JEE Main 2018 — 8 Apr Offline Set D (Previous Year Paper)
JEE Main · 2018 · with answers and explanations
- questions
- 89
- Total marks
- 356
- Duration
- 180 minutes
- Negative marking
- −1
Subjects: Mathematics · Physics · Chemistry
Question 1
Mathematics · 4 marks · −1If the curves , intersect each other at right angles, then the value of is :
- A.
- B.6
- C.
- D.4
Correct answer: A
Explanation: At the common point : , . and gives .
Question 2
Mathematics · 4 marks · −1Let be a vector coplanar with the vectors and . If is perpendicular to and , then is equal to :
- A.84
- B.336
- C.315
- D.256
Correct answer: B
Explanation: Write . ; . So , , .
Question 3
Mathematics · 4 marks · −1For each , let be the greatest integer less than or equal to . Then
- A.does not exist (in )
- B.is equal to 0
- C.is equal to 15
- D.is equal to 120
Correct answer: D
Explanation: , so the expression is since the fractional parts are bounded.
Question 4
Mathematics · 4 marks · −1If is the line of intersection of the planes , and is the line of intersection of the planes , , then the distance of the origin from the plane, containing the lines and , is :
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Directions: , . A point of is . Normal ; plane ; distance .
Question 5
Mathematics · 4 marks · −1The value of is :
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Adding the integral with gives , so .
Question 6
Mathematics · 4 marks · −1Let , , and be the roots of the quadratic equation . Then the area (in sq. units) bounded by the curve and the lines , and , is :
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: ; roots are . Area .
Question 7
Mathematics · 4 marks · −1If sum of all the solutions of the equation in is , then is equal to :
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: , so the equation becomes . Solutions in : ; sum .
Question 8
Mathematics · 4 marks · −1Let and , . If , then the local minimum value of is :
- A.
- B.3
- C.
- D.
Correct answer: A
Explanation: With , ; for the minimum is at .
Question 9
Mathematics · 4 marks · −1The integral is equal to : (where is a constant of integration)
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: Denominator base . Dividing by : ; put to get .
Question 10
Mathematics · 4 marks · −1A bag contains 4 red and 6 black balls. A ball is drawn at random from the bag, its colour is observed and this ball along with two additional balls of the same colour are returned to the bag. If now a ball is drawn at random from the bag, then the probability that this drawn ball is red, is :
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: .
Question 11
Mathematics · 4 marks · −1Let the orthocentre and centroid of a triangle be and respectively. If is the circumcentre of this triangle, then the radius of the circle having line segment as diameter, is :
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Centroid divides orthocentre-circumcentre in , so . ; radius .
Question 12
Mathematics · 4 marks · −1If the tangent at to the curve touches the circle then the value of is :
- A.95
- B.195
- C.185
- D.85
Correct answer: A
Explanation: Tangent: . Distance from centre is , so , .
Question 13
Mathematics · 4 marks · −1If are the distinct roots of the equation , then is equal to :
- A.2
- B.
- C.0
- D.1
Correct answer: D
Explanation: Roots are . , ; sum .
Question 14
Mathematics · 4 marks · −1PQR is a triangular park with m. A T.V. tower stands at the mid-point of QR. If the angles of elevation of the top of the tower at P, Q and R are respectively , and , then the height of the tower (in m) is :
- A.
- B.100
- C.50
- D.
Correct answer: B
Explanation: With tower height at midpoint T: , , and , so , .
Question 15
Mathematics · 4 marks · −1If and , then the standard deviation of the 9 items is :
- A.3
- B.9
- C.4
- D.2
Correct answer: D
Explanation: , .
Question 16
Mathematics · 4 marks · −1The sum of the co-efficients of all odd degree terms in the expansion of , is :
- A.2
- B.
- C.0
- D.1
Correct answer: A
Explanation: Sum . Odd-degree coefficients: .
Question 17
Mathematics · 4 marks · −1Tangents are drawn to the hyperbola at the points P and Q. If these tangents intersect at the point then the area (in sq. units) of is :
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: Chord of contact from : , meeting the hyperbola at . Area .
Question 18
Mathematics · 4 marks · −1From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary are to be selected and arranged in a row on a shelf so that the dictionary is always in the middle. The number of such arrangements is :
- A.at least 750 but less than 1000
- B.at least 1000
- C.less than 500
- D.at least 500 but less than 750
Correct answer: B
Explanation: .
Question 19
Mathematics · 4 marks · −1If the system of linear equations , , has a non-zero solution , then is equal to :
- A.30
- B.
- C.10
- D.
Correct answer: C
Explanation: Determinant zero gives . Solving with : , , so .
Question 20
Mathematics · 4 marks · −1If , then the ordered pair is equal to :
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Adding columns: . Comparing, , .
Question 21
Mathematics · 4 marks · −1Two sets A and B are as under : ; . Then :
- A.neither nor
- B.
- C.
- D. (an empty set)
Correct answer: C
Explanation: A is the open square , ; B is the ellipse . The square's farthest corners give , so .
Question 22
Mathematics · 4 marks · −1Tangent and normal are drawn at on the parabola , which intersect the axis of the parabola at A and B, respectively. If C is the centre of the circle through the points P, A and B and , then a value of is :
- A.
- B.
- C.2
- D.3
Correct answer: C
Explanation: , ; so C is the midpoint (the focus). , ; .
Question 23
Mathematics · 4 marks · −1Let . Then the set S is equal to :
- A.
- B. (an empty set)
- C.
- D.
Correct answer: B
Explanation: Near 0, ; near , . Both are differentiable, so S is empty.
Question 24
Mathematics · 4 marks · −1The Boolean expression is equivalent to :
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: .
Question 25
Mathematics · 4 marks · −1A straight line through a fixed point intersects the coordinate axes at distinct points P and Q. If O is the origin and the rectangle OPRQ is completed, then the locus of R is :
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Line through : , and , giving .
Question 26
Mathematics · 4 marks · −1Let A be the sum of the first 20 terms and B be the sum of the first 40 terms of the series . If , then is equal to :
- A.496
- B.232
- C.248
- D.464
Correct answer: C
Explanation: For even , : , , , .
Question 27
Mathematics · 4 marks · −1Let be the solution of the differential equation , . If , then is equal to :
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: . At : , .
Question 28
Mathematics · 4 marks · −1The length of the projection of the line segment joining the points and on the plane, is :
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: , ; component along normal . Projection .
Question 29
Mathematics · 4 marks · −1Let . Then S :
- A.contains exactly four elements
- B.is an empty set
- C.contains exactly one element
- D.contains exactly two elements
Correct answer: D
Explanation: With : for , ; for , . So .
Question 30
Mathematics · 4 marks · −1Let be in A.P. such that and . If , then is equal to :
- A.33
- B.66
- C.68
- D.34
Correct answer: D
Explanation: ; . So , ; .
Question 31
Physics · 4 marks · −1Three concentric metal shells A, B and C of respective radii a, b and c have surface charge densities , and respectively. The potential of shell B is :
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: .
Question 32
Physics · 4 marks · −1Seven identical circular planar disks, each of mass M and radius R are welded symmetrically as shown. The moment of inertia of the arrangement about the axis normal to the plane and passing through the point P is :

- A.
- B.
- C.
- D.
Correct answer: A
Explanation: About O: . P is at from O: add , total .
Question 33
Physics · 4 marks · −1From a uniform circular disc of radius R and mass 9M, a small disc of radius is removed as shown in the figure. The moment of inertia of the remaining disc about an axis perpendicular to the plane of the disc and passing through centre of disc is :

- A.
- B.
- C.
- D.
Correct answer: B
Explanation: Removed disc has mass M (area ratio 1/9), centre at : . Remaining .
Question 34
Physics · 4 marks · −1The reading of the ammeter for a silicon diode in the given circuit is :

- A.13.5 mA
- B.0
- C.15 mA
- D.11.5 mA
Correct answer: D
Explanation: Diode is forward biased; silicon drop 0.7 V. mA.
Question 35
Physics · 4 marks · −1Unpolarized light of intensity I passes through an ideal polarizer A. Another identical polarizer B is placed behind A. The intensity of light beyond B is found to be . Now another identical polarizer C is placed between A and B. The intensity beyond B is now found to be . The angle between polarizer A and C is :
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: A and B are parallel. With C at angle : , .
Question 36
Physics · 4 marks · −1For an RLC circuit driven with voltage of amplitude and frequency the current exhibits resonance. The quality factor, Q is given by :
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: (the only dimensionless option).
Question 37
Physics · 4 marks · −1Two masses kg and kg, connected by an inextensible string over a frictionless pulley, are moving as shown in the figure. The coefficient of friction of horizontal surface is 0.15. The minimum weight m that should be put on top of to stop the motion is :

- A.10.3 kg
- B.18.3 kg
- C.27.3 kg
- D.43.3 kg
Correct answer: C
Explanation: To stop: kg; smallest option satisfying it is 27.3 kg.
Question 38
Physics · 4 marks · −1In a collinear collision, a particle with an initial speed strikes a stationary particle of the same mass. If the final total kinetic energy is 50% greater than the original kinetic energy, the magnitude of the relative velocity between the two particles, after collision, is :
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: , ; .
Question 39
Physics · 4 marks · −1A particle is moving with a uniform speed in a circular orbit of radius R in a central force inversely proportional to the power of R. If the period of rotation of the particle is T, then :
- A.
- B. for any n.
- C.
- D.
Correct answer: D
Explanation: ; .
Question 40
Physics · 4 marks · −1Two batteries with e.m.f 12 V and 13 V are connected in parallel across a load resistor of . The internal resistances of the two batteries are and respectively. The voltage across the load lies between :
- A.11.7 V and 11.8 V
- B.11.6 V and 11.7 V
- C.11.5 V and 11.6 V
- D.11.4 V and 11.5 V
Correct answer: C
Explanation: V, . V.
Question 41
Physics · 4 marks · −1In an a.c. circuit, the instantaneous e.m.f. and current are given by , . In one cycle of a.c., the average power consumed by the circuit and the wattless current are, respectively :
- A.50, 0
- B.50, 10
- C., 10
- D., 0
Correct answer: C
Explanation: W; wattless current A.
Question 42
Physics · 4 marks · −1An EM wave from air enters a medium. The electric fields are in air and in medium, where the wave number k and frequency refer to their values in air. The medium is non-magnetic. If and refer to relative permittivities of air and medium respectively, which of the following options is correct ?
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Speed in medium is , so refractive index 2 and .
Question 43
Physics · 4 marks · −1A telephonic communication service is working at carrier frequency of 10 GHz. Only 10% of it is utilized for transmission. How many telephonic channels can be transmitted simultaneously if each channel requires a bandwidth of 5 kHz ?
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: .
Question 44
Physics · 4 marks · −1A granite rod of 60 cm length is clamped at its middle point and is set into longitudinal vibrations. The density of granite is kg/m and its Young's modulus is Pa. What will be the fundamental frequency of the longitudinal vibrations ?
- A.7.5 kHz
- B.5 kHz
- C.2.5 kHz
- D.10 kHz
Correct answer: B
Explanation: m/s; clamped at the middle, free ends: m, kHz kHz.
Question 45
Physics · 4 marks · −1It is found that if a neutron suffers an elastic collinear collision with deuterium at rest, fractional loss of its energy is ; while for its similar collision with carbon nucleus at rest, fractional loss of energy is . The values of and are respectively :
- A.(0, 1)
- B.(.89, .28)
- C.(.28, .89)
- D.(0, 0)
Correct answer: B
Explanation: Fractional loss : deuterium gives , carbon gives .
Question 46
Physics · 4 marks · −1The density of a material in the shape of a cube is determined by measuring three sides of the cube and its mass. If the relative errors in measuring the mass and length are respectively 1.5% and 1%, the maximum error in determining the density is:
- A.6%
- B.2.5%
- C.3.5%
- D.4.5%
Correct answer: D
Explanation: .
Question 47
Physics · 4 marks · −1Two moles of an ideal monoatomic gas occupies a volume V at C. The gas expands adiabatically to a volume 2V. Calculate (a) the final temperature of the gas and (b) change in its internal energy.
- A.(a) 195 K (b) 2.7 kJ
- B.(a) 189 K (b) 2.7 kJ
- C.(a) 195 K (b) kJ
- D.(a) 189 K (b) kJ
Correct answer: D
Explanation: K; kJ.
Question 48
Physics · 4 marks · −1A solid sphere of radius r made of a soft material of bulk modulus K is surrounded by a liquid in a cylindrical container. A massless piston of area a floats on the surface of the liquid, covering entire cross section of cylindrical container. When a mass m is placed on the surface of the piston to compress the liquid, the fractional decrement in the radius of the sphere, , is:
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Pressure ; .
Question 49
Physics · 4 marks · −1A parallel plate capacitor of capacitance 90 pF is connected to a battery of emf 20 V. If a dielectric material of dielectric constant is inserted between the plates, the magnitude of the induced charge will be :
- A.0.9 nC
- B.1.2 nC
- C.0.3 nC
- D.2.4 nC
Correct answer: B
Explanation: nC; induced charge nC.
Question 50
Physics · 4 marks · −1The dipole moment of a circular loop carrying a current I, is m and the magnetic field at the centre of the loop is . When the dipole moment is doubled by keeping the current constant, the magnetic field at the centre of the loop is . The ratio is:
- A.
- B.2
- C.
- D.
Correct answer: D
Explanation: so ; , so .
Question 51
Physics · 4 marks · −1An electron from various excited states of hydrogen atom emit radiation to come to the ground state. Let , be the de Broglie wavelength of the electron in the state and the ground state respectively. Let be the wavelength of the emitted photon in the transition from the state to the ground state. For large n, (A, B are constants)
- A.
- B.
- C.
- D.
Correct answer: B
Explanation: . .
Question 52
Physics · 4 marks · −1The mass of a hydrogen molecule is kg. If hydrogen molecules strike, per second, a fixed wall of area 2 cm at an angle of to the normal, and rebound elastically with a speed of m/s, then the pressure on the wall is nearly:
- A. N/m
- B. N/m
- C. N/m
- D. N/m
Correct answer: B
Explanation: Pa.
Question 53
Physics · 4 marks · −1All the graphs below are intended to represent the same motion. One of them does it incorrectly. Pick it up.

- A.Graph (1): velocity vs time
- B.Graph (2): velocity vs position
- C.Graph (3): distance vs time
- D.Graph (4): position vs time
Correct answer: C
Explanation: The motion is uniformly decelerated motion with non-zero initial velocity (velocity reverses). Graph (3) starts with zero slope, i.e. zero initial speed, which contradicts the others.
Question 54
Physics · 4 marks · −1An electron, a proton and an alpha particle having the same kinetic energy are moving in circular orbits of radii , , respectively in a uniform magnetic field B. The relation between , , is:
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: : proton , alpha , electron much smaller.
Question 55
Physics · 4 marks · −1On interchanging the resistances, the balance point of a meter bridge shifts to the left by 10 cm. The resistance of their series combination is . How much was the resistance on the left slot before interchanging the resistances?
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: and after swapping give cm; .
Question 56
Physics · 4 marks · −1In a potentiometer experiment, it is found that no current passes through the galvanometer when the terminals of the cell are connected across 52 cm of the potentiometer wire. If the cell is shunted by a resistance of , a balance is found when the cell is connected across 40 cm of the wire. Find the internal resistance of the cell.
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: .
Question 57
Physics · 4 marks · −1If the series limit frequency of the Lyman series is , then the series limit frequency of the Pfund series is:
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Series limit ; Pfund has , so .
Question 58
Physics · 4 marks · −1The angular width of the central maximum in a single slit diffraction pattern is . The width of the slit is m. The slit is illuminated by monochromatic plane waves. If another slit of same width is made near it, Young's fringes can be observed on a screen placed at a distance 50 cm from the slits. If the observed fringe width is 1 cm, what is slit separation distance? (i.e. distance between the centres of each slit.)
- A.m
- B.m
- C.m
- D.m
Correct answer: B
Explanation: m. m.
Question 59
Physics · 4 marks · −1A particle is moving in a circular path of radius a under the action of an attractive potential . Its total energy is:
- A.
- B.
- C.
- D.Zero
Correct answer: D
Explanation: (attractive), , KE , PE ; total zero.
Question 60
Physics · 4 marks · −1A silver atom in a solid oscillates in simple harmonic motion in some direction with a frequency of /sec. What is the force constant of the bonds connecting one atom with the other? (Mole wt. of silver = 108 and Avagadro number = gm mole)
- A.5.5 N/m
- B.6.4 N/m
- C.7.1 N/m
- D.2.2 N/m
Correct answer: C
Explanation: N/m.
Question 61
Chemistry · 4 marks · −1For 1 molal aqueous solution of the following compounds, which one will show the highest freezing point?
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: The non-ionising complex () gives the smallest depression, hence the highest freezing point.
Question 62
Chemistry · 4 marks · −1Hydrogen peroxide oxidises to in acidic medium but reduces to in alkaline medium. The other products formed are, respectively
- A. and
- B. and
- C. and
- D. and
Correct answer: D
Explanation: As oxidant, is reduced to ; as reductant in base it is oxidised to (with water).
Question 63
Chemistry · 4 marks · −1Which of the following compounds will be suitable for Kjeldahl's method for nitrogen estimation?

- A.Benzenediazonium chloride ()
- B.Pyridine
- C.Aniline ()
- D.Nitrobenzene ()
Correct answer: C
Explanation: Kjeldahl's method fails for nitro/azo/diazo compounds and ring nitrogen (pyridine); aniline is suitable.
Question 64
Chemistry · 4 marks · −1Glucose on prolonged heating with HI gives
- A.6-iodohexanal
- B.n-Hexane
- C.1-Hexene
- D.Hexanoic acid
Correct answer: B
Explanation: HI/heat reduces glucose completely to n-hexane, showing a straight six-carbon chain.
Question 65
Chemistry · 4 marks · −1An alkali is titrated against an acid with methyl orange as indicator, which of the following is a correct combination? (Base, Acid, End point)
- A.Strong, Strong, Pink to colourless
- B.Weak, Strong, Colourless to pink
- C.Strong, Strong, Pinkish red to yellow
- D.Weak, Strong, Yellow to pinkish red
Correct answer: D
Explanation: Methyl orange suits weak base vs strong acid; the alkaline (yellow) solution turns pinkish red at the end point as acid is added.
Question 66
Chemistry · 4 marks · −1The predominant form of histamine present in human blood is (, Histidine = 6.0)

- A.Imidazole ring neutral, side-chain amino group protonated ()
- B.Imidazole ring neutral, side-chain amino group neutral ()
- C.Imidazole ring protonated (imidazolium) and side-chain
- D.Imidazole ring protonated (imidazolium) and side-chain
Correct answer: A
Explanation: Blood pH 7.4 exceeds the ring (6.0), so the ring stays unprotonated; the aliphatic amine () is protonated.
Question 67
Chemistry · 4 marks · −1The increasing order of basicity of the following compounds is: (a) (b) (c) (d)

- A.(d) < (b) < (a) < (c)
- B.(a) < (b) < (c) < (d)
- C.(b) < (a) < (c) < (d)
- D.(b) < (a) < (d) < (c)
Correct answer: D
Explanation: The imine N (b) is least basic; the secondary amine (d) beats the allylic primary amine (a); the amidine (c) is most basic since its conjugate acid is resonance-stabilised.
Question 68
Chemistry · 4 marks · −1Which of the following lines correctly show the temperature dependence of equilibrium constant K, for an exothermic reaction?

- A.A and D
- B.A and B
- C.B and C
- D.C and D
Correct answer: B
Explanation: ; for the plot of vs has positive slope: lines A and B.
Question 69
Chemistry · 4 marks · −1How long (approximate) should water be electrolysed by passing through 100 amperes current so that the oxygen released can completely burn 27.66 g of diborane? (Atomic weight of B = 10.8 u)
- A.1.6 hours
- B.6.4 hours
- C.0.8 hours
- D.3.2 hours
Correct answer: D
Explanation: 27.66 g = 1 mol, needs 3 mol = 12 F. s h.
Question 70
Chemistry · 4 marks · −1Consider the following reaction and statements: . (I) Two isomers are produced if the reactant complex ion is a cis-isomer (II) Two isomers are produced if the reactant complex ion is a trans-isomer (III) Only one isomer is produced if the reactant complex ion is a trans-isomer (IV) Only one isomer is produced if the reactant complex ion is a cis-isomer. The correct statements are
- A.(II) and (IV)
- B.(I) and (II)
- C.(I) and (III)
- D.(III) and (IV)
Correct answer: C
Explanation: Replacing an in the cis isomer can give fac or mer; in the trans isomer every replacement gives the mer isomer.
Question 71
Chemistry · 4 marks · −1Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A reacts with to form product B. A and B are respectively:

- A.Methyl salicylate and methyl 2-bromo-6-hydroxybenzoate
- B.Methyl salicylate and methyl 4-bromo-2-hydroxybenzoate
- C.Methyl phenyl carbonate and 3-bromophenyl methyl carbonate
- D.Methyl phenyl carbonate and 4-bromophenyl methyl carbonate
Correct answer: D
Explanation: Phenoxide attacks the acyl chloride to give (A); the group is o,p-directing, bromination gives the para product (B).
Question 72
Chemistry · 4 marks · −1An aqueous solution contains an unknown concentration of . When 50 mL of a 1 M solution of is added, just begins to precipitate. The final volume is 500 mL. The solubility product of is . What is the original concentration of ?
- A. M
- B. M
- C. M
- D. M
Correct answer: D
Explanation: M in 500 mL, so M there; original (450 mL) M.
Question 73
Chemistry · 4 marks · −1At C the rate of decomposition of a sample of gaseous acetaldehyde initially at a pressure of 363 Torr, was 1.00 Torr s when 5% had reacted and 0.5 Torr s when 33% had reacted. The order of the reaction is
- A.0
- B.2
- C.3
- D.1
Correct answer: B
Explanation: .
Question 74
Chemistry · 4 marks · −1The combustion of benzene (l) gives (g) and (l). Given that heat of combustion of benzene at constant volume is kJ mol at C; heat of combustion (in kJ mol) of benzene at constant pressure will be ( JK mol)
- A.
- B.4152.6
- C.
- D.3260
Correct answer: A
Explanation: ; kJ/mol.
Question 75
Chemistry · 4 marks · −1The ratio of mass percent of C and H of an organic compound is 6 : 1. If one molecule of the above compound contains half as much oxygen as required to burn one molecule of compound completely to and . The empirical formula of compound is
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: C:H mass 6:1 gives mole ratio 1:2. O atoms needed to burn ; is half of that . For : , i.e. .
Question 76
Chemistry · 4 marks · −1The trans-alkenes are formed by the reduction of alkynes with
- A.Sn - HCl
- B. - Pd/C,
- C.
- D.Na/liq.
Correct answer: D
Explanation: Birch-type reduction with Na in liquid gives trans-alkenes (anti addition).
Question 77
Chemistry · 4 marks · −1When metal 'M' is treated with NaOH, a white gelatinous precipitate 'X' is obtained, which is soluble in excess of NaOH. Compound 'X' when heated strongly gives an oxide which is used in chromatography as an adsorbent. The metal 'M' is
- A.Fe
- B.Zn
- C.Ca
- D.Al
Correct answer: D
Explanation: is white, gelatinous and amphoteric (dissolves as ); ignition gives , a chromatography adsorbent.
Question 78
Chemistry · 4 marks · −1According to molecular orbital theory, which of the following will not be a viable molecule?
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: Bond orders: 0, 1, 0.5, 0.5. Zero bond order is not viable.
Question 79
Chemistry · 4 marks · −1The major product formed in the following reaction is: 1-(1-methoxyethyl)-2-ethoxybenzene (a benzene ring bearing and, ortho to it, ) ?

- A.2-(1-iodoethyl)phenol (ring with and ortho )
- B.2-(1-hydroxyethyl)phenol (ring with and ortho )
- C.1-iodo-2-(1-iodoethyl)benzene (ring with and ortho )
- D.1-(2-iodophenyl)ethanol (ring with and ortho )
Correct answer: A
Explanation: The aryl ether cleaves to phenol + (aryl C-O is not broken). The benzylic ether cleaves via a stable benzylic carbocation, which takes to give the benzylic iodide.
Question 80
Chemistry · 4 marks · −1Phenol on treatment with in the presence of NaOH followed by acidification produces compound X as the major product. X on treatment with in the presence of catalytic amount of produces:

- A.4-acetoxybenzene-1,3-dicarboxylic acid (acetylated 4-hydroxyisophthalic acid)
- B.2-acetoxybenzoic acid (aspirin)
- C.4-acetoxybenzoic acid
- D.Salicylic acid mixed anhydride with acetic acid (2-hydroxybenzoyl acetate)
Correct answer: B
Explanation: Kolbe reaction gives salicylic acid (X); acetylation of its OH gives acetylsalicylic acid (aspirin).
Question 81
Chemistry · 4 marks · −1Which of the following compounds contain(s) no covalent bond(s)? , , , ,
- A.,
- B., ,
- C.,
- D.
Correct answer: D
Explanation: Only KCl is purely ionic; the others contain covalent bonds.
Question 82
Chemistry · 4 marks · −1Which type of 'defect' has the presence of cations in the interstitial sites?
- A.Metal deficiency defect
- B.Schottky defect
- C.Vacancy defect
- D.Frenkel defect
Correct answer: D
Explanation: In a Frenkel defect the (smaller) cation leaves its site and occupies an interstitial site.
Question 83
Chemistry · 4 marks · −1The major product of the following reaction is: 2-bromo-1,1-dimethylcyclohexane (Br on the carbon adjacent to the gem-dimethyl carbon, drawn with a wedge) ?

- A.2-methoxy-1,1-dimethylcyclohexane (OMe on a hashed bond)
- B.2-methoxy-1,1-dimethylcyclohexane (OMe on a wedged bond)
- C.3,3-dimethylcyclohexene
- D.1,2-dimethylcyclohexene
Correct answer: C
Explanation: Strong base/nucleophile on a hindered secondary halide: E2. The only -H is on C3 (C1 is quaternary), giving 3,3-dimethylcyclohexene.
Question 84
Chemistry · 4 marks · −1The compound that does not produce nitrogen gas by the thermal decomposition is
- A.
- B.
- C.
- D.
Correct answer: A
Explanation: gives (and ); the others release .
Question 85
Chemistry · 4 marks · −1An aqueous solution contains 0.10 M and 0.20 M HCl. If the equilibrium constants for the formation of from is and that of from ions is then the concentration of ions in aqueous solution is
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: M.
Question 86
Chemistry · 4 marks · −1The oxidation states of Cr in , and respectively are:
- A.+3, 0 and +4
- B.+3, +4 and +6
- C.+3, +2 and +4
- D.+3, 0 and +6
Correct answer: D
Explanation: +3; 0 (neutral benzene); in the last, (2 CN, 2 oxide, 1 peroxide) gives .
Question 87
Chemistry · 4 marks · −1The recommended concentration of fluoride ion in drinking water is up to 1 ppm as fluoride ion is required to make teeth enamel harder by converting to
- A.
- B.
- C.
- D.
Correct answer: D
Explanation: Fluoride replaces hydroxide in hydroxyapatite to form fluorapatite .
Question 88
Chemistry · 4 marks · −1Which of the following salts is the most basic in aqueous solution?
- A.
- B.
- C.
- D.
Correct answer: C
Explanation: is a salt of a strong base and weak acid, so its solution is basic; the others involve weak-base cations.
Question 89
Chemistry · 4 marks · −1Total number of lone pair of electrons in ion is
- A.12
- B.3
- C.6
- D.9
Correct answer: D
Explanation: Central I has 3 lone pairs, each terminal I has 3: total 9.