JEE Main 2019 — 10 Apr Shift 1 (Previous Year Paper)

JEE Main · 2019 · with answers and explanations

questions
88
Total marks
352
Duration
180 minutes
Negative marking
−1

Subjects: Physics · Chemistry · Mathematics

Question 1

Physics · 4 marks · −1

Given below in the left column are different modes of communication using the kinds of waves given in the right column. A. Optical Fibre Communication — P. Ultrasound B. Radar — Q. Infrared Light C. Sonar — R. Microwaves D. Mobile Phones — S. Radio Waves From the options given below, find the most appropriate match between entries in the left and the right column.

  1. A.A-Q, B-S, C-R, D-P
  2. B.A-Q, B-S, C-P, D-R
  3. C.A-S, B-Q, C-R, D-P
  4. D.A-R, B-P, C-S, D-Q

Correct answer: B

Question 2

Physics · 4 marks · −1

In an experiment, the resistance of a material is plotted as a function of temperature (in some range). As shown in the figure, it is a straight line. One may conclude that:

Figure for question 2
  1. A.R(T)=R0T2R(T)=\frac{R_0}{T^2}
  2. B.R(T)=R0e−T2/T02R(T)=R_0e^{-T^2/T_0^2}
  3. C.R(T)=R0e−T02/T2R(T)=R_0e^{-T_0^2/T^2}
  4. D.R(T)=R0eT2/T02R(T)=R_0e^{T^2/T_0^2}

Correct answer: C

Question 3

Physics · 4 marks · −1

A particle of mass mm is moving along a trajectory given by x=x0+acos⁡ω1tx=x_0+a\cos\omega_1 t y=y0+bsin⁡ω2ty=y_0+b\sin\omega_2 t The torque, acting on the particle about the origin, at t=0t=0 is:

  1. A.+my0aω12k^+my_0a\omega_1^2\hat{k}
  2. B.m(−x0b+y0a)ω12k^m(-x_0b+y_0a)\omega_1^2\hat{k}
  3. C.−m(x0bω22−y0aω12)k^-m(x_0b\omega_2^2-y_0a\omega_1^2)\hat{k}
  4. D.Zero

Correct answer: A

Question 4

Physics · 4 marks · −1

A ball is thrown upward with an initial velocity V0V_0 from the surface of the earth. The motion of the ball is affected by a drag force equal to mγv2m\gamma v^2 (where mm is mass of the ball, vv is its instantaneous velocity and γ\gamma is a constant). Time taken by the ball to rise to its zenith is:

  1. A.12γgtan⁡−1(2γgV0)\frac{1}{\sqrt{2\gamma g}}\tan^{-1}\left(\sqrt{\frac{2\gamma}{g}}V_0\right)
  2. B.1γgln⁡(1+γgV0)\frac{1}{\sqrt{\gamma g}}\ln\left(1+\sqrt{\frac{\gamma}{g}}V_0\right)
  3. C.1γgtan⁡−1(γgV0)\frac{1}{\sqrt{\gamma g}}\tan^{-1}\left(\sqrt{\frac{\gamma}{g}}V_0\right)
  4. D.1γgsin⁡−1(γgV0)\frac{1}{\sqrt{\gamma g}}\sin^{-1}\left(\sqrt{\frac{\gamma}{g}}V_0\right)

Correct answer: C

Question 5

Physics · 4 marks · −1

Two particles, of masses MM and 2M2M, moving, as shown, with speeds of 10 m/s and 5 m/s, collide elastically at the origin. After the collision, they move along the indicated directions with speeds v1v_1 and v2v_2, respectively. The values of v1v_1 and v2v_2 are nearly:

Figure for question 5
  1. A.6.5 m/s and 3.2 m/s
  2. B.3.2 m/s and 12.6 m/s
  3. C.6.5 m/s and 6.3 m/s
  4. D.3.2 m/s and 6.3 m/s

Correct answer: C

Question 6

Physics · 4 marks · −1

Two coaxial discs, having moments of inertia I1I_1 and I12\frac{I_1}{2}, are rotating with respective angular velocities ω1\omega_1 and ω12\frac{\omega_1}{2}, about their common axis. They are brought in contact with each other and thereafter they rotate with a common angular velocity. If EfE_f and EiE_i are the final and initial total energies, then (Ef−Ei)(E_f-E_i) is:

  1. A.−I1ω1212-\frac{I_1\omega_1^2}{12}
  2. B.−I1ω1224-\frac{I_1\omega_1^2}{24}
  3. C.I1ω126\frac{I_1\omega_1^2}{6}
  4. D.38I1ω12\frac{3}{8}I_1\omega_1^2

Correct answer: B

Question 7

Physics · 4 marks · −1

A thin disc of mass MM and radius RR has mass per unit area σ(r)=kr2\sigma(r)=kr^2 where rr is the distance from its centre. Its moment of inertia about an axis going through its centre of mass and perpendicular to its plane is:

  1. A.MR26\frac{MR^2}{6}
  2. B.2MR23\frac{2MR^2}{3}
  3. C.MR22\frac{MR^2}{2}
  4. D.MR23\frac{MR^2}{3}

Correct answer: B

Question 8

Physics · 4 marks · −1

The value of acceleration due to gravity at Earth's surface is 9.8 ms−29.8\ \text{ms}^{-2}. The altitude above its surface at which the acceleration due to gravity decreases to 4.9 ms−24.9\ \text{ms}^{-2}, is close to: (Radius of earth =6.4×106=6.4\times10^6 m)

  1. A.2.6×1062.6\times10^6 m
  2. B.6.4×1066.4\times10^6 m
  3. C.1.6×1061.6\times10^6 m
  4. D.9.0×1069.0\times10^6 m

Correct answer: A

Question 9

Physics · 4 marks · −1

The ratio of surface tensions of mercury and water is given to be 7.5 while the ratio of their densities is 13.6. Their contact angles, with glass, are close to 135° and 0°, respectively. It is observed that mercury gets depressed by an amount hh in a capillary tube of radius r1r_1, while water rises by the same amount hh in a capillary tube of radius r2r_2. The ratio, (r1/r2)(r_1/r_2), is then close to:

  1. A.2/5
  2. B.4/5
  3. C.2/3
  4. D.3/5

Correct answer: A

Question 10

Physics · 4 marks · −1

nn moles of an ideal gas with constant volume heat capacity CVC_V undergo an isobaric expansion by certain volume. The ratio of the work done in the process, to the heat supplied is:

  1. A.4nRCV−nR\frac{4nR}{C_V-nR}
  2. B.nRCV−nR\frac{nR}{C_V-nR}
  3. C.4nRCV+nR\frac{4nR}{C_V+nR}
  4. D.nRCV+nR\frac{nR}{C_V+nR}

Correct answer: D

Question 11

Physics · 4 marks · −1

The displacement of a damped harmonic oscillator is given by x(t)=e−0.1tcos⁡(10πt+φ)x(t)=e^{-0.1t}\cos(10\pi t+\varphi). Here tt is in seconds. The time taken for its amplitude of vibration to drop to half of its initial value is close to:

  1. A.4 s
  2. B.27 s
  3. C.7 s
  4. D.13 s

Correct answer: C

Question 12

Physics · 4 marks · −1

A stationary source emits sound waves of frequency 500 Hz. Two observers moving along a line passing through the source detect sound to be of frequencies 480 Hz and 530 Hz. Their respective speeds are, in ms−1\text{ms}^{-1}, (Given speed of sound =300=300 m/s)

  1. A.12, 18
  2. B.16, 14
  3. C.8, 18
  4. D.12, 16

Correct answer: A

Question 13

Physics · 4 marks · −1

Figure shows charge (qq) versus voltage (VV) graph for series and parallel combination of two given capacitors. The capacitances are:

Figure for question 13
  1. A.50 μ\muF and 30 μ\muF
  2. B.20 μ\muF and 30 μ\muF
  3. C.40 μ\muF and 10 μ\muF
  4. D.60 μ\muF and 40 μ\muF

Correct answer: C

Question 14

Physics · 4 marks · −1

A cylinder with fixed capacity of 67.2 lit contains helium gas at STP. The amount of heat needed to raise the temperature of the gas by 20°C is: [Given that R=8.31 J mol−1K−1R=8.31\ \text{J mol}^{-1}\text{K}^{-1}]

  1. A.700 J
  2. B.748 J
  3. C.374 J
  4. D.350 J

Correct answer: B

Question 15

Physics · 4 marks · −1

A uniformly charged ring of radius 3a3a and total charge qq is placed in xyxy-plane centred at origin. A point charge qq is moving towards the ring along the zz-axis and has speed vv at z=4az=4a. The minimum value of vv such that it crosses the origin is:

  1. A.2m(115q24πϵ0a)1/2\sqrt{\frac{2}{m}}\left(\frac{1}{15}\frac{q^2}{4\pi\epsilon_0 a}\right)^{1/2}
  2. B.2m(215q24πϵ0a)1/2\sqrt{\frac{2}{m}}\left(\frac{2}{15}\frac{q^2}{4\pi\epsilon_0 a}\right)^{1/2}
  3. C.2m(15q24πϵ0a)1/2\sqrt{\frac{2}{m}}\left(\frac{1}{5}\frac{q^2}{4\pi\epsilon_0 a}\right)^{1/2}
  4. D.2m(415q24πϵ0a)1/2\sqrt{\frac{2}{m}}\left(\frac{4}{15}\frac{q^2}{4\pi\epsilon_0 a}\right)^{1/2}

Correct answer: B

Question 16

Physics · 4 marks · −1

In the given circuit, an ideal voltmeter connected across the 10 Ω\Omega resistance reads 2 V. The internal resistance rr, of each cell is:

Figure for question 16
  1. A.1 Ω\Omega
  2. B.1.5 Ω\Omega
  3. C.0.5 Ω\Omega
  4. D.0 Ω\Omega

Correct answer: C

Question 17

Physics · 4 marks · −1

A current of 5 A passes through a copper conductor (resistivity =1.7×10−8 Ω=1.7\times10^{-8}\ \Omegam) of radius of cross-section 5 mm. Find the mobility of the charges if their drift velocity is 1.1×10−31.1\times10^{-3} m/s.

  1. A.1.5 m2^2/Vs
  2. B.1.8 m2^2/Vs
  3. C.1.0 m2^2/Vs
  4. D.1.3 m2^2/Vs

Correct answer: C

Question 18

Physics · 4 marks · −1

A proton, an electron, and a Helium nucleus, have the same energy. They are in circular orbits in a plane due to magnetic field perpendicular to the plane. Let rpr_p, rer_e and rHer_{He} be their respective radii, then,

  1. A.re<rp<rHer_e<r_p<r_{He}
  2. B.re>rp>rHer_e>r_p>r_{He}
  3. C.re>rp=rHer_e>r_p=r_{He}
  4. D.re<rp=rHer_e<r_p=r_{He}

Correct answer: D

Question 19

Physics · 4 marks · −1

Two wires A & B are carrying currents I1I_1 & I2I_2 as shown in the figure. The separation between them is dd. A third wire C carrying a current II is to be kept parallel to them at a distance xx from A such that the net force acting on it is zero. The possible values of xx are:

Figure for question 19
  1. A.x=±I1d(I1−I2)x=\pm\frac{I_1d}{(I_1-I_2)}
  2. B.x=(I1I1+I2)dx=\left(\frac{I_1}{I_1+I_2}\right)d and x=I2(I1−I2)dx=\frac{I_2}{(I_1-I_2)}d
  3. C.x=(I1I1−I2)dx=\left(\frac{I_1}{I_1-I_2}\right)d and x=I2(I1+I2)dx=\frac{I_2}{(I_1+I_2)}d
  4. D.x=(I2I1+I2)dx=\left(\frac{I_2}{I_1+I_2}\right)d and x=(I2I1−I2)dx=\left(\frac{I_2}{I_1-I_2}\right)d

Correct answer: A

Question 20

Physics · 4 marks · −1

A transformer consisting of 300 turns in the primary and 150 turns in the secondary gives output power of 2.2 kW. If the current in the secondary coil is 10 A, then the input voltage and current in the primary coil are:

  1. A.440 V and 20 A
  2. B.220 V and 10 A
  3. C.440 V and 5 A
  4. D.220 V and 20 A

Correct answer: C

Question 21

Physics · 4 marks · −1

The electric field of a plane electromagnetic wave is given by E⃗=E0i^cos⁡(kz)cos⁡(ωt)\vec{E}=E_0\hat{i}\cos(kz)\cos(\omega t) The corresponding magnetic field B⃗\vec{B} is then given by:

  1. A.B⃗=E0Cj^sin⁡(kz)sin⁡(ωt)\vec{B}=\frac{E_0}{C}\hat{j}\sin(kz)\sin(\omega t)
  2. B.B⃗=E0Cj^sin⁡(kz)cos⁡(ωt)\vec{B}=\frac{E_0}{C}\hat{j}\sin(kz)\cos(\omega t)
  3. C.B⃗=E0Cj^cos⁡(kz)sin⁡(ωt)\vec{B}=\frac{E_0}{C}\hat{j}\cos(kz)\sin(\omega t)
  4. D.B⃗=E0Ck^sin⁡(kz)cos⁡(ωt)\vec{B}=\frac{E_0}{C}\hat{k}\sin(kz)\cos(\omega t)

Correct answer: A

Question 22

Physics · 4 marks · −1

One plano-convex and one plano-concave lens of same radius of curvature 'RR' but of different materials are joined side by side as shown in the figure. If the refractive index of the material of 1 is μ1\mu_1 and that of 2 is μ2\mu_2, then the focal length of the combination is:

Figure for question 22
  1. A.Rμ1−μ2\frac{R}{\mu_1-\mu_2}
  2. B.2Rμ1−μ2\frac{2R}{\mu_1-\mu_2}
  3. C.R2(μ1−μ2)\frac{R}{2(\mu_1-\mu_2)}
  4. D.R2−(μ1−μ2)\frac{R}{2-(\mu_1-\mu_2)}

Correct answer: A

Question 23

Physics · 4 marks · −1

A ray of light AO in vacuum is incident on a glass slab at angle 60° and refracted at angle 30° along OB as shown in the figure. The optical path length of light ray from A to B is:

Figure for question 23
  1. A.2a+2b32a+\frac{2b}{\sqrt3}
  2. B.23a+2b\frac{2\sqrt3}{a}+2b
  3. C.2a+2b2a+2b
  4. D.2a+2b32a+\frac{2b}{3}

Correct answer: C

Question 24

Physics · 4 marks · −1

In a photoelectric effect experiment the threshold wavelength of light is 380 nm. If the wavelength of incident light is 260 nm, the maximum kinetic energy of emitted electrons will be: Given E (in eV)=1237λ (in nm)E\ (\text{in eV})=\frac{1237}{\lambda\ (\text{in nm})}

  1. A.3.0 eV
  2. B.4.5 eV
  3. C.15.1 eV
  4. D.1.5 eV

Correct answer: D

Question 25

Physics · 4 marks · −1

Two radioactive materials A and B have decay constants 10λ10\lambda and λ\lambda, respectively. If initially they have the same number of nuclei, then the ratio of the number of nuclei of A to that of B will be 1/e1/e after a time:

  1. A.110λ\frac{1}{10\lambda}
  2. B.111λ\frac{1}{11\lambda}
  3. C.1110λ\frac{11}{10\lambda}
  4. D.19λ\frac{1}{9\lambda}

Correct answer: D

Question 26

Physics · 4 marks · −1

An npn transistor operates as a common emitter amplifier, with a power gain of 60 dB. The input circuit resistance is 100 Ω\Omega and the output load resistance is 10 kΩ\Omega. The common emitter current gain β\beta is:

  1. A.6×1026\times10^2
  2. B.60
  3. C.10210^2
  4. D.10410^4

Correct answer: C

Question 27

Physics · 4 marks · −1

A message signal of frequency 100 MHz and peak voltage 100 V is used to execute amplitude modulation on a carrier wave of frequency 300 GHz and peak voltage 400 V. The modulation index and difference between the two side band frequencies are:

  1. A.0.25 ; 1×1081\times10^8 Hz
  2. B.4 ; 2×1082\times10^8 Hz
  3. C.0.25 ; 2×1082\times10^8 Hz
  4. D.4 ; 1×1081\times10^8 Hz

Correct answer: C

Question 28

Physics · 4 marks · −1

In a meter bridge experiment, the circuit diagram and the corresponding observation table are shown in figure. Sl. No. 1: R = 1000 Ω\Omega, ll = 60 cm Sl. No. 2: R = 100 Ω\Omega, ll = 13 cm Sl. No. 3: R = 10 Ω\Omega, ll = 1.5 cm Sl. No. 4: R = 1 Ω\Omega, ll = 1.0 cm Which of the readings is inconsistent?

Figure for question 28
  1. A.1
  2. B.2
  3. C.3
  4. D.4

Correct answer: D

Explanation: With R in the left gap, X=R(100−l)/lX=R(100-l)/l gives about 667, 669, 657 and 99 Ω\Omega for readings 1–4; reading 4 is inconsistent.

Question 29

Chemistry · 4 marks · −1

The increasing order of the reactivity of the following compounds towards electrophilic aromatic substitution reactions is: (I) chlorobenzene, (II) toluene, (III) acetophenone

Figure for question 29
  1. A.II < I < III
  2. B.I < III < II
  3. C.III < I < II
  4. D.III < II < I

Correct answer: C

Question 30

Chemistry · 4 marks · −1

Major products of the following reaction are: Benzaldehyde (C6H5CHOC_6H_5CHO) + HCHO →(i) 50% NaOH; (ii) H3O+\xrightarrow{\text{(i) 50\% NaOH; (ii) }H_3O^+}

Figure for question 30
  1. A.CH3OHCH_3OH and benzoic acid (C6H5COOHC_6H_5COOH)
  2. B.HCOOH and benzyl alcohol (C6H5CH2OHC_6H_5CH_2OH)
  3. C.Benzyl alcohol (C6H5CH2OHC_6H_5CH_2OH) and benzoic acid (C6H5COOHC_6H_5COOH)
  4. D.CH3OHCH_3OH and HCO2HHCO_2H

Correct answer: B

Question 31

Chemistry · 4 marks · −1

Amylopectin is composed of:

  1. A.α\alpha-D-glucose, C1−C4C_1-C_4 and C2−C6C_2-C_6 linkages
  2. B.β\beta-D-glucose, C1−C4C_1-C_4 and C1−C6C_1-C_6 linkages
  3. C.α\alpha-D-glucose, C1−C4C_1-C_4 and C1−C6C_1-C_6 linkages
  4. D.β\beta-D-glucose, C1−C4C_1-C_4 and C2−C6C_2-C_6 linkages

Correct answer: C

Question 32

Chemistry · 4 marks · −1

The principle of column chromatography is:

  1. A.Differential adsorption of the substances on the solid phase.
  2. B.Differential absorption of the substances on the solid phase.
  3. C.Capillary action.
  4. D.Gravitational force.

Correct answer: A

Question 33

Chemistry · 4 marks · −1

Increasing rate of SN1S_N1 reaction in the following compounds is: (A) 1-iodo-1-phenylethane; (B) 1-iodo-1-(3-methoxyphenyl)ethane; (C) 1-iodo-1-(4-methylphenyl)ethane; (D) 1-iodo-1-(4-methoxyphenyl)ethane

Figure for question 33
  1. A.(B) < (A) < (D) < (C)
  2. B.(B) < (A) < (C) < (D)
  3. C.(A) < (B) < (C) < (D)
  4. D.(A) < (B) < (D) < (C)

Correct answer: B

Question 34

Chemistry · 4 marks · −1

Ethylamine (C2H5NH2C_2H_5NH_2) can be obtained from N-ethylphthalimide on treatment with:

  1. A.CaH2CaH_2
  2. B.NaBH4NaBH_4
  3. C.H2OH_2O
  4. D.NH2NH2NH_2NH_2

Correct answer: D

Question 35

Chemistry · 4 marks · −1

The major product of the following reaction is: 3-Methoxyphenyl–CH(CN)–O–CH(CH3_3)2_2 (the benzylic carbon carries a CN group and an isopropoxy group; the ring carries OCH3_3 meta to it) →ΔHI (excess)\xrightarrow[\Delta]{\text{HI (excess)}}

Figure for question 35
  1. A.3-Hydroxyphenyl–CH(OH)–CN (ring OH, benzylic OH)
  2. B.3-Hydroxyphenyl–CH(I)–CN (ring OH, benzylic I)
  3. C.3-Iodophenyl–CH(OH)–CN (ring I, benzylic OH)
  4. D.3-Iodophenyl–CH(I)–CN (ring I, benzylic I)

Correct answer: B

Question 36

Chemistry · 4 marks · −1

The major product of the following reaction is: CH3−CH(CH3)−CH(Br)−CH3→CH3OHCH_3-CH(CH_3)-CH(Br)-CH_3 \xrightarrow{CH_3OH}

  1. A.CH3−CH(CH3)−CH(OCH3)−CH3CH_3-CH(CH_3)-CH(OCH_3)-CH_3
  2. B.CH3−C(CH3)=CH−CH3CH_3-C(CH_3)=CH-CH_3
  3. C.CH3−C(CH3)(OCH3)−CH2CH3CH_3-C(CH_3)(OCH_3)-CH_2CH_3
  4. D.CH3−CH(CH3)−CH=CH2CH_3-CH(CH_3)-CH=CH_2

Correct answer: C

Question 37

Chemistry · 4 marks · −1

Which of the following is a condensation polymer?

  1. A.Buna - S
  2. B.Nylon 6, 6
  3. C.Teflon
  4. D.Neoprene

Correct answer: B

Question 38

Chemistry · 4 marks · −1

The major product of the following reaction is: CH3CH(OH)CH2CH2NH2→triethylamineethyl formate (1 equiv.)CH_3CH(OH)CH_2CH_2NH_2 \xrightarrow[\text{triethylamine}]{\text{ethyl formate (1 equiv.)}}

  1. A.CH3CH(OCHO)CH2CH2NH2CH_3CH(OCHO)CH_2CH_2NH_2 (O-formyl ester)
  2. B.CH3CH(OH)CH2CH2NHCHOCH_3CH(OH)CH_2CH_2NHCHO
  3. C.CH3CH=CH−CH2NH2CH_3CH=CH-CH_2NH_2
  4. D.CH3−CH(OH)−CH=CH2CH_3-CH(OH)-CH=CH_2

Correct answer: B

Question 39

Chemistry · 4 marks · −1

The isoelectronic set of ions is:

  1. A.N3−N^{3-}, O2−O^{2-}, F−F^- and Na+Na^+
  2. B.Li+Li^+, Na+Na^+, O2−O^{2-} and F−F^-
  3. C.N3−N^{3-}, Li+Li^+, Mg2+Mg^{2+} and O2−O^{2-}
  4. D.F−F^-, Li+Li^+, Na+Na^+ and Mg2+Mg^{2+}

Correct answer: A

Question 40

Chemistry · 4 marks · −1

Match the refining methods (Column I) with metals (Column II). Column I (Refining methods): (I) Liquation (II) Zone Refining (III) Mond Process (IV) Van Arkel Method Column II (Metals): (a) Zr (b) Ni (c) Sn (d) Ga

  1. A.(I)-(c); (II)-(a); (III)-(b); (IV)-(d)
  2. B.(I)-(c); (II)-(d); (III)-(b); (IV)-(a)
  3. C.(I)-(b); (II)-(c); (III)-(d); (IV)-(a)
  4. D.(I)-(b); (II)-(d); (III)-(a); (IV)-(c)

Correct answer: B

Question 41

Chemistry · 4 marks · −1

The synonym for water gas when used in the production of methanol is:

  1. A.fuel gas
  2. B.natural gas
  3. C.laughing gas
  4. D.syn gas

Correct answer: D

Question 42

Chemistry · 4 marks · −1

The alloy used in the construction of aircrafts is:

  1. A.Mg - Al
  2. B.Mg - Sn
  3. C.Mg - Zn
  4. D.Mg - Mn

Correct answer: A

Question 43

Chemistry · 4 marks · −1

The oxoacid of sulphur that does not contain bond between sulphur atoms is:

  1. A.H2S2O4H_2S_2O_4
  2. B.H2S4O6H_2S_4O_6
  3. C.H2S2O3H_2S_2O_3
  4. D.H2S2O7H_2S_2O_7

Correct answer: D

Question 44

Chemistry · 4 marks · −1

The correct order of catenation is:

  1. A.Si > Sn > C > Ge
  2. B.Ge > Sn > Si > C
  3. C.C > Si > Ge ≈\approx Sn
  4. D.C > Sn > Si ≈\approx Ge

Correct answer: C

Question 45

Chemistry · 4 marks · −1

Consider the hydrated ions of Ti2+Ti^{2+}, V2+V^{2+}, Ti3+Ti^{3+}, and Sc3+Sc^{3+}. The correct order of their spin-only magnetic moments is:

  1. A.Sc3+<Ti3+<Ti2+<V2+Sc^{3+}<Ti^{3+}<Ti^{2+}<V^{2+}
  2. B.Ti3+<Ti2+<Sc3+<V2+Ti^{3+}<Ti^{2+}<Sc^{3+}<V^{2+}
  3. C.Sc3+<Ti3+<V2+<Ti2+Sc^{3+}<Ti^{3+}<V^{2+}<Ti^{2+}
  4. D.V2+<Ti2+<Ti3+<Sc3+V^{2+}<Ti^{2+}<Ti^{3+}<Sc^{3+}

Correct answer: A

Question 46

Chemistry · 4 marks · −1

Three complexes, [CoCl(NH3)5]2+[CoCl(NH_3)_5]^{2+} (I), [Co(NH3)5H2O]3+[Co(NH_3)_5H_2O]^{3+} (II) and [Co(NH3)6]3+[Co(NH_3)_6]^{3+} (III) absorb light in the visible region. The correct order of the wavelength of light absorbed by them is:

  1. A.(II) > (I) > (III)
  2. B.(I) > (II) > (III)
  3. C.(III) > (I) > (II)
  4. D.(III) > (II) > (I)

Correct answer: B

Question 47

Chemistry · 4 marks · −1

The species that can have a trans-isomer is: (en = ethane-1, 2-diamine, ox = oxalate)

  1. A.[Pt(en)Cl2][Pt(en)Cl_2]
  2. B.[Zn(en)Cl2][Zn(en)Cl_2]
  3. C.[Cr(en)2(ox)]+[Cr(en)_2(ox)]^+
  4. D.[Pt(en)2Cl2]2+[Pt(en)_2Cl_2]^{2+}

Correct answer: D

Question 48

Chemistry · 4 marks · −1

The regions of the atmosphere, where clouds form and where we live, respectively, are:

  1. A.Troposphere and Troposphere
  2. B.Troposphere and Stratosphere
  3. C.Stratosphere and Troposphere
  4. D.Stratosphere and Stratosphere

Correct answer: A

Question 49

Chemistry · 4 marks · −1

At 300 K and 1 atmospheric pressure, 10 mL of a hydrocarbon required 55 mL of O2O_2 for complete combustion, and 40 mL of CO2CO_2 is formed. The formula of the hydrocarbon is:

  1. A.C4H6C_4H_6
  2. B.C4H8C_4H_8
  3. C.C4H10C_4H_{10}
  4. D.C4H7ClC_4H_7Cl

Correct answer: A

Question 50

Chemistry · 4 marks · −1

Consider the following table: Gas A: a=642.32a=642.32 kPa dm6^6 mol−1^{-1}, b=0.05196b=0.05196 dm3^3 mol−1^{-1} Gas B: a=155.21a=155.21, b=0.04136b=0.04136 Gas C: a=431.91a=431.91, b=0.05196b=0.05196 Gas D: a=155.21a=155.21, b=0.4382b=0.4382 aa and bb are van der Waals constants. The correct statement about the gases is:

  1. A.Gas C will occupy lesser volume than gas A; gas B will be more compressible than gas D
  2. B.Gas C will occupy more volume than gas A; gas B will be lesser compressible than gas D
  3. C.Gas C will occupy more volume than gas A; gas B will be more compressible than gas D
  4. D.Gas C will occupy lesser volume than gas A; gas B will be lesser compressible than gas D

Correct answer: C

Question 51

Chemistry · 4 marks · −1

The graph between ∣ψ∣2|\psi|^2 and rr (radial distance) is shown below. This represents:

Figure for question 51
  1. A.1s orbital
  2. B.2s orbital
  3. C.3s orbital
  4. D.2p orbital

Correct answer: B

Question 52

Chemistry · 4 marks · −1

During the change of O2O_2 to O2−O_2^-, the incoming electron goes to the orbital:

  1. A.σ∗2pz\sigma^*2p_z
  2. B.π∗2px\pi^*2p_x
  3. C.π2px\pi 2p_x
  4. D.π2py\pi 2p_y

Correct answer: B

Question 53

Chemistry · 4 marks · −1

A process will be spontaneous at all temperatures if:

  1. A.ΔH>0\Delta H>0 and ΔS>0\Delta S>0
  2. B.ΔH<0\Delta H<0 and ΔS<0\Delta S<0
  3. C.ΔH<0\Delta H<0 and ΔS>0\Delta S>0
  4. D.ΔH>0\Delta H>0 and ΔS<0\Delta S<0

Correct answer: C

Question 54

Chemistry · 4 marks · −1

At room temperature, a dilute solution of urea is prepared by dissolving 0.60 g of urea in 360 g of water. If the vapour pressure of pure water at this temperature is 35 mmHg, lowering of vapour pressure will be: (molar mass of urea =60 g mol−1=60\ \text{g mol}^{-1})

  1. A.0.027 mmHg
  2. B.0.031 mmHg
  3. C.0.017 mmHg
  4. D.0.028 mmHg

Correct answer: C

Question 55

Chemistry · 4 marks · −1

Consider the following statements (a) The pH of a mixture containing 400 mL of 0.1 M H2SO4H_2SO_4 and 400 mL of 0.1 M NaOH will be approximately 1.3. (b) Ionic product of water is temperature dependent. (c) A monobasic acid with Ka=10−5K_a=10^{-5} has a pH = 5. The degree of dissociation of this acid is 50%. (d) The Le Chatelier's principle is not applicable to common-ion effect. The correct statements are:

  1. A.(a), (b) and (c)
  2. B.(a), (b) and (d)
  3. C.(a) and (b)
  4. D.(b) and (c)

Correct answer: A

Question 56

Chemistry · 4 marks · −1

Consider the statements S1 and S2: S1: Conductivity always increases with decrease in the concentration of electrolyte. S2: Molar conductivity always increases with decrease in the concentration of electrolyte. The correct option among the following is:

  1. A.Both S1 and S2 are correct
  2. B.Both S1 and S2 are wrong
  3. C.S1 is wrong and S2 is correct
  4. D.S1 is correct and S2 is wrong

Correct answer: C

Question 57

Chemistry · 4 marks · −1

A bacterial infection in an internal wound grows as N′(t)=N0exp⁡(t)N'(t)=N_0\exp(t), where the time tt is in hours. A dose of antibiotic, taken orally, needs 1 hour to reach the wound. Once it reaches there, the bacterial population goes down as dNdt=−5N2\frac{dN}{dt}=-5N^2. What will be the plot of N0N\frac{N_0}{N} vs. tt after 1 hour?

Figure for question 57
  1. A.Graph 1: N0/NN_0/N first decreases then rises (a U-shaped curve) with tt
  2. B.Graph 2: N0/NN_0/N increases linearly with tt (straight line with positive slope)
  3. C.Graph 3: N0/NN_0/N rises slowly and then abruptly steeply (two line segments)
  4. D.Graph 4: N0/NN_0/N decreases linearly with tt (straight line with negative slope)

Correct answer: B

Question 58

Chemistry · 4 marks · −1

A gas undergoes physical adsorption on a surface and follows the given Freundlich adsorption isotherm equation xm=kp0.5\frac{x}{m}=kp^{0.5} Adsorption of the gas increases with:

  1. A.Increase in p and increase in T
  2. B.Increase in p and decrease in T
  3. C.Decrease in p and increase in T
  4. D.Decrease in p and decrease in T

Correct answer: B

Question 59

Mathematics · 4 marks · −1

Let f(x)=x2f(x)=x^2, x∈Rx\in\mathbf{R}. For any A⊆RA\subseteq\mathbf{R}, define g(A)={x∈R:f(x)∈A}g(A)=\{x\in\mathbf{R}: f(x)\in A\}. If S=[0,4]S=[0,4], then which one of the following statements is not true?

  1. A.f(g(S))≠f(S)f(g(S))\neq f(S)
  2. B.f(g(S))=Sf(g(S))=S
  3. C.g(f(S))≠Sg(f(S))\neq S
  4. D.g(f(S))=g(S)g(f(S))=g(S)

Correct answer: D

Question 60

Mathematics · 4 marks · −1

If a>0a>0 and z=(1+i)2a−iz=\frac{(1+i)^2}{a-i}, has magnitude 25\sqrt{\frac{2}{5}}, then zˉ\bar{z} is equal to:

  1. A.−15−35i-\frac{1}{5}-\frac{3}{5}i
  2. B.−15+35i-\frac{1}{5}+\frac{3}{5}i
  3. C.−35−15i-\frac{3}{5}-\frac{1}{5}i
  4. D.15−35i\frac{1}{5}-\frac{3}{5}i

Correct answer: A

Question 61

Mathematics · 4 marks · −1

If α\alpha and β\beta are the roots of the quadratic equation, x2+xsin⁡θ−2sin⁡θ=0x^2+x\sin\theta-2\sin\theta=0, θ∈(0,π2)\theta\in\left(0,\frac{\pi}{2}\right), then α12+β12(α−12+β−12)(α−β)24\frac{\alpha^{12}+\beta^{12}}{(\alpha^{-12}+\beta^{-12})(\alpha-\beta)^{24}} is equal to:

  1. A.26(sin⁡θ+8)12\frac{2^6}{(\sin\theta+8)^{12}}
  2. B.212(sin⁡θ−8)6\frac{2^{12}}{(\sin\theta-8)^6}
  3. C.212(sin⁡θ+8)12\frac{2^{12}}{(\sin\theta+8)^{12}}
  4. D.212(sin⁡θ−4)12\frac{2^{12}}{(\sin\theta-4)^{12}}

Correct answer: C

Question 62

Mathematics · 4 marks · −1

If Δ1=∣xsin⁡θcos⁡θ−sin⁡θ−x1cos⁡θ1x∣\Delta_1=\begin{vmatrix} x & \sin\theta & \cos\theta \\ -\sin\theta & -x & 1 \\ \cos\theta & 1 & x \end{vmatrix} and Δ2=∣xsin⁡2θcos⁡2θ−sin⁡2θ−x1cos⁡2θ1x∣\Delta_2=\begin{vmatrix} x & \sin2\theta & \cos2\theta \\ -\sin2\theta & -x & 1 \\ \cos2\theta & 1 & x \end{vmatrix}, x≠0x\neq0; then for all θ∈(0,π2)\theta\in\left(0,\frac{\pi}{2}\right):

  1. A.Δ1−Δ2=−2x3\Delta_1-\Delta_2=-2x^3
  2. B.Δ1+Δ2=−2x3\Delta_1+\Delta_2=-2x^3
  3. C.Δ1+Δ2=−2(x3+x−1)\Delta_1+\Delta_2=-2(x^3+x-1)
  4. D.Δ1−Δ2=x(cos⁡2θ−cos⁡4θ)\Delta_1-\Delta_2=x(\cos2\theta-\cos4\theta)

Correct answer: B

Question 63

Mathematics · 4 marks · −1

If the system of linear equations x+y+z=5x+y+z=5 x+2y+2z=6x+2y+2z=6 x+3y+λz=μx+3y+\lambda z=\mu, (λ,μ∈R)(\lambda,\mu\in\mathbf{R}), has infinitely many solutions, then the value of λ+μ\lambda+\mu is:

  1. A.12
  2. B.10
  3. C.9
  4. D.7

Correct answer: B

Question 64

Mathematics · 4 marks · −1

The number of 6 digit numbers that can be formed using the digits 0, 1, 2, 5, 7 and 9 which are divisible by 11 and no digit is repeated, is:

  1. A.48
  2. B.60
  3. C.72
  4. D.36

Correct answer: B

Question 65

Mathematics · 4 marks · −1

If a1,a2,a3,…,ana_1, a_2, a_3, \ldots, a_n are in A.P. and a1+a4+a7+…+a16=114a_1+a_4+a_7+\ldots+a_{16}=114, then a1+a6+a11+a16a_1+a_6+a_{11}+a_{16} is equal to:

  1. A.38
  2. B.64
  3. C.76
  4. D.98

Correct answer: C

Question 66

Mathematics · 4 marks · −1

3×1312+5×(13+23)12+22+7×(13+23+33)12+22+32+…\frac{3\times1^3}{1^2}+\frac{5\times(1^3+2^3)}{1^2+2^2}+\frac{7\times(1^3+2^3+3^3)}{1^2+2^2+3^2}+\ldots upto 10th10^{\text{th}} term, is:

  1. A.600
  2. B.620
  3. C.660
  4. D.680

Correct answer: C

Question 67

Mathematics · 4 marks · −1

If the coefficients of x2x^2 and x3x^3 are both zero, in the expansion of the expression (1+ax+bx2)(1−3x)15(1+ax+bx^2)(1-3x)^{15} in powers of xx, then the ordered pair (a,b)(a,b) is equal to:

  1. A.(−21, 714)
  2. B.(−54, 315)
  3. C.(28, 861)
  4. D.(28, 315)

Correct answer: D

Question 68

Mathematics · 4 marks · −1

If lim⁡x→1x4−1x−1=lim⁡x→kx3−k3x2−k2\lim_{x\to1}\frac{x^4-1}{x-1}=\lim_{x\to k}\frac{x^3-k^3}{x^2-k^2}, then kk is:

  1. A.43\frac{4}{3}
  2. B.83\frac{8}{3}
  3. C.38\frac{3}{8}
  4. D.32\frac{3}{2}

Correct answer: B

Question 69

Mathematics · 4 marks · −1

If f(x)={sin⁡(p+1)x+sin⁡xx,x<0q,x=0x+x2−xx3/2,x>0f(x)=\begin{cases}\frac{\sin(p+1)x+\sin x}{x}, & x<0\\ q, & x=0\\ \frac{\sqrt{x+x^2}-\sqrt{x}}{x^{3/2}}, & x>0\end{cases} is continuous at x=0x=0, then the ordered pair (p,q)(p,q) is equal to:

  1. A.(−32,12)\left(-\frac{3}{2},\frac{1}{2}\right)
  2. B.(52,12)\left(\frac{5}{2},\frac{1}{2}\right)
  3. C.(−12,32)\left(-\frac{1}{2},\frac{3}{2}\right)
  4. D.(−32,−12)\left(-\frac{3}{2},-\frac{1}{2}\right)

Correct answer: A

Question 70

Mathematics · 4 marks · −1

Let f:R→Rf:\mathbf{R}\to\mathbf{R} be differentiable at c∈Rc\in\mathbf{R} and f(c)=0f(c)=0. If g(x)=∣f(x)∣g(x)=|f(x)|, then at x=cx=c, gg is:

  1. A.differentiable if f′(c)≠0f'(c)\neq0
  2. B.differentiable if f′(c)=0f'(c)=0
  3. C.not differentiable if f′(c)=0f'(c)=0
  4. D.not differentiable

Correct answer: B

Question 71

Mathematics · 4 marks · −1

Let f(x)=ex−xf(x)=e^x-x and g(x)=x2−xg(x)=x^2-x, ∀x∈R\forall x\in\mathbf{R}. Then the set of all x∈Rx\in\mathbf{R}, where the function h(x)=(f∘g)(x)h(x)=(f\circ g)(x) is increasing, is:

  1. A.[−12,0]∪[1,∞)\left[\frac{-1}{2},0\right]\cup[1,\infty)
  2. B.[0,12]∪[1,∞)\left[0,\frac{1}{2}\right]\cup[1,\infty)
  3. C.[−1,−12]∪[12,∞)\left[-1,\frac{-1}{2}\right]\cup\left[\frac{1}{2},\infty\right)
  4. D.[0,∞)[0,\infty)

Correct answer: B

Question 72

Mathematics · 4 marks · −1

If ∫dx(x2−2x+10)2=A(tan⁡−1(x−13)+f(x)x2−2x+10)+C\int\frac{dx}{(x^2-2x+10)^2}=A\left(\tan^{-1}\left(\frac{x-1}{3}\right)+\frac{f(x)}{x^2-2x+10}\right)+C where CC is a constant of integration, then:

  1. A.A=181A=\frac{1}{81} and f(x)=3(x−1)f(x)=3(x-1)
  2. B.A=127A=\frac{1}{27} and f(x)=9(x−1)f(x)=9(x-1)
  3. C.A=154A=\frac{1}{54} and f(x)=3(x−1)f(x)=3(x-1)
  4. D.A=154A=\frac{1}{54} and f(x)=9(x−1)2f(x)=9(x-1)^2

Correct answer: C

Question 73

Mathematics · 4 marks · −1

The value of ∫02π[sin⁡2x(1+cos⁡3x)] dx\int_0^{2\pi}[\sin2x(1+\cos3x)]\,dx, where [t][t] denotes the greatest integer function, is:

  1. A.2π2\pi
  2. B.−2π-2\pi
  3. C.π\pi
  4. D.−π-\pi

Correct answer: D

Question 74

Mathematics · 4 marks · −1

lim⁡n→∞((n+1)1/3n4/3+(n+2)1/3n4/3+…+(2n)1/3n4/3)\lim_{n\to\infty}\left(\frac{(n+1)^{1/3}}{n^{4/3}}+\frac{(n+2)^{1/3}}{n^{4/3}}+\ldots+\frac{(2n)^{1/3}}{n^{4/3}}\right) is equal to:

  1. A.34(2)4/3−34\frac{3}{4}(2)^{4/3}-\frac{3}{4}
  2. B.43(2)4/3\frac{4}{3}(2)^{4/3}
  3. C.34(2)4/3−43\frac{3}{4}(2)^{4/3}-\frac{4}{3}
  4. D.43(2)3/4\frac{4}{3}(2)^{3/4}

Correct answer: A

Question 75

Mathematics · 4 marks · −1

If y=y(x)y=y(x) is the solution of the differential equation dydx=(tan⁡x−y)sec⁡2x\frac{dy}{dx}=(\tan x-y)\sec^2x, x∈(−π2,π2)x\in\left(-\frac{\pi}{2},\frac{\pi}{2}\right), such that y(0)=0y(0)=0, then y(−π4)y\left(-\frac{\pi}{4}\right) is equal to:

  1. A.12−e\frac{1}{2}-e
  2. B.e−2e-2
  3. C.2+1e2+\frac{1}{e}
  4. D.1e−2\frac{1}{e}-2

Correct answer: B

Question 76

Mathematics · 4 marks · −1

The region represented by ∣x−y∣≤2|x-y|\le2 and ∣x+y∣≤2|x+y|\le2 is bounded by a:

  1. A.rhombus of side length 2 units
  2. B.rhombus of area 828\sqrt2 sq. units
  3. C.square of side length 222\sqrt2 units
  4. D.square of area 16 sq. units

Correct answer: C

Question 77

Mathematics · 4 marks · −1

If the circles x2+y2+5Kx+2y+K=0x^2+y^2+5Kx+2y+K=0 and 2(x2+y2)+2Kx+3y−1=02(x^2+y^2)+2Kx+3y-1=0, (K∈R)(K\in\mathbf{R}), intersect at the points P and Q, then the line 4x+5y−K=04x+5y-K=0 passes through P and Q, for:

  1. A.exactly one value of K
  2. B.exactly two values of K
  3. C.infinitely many values of K
  4. D.no value of K.

Correct answer: D

Question 78

Mathematics · 4 marks · −1

The line x=yx=y touches a circle at the point (1, 1). If the circle also passes through the point (1, −3), then its radius is:

  1. A.2
  2. B.3
  3. C.222\sqrt2
  4. D.323\sqrt2

Correct answer: C

Question 79

Mathematics · 4 marks · −1

If the line x−2y=12x-2y=12 is tangent to the ellipse x2a2+y2b2=1\frac{x^2}{a^2}+\frac{y^2}{b^2}=1 at the point (3,−92)\left(3,\frac{-9}{2}\right), then the length of the latus rectum of the ellipse is:

  1. A.9
  2. B.838\sqrt3
  3. C.5
  4. D.12212\sqrt2

Correct answer: A

Question 80

Mathematics · 4 marks · −1

If a directrix of a hyperbola centred at the origin and passing through the point (4,−23)(4,-2\sqrt3) is 5x=455x=4\sqrt5 and its eccentricity is ee, then:

  1. A.4e4−24e2+27=04e^4-24e^2+27=0
  2. B.4e4−12e2−27=04e^4-12e^2-27=0
  3. C.4e4+8e2−35=04e^4+8e^2-35=0
  4. D.4e4−24e2+35=04e^4-24e^2+35=0

Correct answer: D

Question 81

Mathematics · 4 marks · −1

Let A(3, 0, −1), B(2, 10, 6) and C(1, 2, 1) be the vertices of a triangle and M be the midpoint of AC. If G divides BM in the ratio, 2 : 1, then cos⁡(∠GOA)\cos(\angle GOA) (O being the origin) is equal to:

  1. A.115\frac{1}{\sqrt{15}}
  2. B.130\frac{1}{\sqrt{30}}
  3. C.1215\frac{1}{2\sqrt{15}}
  4. D.1610\frac{1}{6\sqrt{10}}

Correct answer: A

Question 82

Mathematics · 4 marks · −1

If Q(0, −1, −3) is the image of the point P in the plane 3x−y+4z=23x-y+4z=2 and R is the point (3, −1, −2), then the area (in sq. units) of ΔPQR\Delta PQR is:

  1. A.914\frac{\sqrt{91}}{4}
  2. B.2132\sqrt{13}
  3. C.652\frac{\sqrt{65}}{2}
  4. D.912\frac{\sqrt{91}}{2}

Correct answer: D

Question 83

Mathematics · 4 marks · −1

If the length of the perpendicular from the point (β,0,β)(\beta,0,\beta) (β≠0)(\beta\neq0) to the line, x1=y−10=z+1−1\frac{x}{1}=\frac{y-1}{0}=\frac{z+1}{-1} is 32\sqrt{\frac{3}{2}}, then β\beta is equal to:

  1. A.−2
  2. B.−1
  3. C.1
  4. D.2

Correct answer: B

Question 84

Mathematics · 4 marks · −1

Assume that each born child is equally likely to be a boy or a girl. If two families have two children each, then the conditional probability that all children are girls given that at least two are girls is:

  1. A.110\frac{1}{10}
  2. B.111\frac{1}{11}
  3. C.112\frac{1}{12}
  4. D.117\frac{1}{17}

Correct answer: B

Question 85

Mathematics · 4 marks · −1

If for some x∈Rx\in\mathbf{R}, the frequency distribution of the marks obtained by 20 students in a test is: Marks: 2, 3, 5, 7 Frequency: (x+1)2(x+1)^2, 2x−52x-5, x2−3xx^2-3x, xx then the mean of the marks is:

  1. A.2.5
  2. B.3.2
  3. C.3.0
  4. D.2.8

Correct answer: D

Question 86

Mathematics · 4 marks · −1

All the pairs (x,y)(x,y) that satisfy the inequality 2sin⁡2x−2sin⁡x+5⋅14sin⁡2y≤12^{\sqrt{\sin^2x-2\sin x+5}}\cdot\frac{1}{4^{\sin^2y}}\le1 also satisfy the equation:

  1. A.sin⁡x=2sin⁡y\sin x=2\sin y
  2. B.2sin⁡x=sin⁡y2\sin x=\sin y
  3. C.sin⁡x=∣sin⁡y∣\sin x=|\sin y|
  4. D.2∣sin⁡x∣=3sin⁡y2|\sin x|=3\sin y

Correct answer: C

Question 87

Mathematics · 4 marks · −1

ABC is a triangular park with AB = AC = 100 metres. A vertical tower is situated at the mid-point of BC. If the angles of elevation of the top of the tower at A and B are cot⁡−1(32)\cot^{-1}(3\sqrt2) and cosec−1(22)\text{cosec}^{-1}(2\sqrt2) respectively, then the height of the tower (in metres) is:

  1. A.10033\frac{100}{3\sqrt3}
  2. B.25
  3. C.20
  4. D.10510\sqrt5

Correct answer: C

Question 88

Mathematics · 4 marks · −1

Which one of the following Boolean expressions is a tautology?

  1. A.(p∨q)∧(∼p∨∼q)(p\lor q)\land(\sim p\lor\sim q)
  2. B.(p∧q)∨(p∧∼q)(p\land q)\lor(p\land\sim q)
  3. C.(p∨q)∧(p∨∼q)(p\lor q)\land(p\lor\sim q)
  4. D.(p∨q)∨(p∨∼q)(p\lor q)\lor(p\lor\sim q)

Correct answer: D

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