. .
Question 34
Mathematics · 4 marks · −1If , then is equal to
- A.2
- B.3
- C.0
- D.1
Correct answer: D
Explanation: , so .
Question 35
Mathematics · 4 marks · −1The variance of first 50 even natural numbers is
- A.
- B.833
- C.437
- D.
Correct answer: B
Explanation: .
Question 36
Mathematics · 4 marks · −1A bird is sitting on the top of a vertical pole 20 m high and its elevation from a point O on the ground is . It flies off horizontally straight away from the point O. After one second, the elevation of the bird from O is reduced to . Then the speed (in m/s) of the bird is
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: m in 1 s.
Question 37
Mathematics · 4 marks · −1The integral equals
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Integrand , changing sign at ; evaluating gives .
Question 38
Mathematics · 4 marks · −1The statement is
- A.equivalent to
- B.equivalent to
- C.a tautology
- D.a fallacy
Correct answer: A
Explanation: Truth table: is true exactly when p, q agree.
Question 39
Mathematics · 4 marks · −1If A is an non-singular matrix such that and , then equals
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: , so , hence .
Question 40
Mathematics · 4 marks · −1The integral is equal to
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: .
Question 41
Mathematics · 4 marks · −1If z is a complex number such that , then the minimum value of
- A.is equal to
- B.lies in the interval (1, 2)
- C.is strictly greater than
- D.is strictly greater than but less than
Correct answer: B
Explanation: Minimum distance from to the region is .
Question 42
Mathematics · 4 marks · −1If g is the inverse of a function f and , then is equal to
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: .
Question 43
Mathematics · 4 marks · −1If , and and , then K is equal to
- A.
- B.
- C.1
- D.
Correct answer: C
Explanation: The determinant is the square of the Vandermonde , so .
Question 44
Mathematics · 4 marks · −1Let where and . Then equals
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: .
Question 45
Mathematics · 4 marks · −1Let and be the roots of equation , . If p, q, r are in A.P. and , then the value of is
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: and give , i.e. ; .
Question 46
Mathematics · 4 marks · −1Let A and B be two events such that , and , where stands for the complement of the event A. Then the events A and B are
- A.mutually exclusive and independent
- B.equally likely but not independent
- C.independent but not equally likely
- D.independent and equally likely
Correct answer: C
Explanation: , ; .
Question 47
Mathematics · 4 marks · −1If f and g are differentiable functions in [0, 1] satisfying , and , then for some
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: has ; Rolle gives .
Question 48
Mathematics · 4 marks · −1Let the population of rabbits surviving at a time t be governed by the differential equation . If , then equals
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: .
Question 49
Mathematics · 4 marks · −1Let C be the circle with centre at (1, 1) and radius = 1. If T is the circle centred at (0, y), passing through origin and touching the circle C externally, then the radius of T is equal to
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: .
Question 50
Mathematics · 4 marks · −1The area of the region described by is
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Left half-disc plus the parabolic region for : .
Question 51
Mathematics · 4 marks · −1Let a, b, c and d be non-zero numbers. If the point of intersection of the lines and lies in the fourth quadrant and is equidistant from the two axes then
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Point : , , i.e. .
Question 52
Mathematics · 4 marks · −1Let PS be the median of the triangle with vertices P(2, 2), Q(6, ) and R(7, 3). The equation of the line passing through and parallel to PS is
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: , slope of PS ; line: .
Question 53
Mathematics · 4 marks · −1is equal to
- A.
- B.1
- C.
- D.
Correct answer: D
Explanation: .
Question 54
Mathematics · 4 marks · −1If and , where is the set of natural numbers, then is equal to
- A.
- B.
- C.X
- D.Y
Correct answer: D
Explanation: is always a multiple of 9 (binomial expansion of ), so .
Question 55
Mathematics · 4 marks · −1The locus of the foot of perpendicular drawn from the centre of the ellipse on any tangent to it is
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Tangent with foot , : .
Question 56
Mathematics · 4 marks · −1Three positive numbers form an increasing G.P. If the middle term in this G.P. is doubled, the new numbers are in A.P. Then the common ratio of the G.P. is
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: , increasing so .
Question 57
Mathematics · 4 marks · −1If , then k is equal to
- A.
- B.
- C.100
- D.110
Correct answer: C
Explanation: AGP: telescopes to give , so .
Question 58
Mathematics · 4 marks · −1The angle between the lines whose direction cosines satisfy the equations and is
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Substituting gives : directions and , .
Question 59
Mathematics · 4 marks · −1The slope of the line touching both the parabolas and is
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Tangent to touches when , .
Question 60
Mathematics · 4 marks · −1If and are extreme points of , then
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: has roots : , .
Question 61
Chemistry · 4 marks · −1Which one of the following properties is not shown by NO?
- A.It combines with oxygen to form nitrogen dioxide
- B.It's bond order is 2.5
- C.It is diamagnetic in gaseous state
- D.It is a neutral oxide
Correct answer: C
Explanation: NO has an odd electron and is paramagnetic.
Question 62
Chemistry · 4 marks · −1If Z is a compressibility factor, van der Waals equation at low pressure can be written as:
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: At low pressure the b terms are negligible: , .
Question 63
Chemistry · 4 marks · −1The metal that cannot be obtained by electrolysis of an aqueous solution of its salts is:
- A.Cu
- B.Cr
- C.Ag
- D.Ca
Correct answer: D
Explanation: Water is reduced (H2 evolves) in preference to .
Question 64
Chemistry · 4 marks · −1Resistance of 0.2 M solution of an electrolyte is . The specific conductance of the solution is 1.4 S m. The resistance of 0.5 M solution of the same electrolyte is . The molar conductivity of 0.5 M solution of the electrolyte in S m mol is:
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Cell constant m; S/m; .
Question 65
Chemistry · 4 marks · −1CsCl crystallises in body centred cubic lattice. If 'a' is its edge length then which of the following expressions is correct?
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Ions touch along the body diagonal: .
Question 66
Chemistry · 4 marks · −1Consider separate solutions of 0.500 M (aq), 0.100 M (aq), 0.250 M KBr(aq) and 0.125 M (aq) at C. Which statement is true about these solutions, assuming all salts to be strong electrolytes?
- A.0.125 M (aq) has the highest osmotic pressure.
- B.0.500 M (aq) has the highest osmotic pressure.
- C.They all have the same osmotic pressure.
- D.0.100 M (aq) has the highest osmotic pressure.
Correct answer: C
Explanation: : , , , — all isotonic.
Question 67
Chemistry · 4 marks · −1In which of the following reactions acts as a reducing agent? (a) (b) (c) (d)
- A.(a), (c)
- B.(b), (d)
- C.(a), (b)
- D.(c), (d)
Correct answer: B
Explanation: A reducing agent loses electrons: (b) and (d).
Question 68
Chemistry · 4 marks · −1In reactions, the correct order of reactivity for the following compounds: , , and is:
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: rate falls with steric hindrance: methyl > 1° > 2° > 3°.
Question 69
Chemistry · 4 marks · −1The octahedral complex of a metal ion with four monodentate ligands , , and absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing order of ligand strength of the four ligands is:
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Stronger field means larger splitting and shorter absorbed wavelength: red < yellow < green < blue, i.e. .
Question 70
Chemistry · 4 marks · −1For the estimation of nitrogen, 1.4 g of organic compound was digested by Kjeldahl method and the evolved ammonia was absorbed in 60 mL of sulphuric acid. The unreacted acid required 20 ml of sodium hydroxide for complete neutralization. The percentage of nitrogen in the compound is:
- A.3%
- B.5%
- C.6%
- D.10%
Correct answer: D
Explanation: meq of acid used ; %N .
Question 71
Chemistry · 4 marks · −1The equivalent conductance of NaCl at concentration C and at infinite dilution are and , respectively. The correct relationship between and is given as: (where the constant B is positive)
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Debye-Huckel-Onsager (Kohlrausch) law for strong electrolytes.
Question 72
Chemistry · 4 marks · −1For the reaction, , if where the symbols have usual meaning then the value of x is: (assuming ideality)
- A.
- B.1
- C.
- D.
Correct answer: D
Explanation: .
Question 73
Chemistry · 4 marks · −1In the reaction, , the product C is:
- A.Ethylene
- B.Acetyl chloride
- C.Acetaldehyde
- D.Acetylene
Correct answer: A
Explanation: Ethanol, then chloroethane, then dehydrohalogenation to ethylene.
Question 74
Chemistry · 4 marks · −1Sodium phenoxide when heated with under pressure at C yields a product which on acetylation produces C. The major product C would be:

- A.Methyl salicylate (2-hydroxybenzoic acid methyl ester)
- B.3-acetoxybenzoic acid
- C.2-acetoxybenzoic acid (aspirin)
- D.2-hydroxy-1,4-diacetylbenzene type (OH with two COCH3 groups)
Correct answer: C
Explanation: Kolbe reaction gives salicylic acid; acetylation of the phenolic OH gives aspirin.
Question 75
Chemistry · 4 marks · −1On heating an aliphatic primary amine with chloroform and ethanolic potassium hydroxide, the organic compound formed is:
- A.an alkyl cyanide
- B.an alkyl isocyanide
- C.an alkanol
- D.an alkanediol
Correct answer: B
Explanation: Carbylamine reaction: .
Question 76
Chemistry · 4 marks · −1The correct statement for the molecule, is:
- A.it contains and ions.
- B.it contains , and lattice molecule.
- C.it is a covalent molecule.
- D.it contains and ions.
Correct answer: D
Explanation: Cs shows only +1; the anion is triiodide .
Question 77
Chemistry · 4 marks · −1The equation which is balanced and represents the correct product(s) is:
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: (1) is not charge balanced; (2) actually gives ; (3) is unfavourable; (4) is balanced and correct.
Question 78
Chemistry · 4 marks · −1For which of the following molecule significant ? (a) 1,4-dichlorobenzene (b) 1,4-dicyanobenzene (c) hydroquinone (1,4-dihydroxybenzene) (d) benzene-1,4-dithiol

- A.Only (c)
- B.(c) and (d)
- C.Only (a)
- D.(a) and (b)
Correct answer: B
Explanation: The -OH and -SH groups are bent and rotate, so most conformations have a net dipole; the linear C-Cl and C-CN dipoles cancel.
Question 79
Chemistry · 4 marks · −1For the non-stoichiometre reaction , the following kinetic data were obtained in three separate experiments, all at 298 K. [A] = 0.1 M, [B] = 0.1 M: rate of formation of C = ; [A] = 0.1 M, [B] = 0.2 M: ; [A] = 0.2 M, [B] = 0.1 M: (mol L s). The rate law for the formation of C is:
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: Doubling B leaves the rate unchanged (zero order in B); doubling A doubles it (first order).
Question 80
Chemistry · 4 marks · −1Which series of reactions correctly represents chemical reactions related to iron and its compound?
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: Only series (2) is chemically correct (blast-furnace reduction steps).
Question 81
Chemistry · 4 marks · −1Considering the basic strength of amines in aqueous solution, which one has the smallest value?
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: In water, dimethylamine is the strongest base among these.
Question 82
Chemistry · 4 marks · −1Which one of the following bases is not present in DNA?
- A.Cytosine
- B.Thymine
- C.Quinoline
- D.Adenine
Correct answer: C
Explanation: DNA bases are A, G, C, T; quinoline is not a nucleobase.
Question 83
Chemistry · 4 marks · −1The correct set of four quantum numbers for the valence elections of rubidium atom (Z = 37) is:
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Rb: [Kr]5s, so .
Question 84
Chemistry · 4 marks · −1The major organic compound formed by the reaction of 1, 1, 1-trichloroethane with silver powder is:
- A.2-Butyne
- B.2-Butene
- C.Acetylene
- D.Ethene
Correct answer: A
Explanation: .
Question 85
Chemistry · 4 marks · −1Given below are the half-cell reactions: ; V; ; V. The for will be:
- A. V; the reaction will not occur
- B. V; the reaction will occur
- C. V; the reaction will not occur
- D. V; the reaction will occur
Correct answer: C
Explanation: V; negative, so non-spontaneous.
Question 86
Chemistry · 4 marks · −1The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1 : 4. The ratio of number of their molecule is:
- A.1 : 8
- B.3 : 16
- C.1 : 4
- D.7 : 32
Correct answer: D
Explanation: .
Question 87
Chemistry · 4 marks · −1Which one is classified as a condensation polymer?
- A.Teflon
- B.Acrylonitrile
- C.Dacron
- D.Neoprene
Correct answer: C
Explanation: Dacron (terylene) is a polyester made by condensation.
Question 88
Chemistry · 4 marks · −1Among the following oxoacids, the correct decreasing order of acid strength is:
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Acid strength rises with oxidation state of Cl.
Question 89
Chemistry · 4 marks · −1The most suitable reagent for the conversion of is:
- A.
- B.PCC (Pyridinium Chlorochromate)
- C.
- D.
Correct answer: B
Explanation: PCC stops the oxidation of a primary alcohol at the aldehyde.