JEE Main 2019 — 11 Jan Shift 1 (Previous Year Paper)

JEE Main · 2019 · with answers and explanations

questions
82
Total marks
328
Duration
180 minutes
Negative marking
−1

Subjects: Physics · Chemistry · Mathematics

Question 1

Physics · 4 marks · −1

The force of interaction between two atoms is given by F=αβexp⁡(−x2αkT)F=\alpha\beta\exp\left(-\frac{x^2}{\alpha kT}\right); where xx is the distance, kk is the Boltzmann constant and TT is temperature and α\alpha and β\beta are two constants. The dimension of β\beta is:

  1. A.MLT−2MLT^{-2}
  2. B.M2L2T−2M^2L^2T^{-2}
  3. C.M0L2T−4M^0L^2T^{-4}
  4. D.M2LT−4M^2LT^{-4}

Correct answer: D

Question 2

Physics · 4 marks · −1

A particle is moving along a circular path with a constant speed of 10 m s−110\ \text{m s}^{-1}. What is the magnitude of the change in velocity of the particle, when it moves through an angle of 60∘60^\circ around the centre of the circle?

  1. A.zero
  2. B.10310\sqrt{3} m/s
  3. C.10210\sqrt{2} m/s
  4. D.1010 m/s

Correct answer: D

Question 3

Physics · 4 marks · −1

A body is projected at t=0t=0 with a velocity 10 m s−110\ \text{m s}^{-1} at an angle of 60∘60^\circ with the horizontal. The radius of curvature of its trajectory at t=1t=1 s is RR. Neglecting air resistance and taking acceleration due to gravity g=10 m s−2g=10\ \text{m s}^{-2}, the value of RR is:

  1. A.2.5 m
  2. B.5.1 m
  3. C.2.8 m
  4. D.10.3 m

Correct answer: C

Question 4

Physics · 4 marks · −1

A liquid of density ρ\rho is coming out of a hose pipe of radius aa with horizontal speed vv and hits a mesh. 50% of the liquid passes through the mesh unaffected. 25% looses all of its momentum and 25% comes back with the same speed. The resultant pressure on the mesh will be:

  1. A.14ρv2\frac{1}{4}\rho v^2
  2. B.12ρv2\frac{1}{2}\rho v^2
  3. C.34ρv2\frac{3}{4}\rho v^2
  4. D.ρv2\rho v^2

Correct answer: C

Question 5

Physics · 4 marks · −1

A slab is subjected to two forces F⃗1\vec{F}_1 and F⃗2\vec{F}_2 of same magnitude FF as shown in the figure. Force F⃗2\vec{F}_2 is in XY-plane while force F⃗1\vec{F}_1 acts along z-axis at the point (2i⃗+3j⃗)(2\vec{i}+3\vec{j}). The moment of these forces about point O will be:

Figure for question 5
  1. A.(3i^+2j^−3k^)F(3\hat{i}+2\hat{j}-3\hat{k})F
  2. B.(3i^−2j^+3k^)F(3\hat{i}-2\hat{j}+3\hat{k})F
  3. C.(3i^+2j^+3k^)F(3\hat{i}+2\hat{j}+3\hat{k})F
  4. D.(3i^−2j^−3k^)F(3\hat{i}-2\hat{j}-3\hat{k})F

Correct answer: B

Question 6

Physics · 4 marks · −1

An equilateral triangle ABC is cut from a thin solid sheet of wood. (See figure) D, E and F are the mid-points of its sides as shown and G is the centre of the triangle. The moment of inertia of the triangle about an axis passing through G and perpendicular to the plane of the triangle is I0I_0. If the smaller triangle DEF is removed from ABC, the moment of inertia of the remaining figure about the same axis is II. Then:

Figure for question 6
  1. A.I=I04I=\frac{I_0}{4}
  2. B.I=34I0I=\frac{3}{4}I_0
  3. C.I=916I0I=\frac{9}{16}I_0
  4. D.I=1516I0I=\frac{15}{16}I_0

Correct answer: D

Question 7

Physics · 4 marks · −1

A satellite is revolving in a circular orbit at a height hh from the earth surface, such that h≪Rh\ll R where RR is the radius of the earth. Assuming that the effect of earth's atmosphere can be neglected the minimum increase in the speed required so that the satellite could escape from the gravitational field of earth is:

  1. A.gR\sqrt{gR}
  2. B.2gR\sqrt{2gR}
  3. C.gR(2−1)\sqrt{gR}(\sqrt{2}-1)
  4. D.gR2\sqrt{\frac{gR}{2}}

Correct answer: C

Question 8

Physics · 4 marks · −1

Ice at −20∘-20^\circC is added to 50 g of water at 40∘40^\circC. When the temperature of the mixture reaches 0∘0^\circC, it is found that 20 g of ice is still unmelted. The amount of ice added to the water was close to (Specific heat of water =4.2=4.2 J/g/∘^\circC, Specific heat of Ice =2.1=2.1 J/g/∘^\circC, Heat of fusion of water at 0∘0^\circC =334=334 J/g)

  1. A.60 g
  2. B.40 g
  3. C.50 g
  4. D.100 g

Correct answer: B

Question 9

Physics · 4 marks · −1

A rigid diatomic ideal gas undergoes an adiabatic process at room temperature. The relation between temperature and volume for this process is TVx=TV^x= constant, then xx is:

  1. A.23\frac{2}{3}
  2. B.25\frac{2}{5}
  3. C.53\frac{5}{3}
  4. D.35\frac{3}{5}

Correct answer: B

Question 10

Physics · 4 marks · −1

A gas mixture consists of 3 moles of oxygen and 5 moles of argon at temperature TT. Considering only translational and rotational modes, the total internal energy of the system is:

  1. A.4 RT
  2. B.12 RT
  3. C.15 RT
  4. D.20 RT

Correct answer: C

Question 11

Physics · 4 marks · −1

Equation of travelling wave on a stretched string of linear density 5 g/m is y=0.03sin⁡(450t−9x)y=0.03\sin(450t-9x) where distance and time are measured in SI units. The tension in the string is:

  1. A.5 N
  2. B.7.5 N
  3. C.10 N
  4. D.12.5 N

Correct answer: D

Question 12

Physics · 4 marks · −1

Three charges QQ, +q+q and +q+q are placed at the vertices of a right-angle isosceles triangle as shown below. The net electrostatic energy of the configuration is zero, if the value of QQ is:

Figure for question 12
  1. A.−q1+2\frac{-q}{1+\sqrt{2}}
  2. B.−2q2+1\frac{-\sqrt{2}q}{\sqrt{2}+1}
  3. C.−2q-2q
  4. D.+q+q

Correct answer: B

Question 13

Physics · 4 marks · −1

The given graph shows variation (with distance rr from centre) of:

Figure for question 13
  1. A.Potential of a uniformly charged spherical shell
  2. B.Potential of a uniformly charged sphere
  3. C.Electric field of a uniformly charged spherical shell
  4. D.Electric field of a uniformly charged sphere

Correct answer: A

Question 14

Physics · 4 marks · −1

Two equal resistances when connected in series to a battery, consume electric power of 60 W. If these resistances are now connected in parallel combination to the same battery, the electric power consumed will be:

  1. A.60 W
  2. B.240 W
  3. C.120 W
  4. D.30 W

Correct answer: B

Question 15

Physics · 4 marks · −1

In a Wheatstone bridge (see fig.), Resistances P and Q are approximately equal. When R=400 ΩR=400\ \Omega, the bridge is balanced. On interchanging P and Q, the value of R, for balance, is 405 Ω405\ \Omega. The value of X is close to:

Figure for question 15
  1. A.401.5 ohm
  2. B.404.5 ohm
  3. C.402.5 ohm
  4. D.403.5 ohm

Correct answer: C

Question 16

Physics · 4 marks · −1

In an experiment, electrons are accelerated, from rest, by applying a voltage of 500 V. Calculate the radius of the path if a magnetic field 100 mT is then applied. [Charge of the electron =1.6×10−19=1.6\times10^{-19} C, Mass of the electron =9.1×10−31=9.1\times10^{-31} kg]

  1. A.7.5 m
  2. B.7.5×10−27.5\times10^{-2} m
  3. C.7.5×10−47.5\times10^{-4} m
  4. D.7.5×10−37.5\times10^{-3} m

Correct answer: C

Question 17

Physics · 4 marks · −1

There are two long co-axial solenoids of same length ll. The inner and outer coils have radii r1r_1 and r2r_2 and number of turns per unit length n1n_1 and n2n_2, respectively. The ratio of mutual inductance to the self-inductance of the inner-coil is:

  1. A.n2n1\frac{n_2}{n_1}
  2. B.n2n1⋅r22r12\frac{n_2}{n_1}\cdot\frac{r_2^2}{r_1^2}
  3. C.n2n1⋅r1r2\frac{n_2}{n_1}\cdot\frac{r_1}{r_2}
  4. D.n1n2\frac{n_1}{n_2}

Correct answer: A

Question 18

Physics · 4 marks · −1

In the circuit shown, the switch S1S_1 is closed at time t=0t=0 and the switch S2S_2 is kept open. At some later time (t0t_0), the switch S1S_1 is opened and S2S_2 is closed. The behaviour of the current II as a function of time tt is given by:

Figure for question 18
  1. A.Graph: I rises linearly from 0 to a peak at t0t_0, then decays exponentially (concave up) toward zero.
  2. B.Graph: I rises exponentially (concave down, saturating) from 0 up to t0t_0, then decays exponentially toward zero.
  3. C.Graph: I rises linearly to a peak at t0t_0 and then falls linearly to zero (triangle).
  4. D.Graph: I rises along a concave-down curve to t0t_0 and then falls along a concave-down curve to zero.

Correct answer: B

Question 19

Physics · 4 marks · −1

An electromagnetic wave of intensity 50 W m−250\ \text{W m}^{-2} enters in a medium of refractive index nn without any loss. The ratio of the magnitudes of electric fields, and the ratio of the magnitudes of magnetic fields of the wave before and after entering into the medium are respectively, given by:

  1. A.(1n,n)\left(\frac{1}{\sqrt{n}},\sqrt{n}\right)
  2. B.(n,1n)\left(\sqrt{n},\frac{1}{\sqrt{n}}\right)
  3. C.(n,n)\left(\sqrt{n},\sqrt{n}\right)
  4. D.(1n,1n)\left(\frac{1}{\sqrt{n}},\frac{1}{\sqrt{n}}\right)

Correct answer: B

Question 20

Physics · 4 marks · −1

An object is at a distance of 20 m from a convex lens of focal length 0.3 m. The lens forms an image of the object. If the object moves away from the lens at a speed of 5 m/s, the speed and direction of the image will be:

  1. A.2.26×10−32.26\times10^{-3} m/s away from the lens
  2. B.1.16×10−31.16\times10^{-3} m/s towards the lens
  3. C.3.22×10−33.22\times10^{-3} m/s towards the lens
  4. D.0.92×10−30.92\times10^{-3} m/s away from the lens

Correct answer: B

Question 21

Physics · 4 marks · −1

In a Young's double slit experiment, the path difference, at a certain point on the screen, between two interfering waves is 18\frac{1}{8}th of wavelength. The ratio of the intensity at this point to that at the centre of a bright fringe is close to:

  1. A.0.74
  2. B.0.80
  3. C.0.85
  4. D.0.94

Correct answer: C

Question 22

Physics · 4 marks · −1

If the de Broglie wavelength of an electron is equal to 10−310^{-3} times the wavelength of a photon of frequency 6×10146\times10^{14} Hz, then the speed of electron is equal to: (Speed of light =3×108=3\times10^{8} m/s, Planck's constant =6.63×10−34=6.63\times10^{-34} J s, Mass of electron =9.1×10−31=9.1\times10^{-31} kg)

  1. A.1.8×1061.8\times10^{6} m/s
  2. B.1.45×1061.45\times10^{6} m/s
  3. C.1.1×1061.1\times10^{6} m/s
  4. D.1.7×1061.7\times10^{6} m/s

Correct answer: B

Question 23

Physics · 4 marks · −1

A hydrogen atom, initially in the ground state is excited by absorbing a photon of wavelength 980 Å. The radius of the atom in the excited state, in terms of Bohr radius a0a_0, will be: (hc=12500hc=12500 eV-Å)

  1. A.4a04a_0
  2. B.9a09a_0
  3. C.16a016a_0
  4. D.25a025a_0

Correct answer: C

Question 24

Physics · 4 marks · −1

In the given circuit the current through Zener Diode is close to:

Figure for question 24
  1. A.6.7 mA
  2. B.4.0 mA
  3. C.0.0 mA
  4. D.6.0 mA

Correct answer: C

Question 25

Physics · 4 marks · −1

The variation of refractive index of a crown glass thin prism with wavelength of the incident light is shown. Which of the following graphs is the correct one, if DmD_m is the angle of minimum deviation?

Figure for question 25
  1. A.Graph: DmD_m decreases monotonically with λ\lambda from 400 nm to 700 nm (concave up).
  2. B.Graph: DmD_m increases with λ\lambda, rising more steeply at longer wavelengths.
  3. C.Graph: DmD_m increases with λ\lambda and levels off (concave down).
  4. D.Graph: DmD_m first decreases then increases, with a minimum near 550 nm.

Correct answer: A

Question 26

Physics · 4 marks · −1

The resistance of the meter bridge AB in given figure is 4 Ω4\ \Omega. With a cell of emf ε=0.5\varepsilon=0.5 V and rheostat resistance Rh=2 ΩR_h=2\ \Omega the null point is obtained at some point J. When the cell is replaced by another one of emf ε=ε2\varepsilon=\varepsilon_2 the same null point J is found for Rh=6 ΩR_h=6\ \Omega. The emf ε2\varepsilon_2 is:

Figure for question 26
  1. A.0.3 V
  2. B.0.5 V
  3. C.0.4 V
  4. D.0.6 V

Correct answer: A

Question 27

Chemistry · 4 marks · −1

Among the following compounds, which one is found in RNA?

Figure for question 27
  1. A.Uracil (pyrimidine-2,4-dione ring with two N-H groups; structure drawn)
  2. B.Cytosine (4-amino-pyrimidin-2-one; structure drawn)
  3. C.Thymine (5-methyluracil; structure drawn)
  4. D.1,3-Dimethyluracil (uracil with both N-H replaced by N-Me; structure drawn)

Correct answer: A

Question 28

Chemistry · 4 marks · −1

The polymer obtained from the following reactions is: HOOC(CH2)4NH2→(ii) polymerisation(i) NaNO2/H3O+\text{HOOC(CH}_2)_4\text{NH}_2 \xrightarrow[\text{(ii) polymerisation}]{\text{(i) NaNO}_2/\text{H}_3\text{O}^+}

Figure for question 28
  1. A.[ ⁣−OC(=O)(CH2)4O−]n\left[\!-\text{OC(=O)(CH}_2)_4\text{O}-\right]_n
  2. B.[ ⁣−HNC(=O)(CH2)4C(=O)NH−]n\left[\!-\text{HNC(=O)(CH}_2)_4\text{C(=O)NH}-\right]_n
  3. C.[ ⁣−O−(CH2)4−C(=O)−]n\left[\!-\text{O}-(\text{CH}_2)_4-\text{C(=O)}-\right]_n
  4. D.[ ⁣−C(=O)−(CH2)4−NH−]n\left[\!-\text{C(=O)}-(\text{CH}_2)_4-\text{NH}-\right]_n

Correct answer: C

Question 29

Chemistry · 4 marks · −1

The major product of the following reaction is: 4-methylacetophenone (p-CH3C6H4COCH3p\text{-CH}_3\text{C}_6\text{H}_4\text{COCH}_3) →(ii) H2SO4 (dil)(i) KMnO4/KOH, Δ\xrightarrow[\text{(ii) H}_2\text{SO}_4\text{ (dil)}]{\text{(i) KMnO}_4/\text{KOH},\ \Delta}

Figure for question 29
  1. A.p-HOOC-C6H4-COCOOHp\text{-HOOC-C}_6\text{H}_4\text{-COCOOH}
  2. B.p-HOOC-C6H4-COOHp\text{-HOOC-C}_6\text{H}_4\text{-COOH} (terephthalic acid)
  3. C.p-OHC-C6H4-COOHp\text{-OHC-C}_6\text{H}_4\text{-COOH}
  4. D.p-HOOC-C6H4-COCH3p\text{-HOOC-C}_6\text{H}_4\text{-COCH}_3

Correct answer: B

Question 30

Chemistry · 4 marks · −1

The major product of the following reaction is: 4-hydroxybenzenesulfonic acid →Br2 (excess)\xrightarrow{\text{Br}_2\ (\text{excess})}

Figure for question 30
  1. A.2,6-Dibromo-4-hydroxybenzenesulfonic acid (Br ortho to OH on both sides, SO3_3H retained)
  2. B.3-Bromo-4-hydroxybenzenesulfonic acid (one Br ortho to OH, SO3_3H retained)
  3. C.3,4,5-Tribromophenol
  4. D.2,4,6-Tribromophenol

Correct answer: D

Question 31

Chemistry · 4 marks · −1

The major product of the following reaction is: 5-chlorocyclohex-3-en-1-one →(ii) alc. KOH(i) HBr\xrightarrow[\text{(ii) alc. KOH}]{\text{(i) HBr}}

Figure for question 31
  1. A.5-Hydroxycyclohex-2-en-1-one
  2. B.5-Chlorocyclohex-2-en-1-one
  3. C.Phenol
  4. D.3-Chlorocyclohex-3-en-1-one (Cl on a ring C=C carbon)

Correct answer: C

Question 32

Chemistry · 4 marks · −1

Which compound(s) out of the following is/are not aromatic? (A) cyclopropenyl cation (B) cyclopentadienyl cation (C) cycloheptatrienyl anion (D) cycloheptatriene

Figure for question 32
  1. A.(B)
  2. B.(A) and (C)
  3. C.(B), (C) and (D)
  4. D.(C) and (D)

Correct answer: C

Question 33

Chemistry · 4 marks · −1

The major product of the following reaction is: ethyl 2-(cyanomethyl)benzoate →(ii) DIBAL-H(i) Ni/H2\xrightarrow[\text{(ii) DIBAL-H}]{\text{(i) Ni/H}_2}

Figure for question 33
  1. A.2-(2-Oxoethyl)benzaldehyde (o-OHC-C6H4-CH2CHOo\text{-OHC-C}_6\text{H}_4\text{-CH}_2\text{CHO})
  2. B.3,4-Dihydroisoquinoline (cyclic imine fused to benzene)
  3. C.1,2,3,4-Tetrahydroisoquinoline
  4. D.2-(2-Aminoethyl)benzyl alcohol (o-HOCH2-C6H4-CH2CH2NH2o\text{-HOCH}_2\text{-C}_6\text{H}_4\text{-CH}_2\text{CH}_2\text{NH}_2)

Correct answer: B

Question 34

Chemistry · 4 marks · −1

The correct match between items I and II is:<br>Item-I (Mixture): (A) H2_2O : Sugar (B) H2_2O : Aniline (C) H2_2O : Toluene<br>Item-II (Separation method): (P) Sublimation (Q) Recrystallization (R) Steam distillation (S) Differential extraction

  1. A.(A)→\to(R); (B)→\to(P); (C)→\to(S)
  2. B.(A)→\to(S); (B)→\to(R); (C)→\to(P)
  3. C.(A)→\to(Q); (B)→\to(R); (C)→\to(S)
  4. D.(A)→\to(Q); (B)→\to(R); (C)→\to(P)

Correct answer: C

Question 35

Chemistry · 4 marks · −1

The correct match between item (I) and item (II) is:<br>Item-I: (A) Norethindrone (B) Ofloxacin (C) Equanil<br>Item-II: (P) Anti-biotic (Q) Anti-fertility (R) Hypertension (S) Analgesics

  1. A.(A)→\to(R); (B)→\to(P); (C)→\to(S)
  2. B.(A)→\to(R); (B)→\to(P); (C)→\to(R)
  3. C.(A)→\to(Q); (B)→\to(R); (C)→\to(S)
  4. D.(A)→\to(Q); (B)→\to(P); (C)→\to(R)

Correct answer: D

Question 36

Chemistry · 4 marks · −1

An organic compound is estimated through Dumas method and was found to evolve 6 moles of CO2_2, 4 moles of H2_2O and 1 mole of nitrogen gas. The formula of the compound is:

  1. A.C12_{12}H8_8N2_2
  2. B.C12_{12}H8_8N
  3. C.C6_6H8_8N2_2
  4. D.C6_6H8_8N

Correct answer: C

Question 37

Chemistry · 4 marks · −1

The correct order of the atomic radii of C, Cs, Al, and S is:

  1. A.S < C < Cs < Al
  2. B.C < S < Al < Cs
  3. C.C < S < Cs < Al
  4. D.S < C < Al < Cs

Correct answer: B

Question 38

Chemistry · 4 marks · −1

Match the ores (column A) with the metals (column B):<br>Column A (Ores): (I) Siderite (II) Kaolinite (III) Malachite (IV) Calamine<br>Column B (Metals): (a) Zinc (b) Copper (c) Iron (d) Aluminium

  1. A.(I)-(a); (II)-(b); (III)-(c); (IV)-(d)
  2. B.(I)-(c); (II)-(d); (III)-(b); (IV)-(a)
  3. C.(I)-(b); (II)-(c); (III)-(d); (IV)-(a)
  4. D.(I)-(c); (II)-(d); (III)-(a); (IV)-(b)

Correct answer: B

Question 39

Chemistry · 4 marks · −1

NaH is an example of:

  1. A.metallic hydride
  2. B.molecular hydride
  3. C.saline hydride
  4. D.electron-rich hydride

Correct answer: C

Question 40

Chemistry · 4 marks · −1

The correct statements among (a) to (d) regarding H2_2 as a fuel are:<br>(a) It produces less pollutants than petrol.<br>(b) A cylinder of compressed dihydrogen weighs ~30 times more than a petrol tank producing the same amount of energy.<br>(c) Dihydrogen is stored in tanks of metal alloys like NaNi5_5.<br>(d) On combustion, values of energy released per gram of liquid dihydrogen and LPG are 50 and 142 kJ, respectively.

  1. A.(a) and (c) only
  2. B.(b), (c) and (d) only
  3. C.(b) and (d) only
  4. D.(a), (b) and (c) only

Correct answer: D

Question 41

Chemistry · 4 marks · −1

The amphoteric hydroxide is:

  1. A.Be(OH)2_2
  2. B.Mg(OH)2_2
  3. C.Ca(OH)2_2
  4. D.Sr(OH)2_2

Correct answer: A

Question 42

Chemistry · 4 marks · −1

The chloride that CANNOT get hydrolysed is:

  1. A.CCl4_4
  2. B.SiCl4_4
  3. C.SnCl4_4
  4. D.PbCl4_4

Correct answer: A

Question 43

Chemistry · 4 marks · −1

The element that usually does NOT show variable oxidation states is:

  1. A.Sc
  2. B.Cu
  3. C.Ti
  4. D.V

Correct answer: A

Question 44

Chemistry · 4 marks · −1

Match the metals (column I) with the coordination compound(s)/enzyme(s) (column II):<br>Column I (Metals): (A) Co (B) Zn (C) Rh (D) Mg<br>Column II: (i) Wilkinson catalyst (ii) Chlorophyll (iii) Vitamin B12_{12} (iv) Carbonic anhydrase

  1. A.(A)-(ii); (B)-(i); (C)-(iv); (D)-(iii)
  2. B.(A)-(iv); (B)-(iii); (C)-(i); (D)-(ii)
  3. C.(A)-(i); (B)-(ii); (C)-(iii); (D)-(iv)
  4. D.(A)-(iii); (B)-(iv); (C)-(i); (D)-(ii)

Correct answer: D

Question 45

Chemistry · 4 marks · −1

The concentration of dissolved oxygen (DO) in cold water can go upto:

  1. A.8 ppm
  2. B.10 ppm
  3. C.14 ppm
  4. D.16 ppm

Correct answer: B

Question 46

Chemistry · 4 marks · −1

Peroxyacetyl nitrate (PAN), an eye irritant is produced by:

  1. A.acid rain
  2. B.organic waste
  3. C.photochemical smog
  4. D.classical smog

Correct answer: C

Question 47

Chemistry · 4 marks · −1

A 10 mg effervescent tablet containing sodium bicarbonate and oxalic acid releases 0.25 ml of CO2_2 at T=298.15T=298.15 K and p=1p=1 bar. If molar volume of CO2_2 is 25.0 L under such condition, what is the percentage of sodium bicarbonate in each tablet? [Molar mass of NaHCO3=84_3=84 g mol−1^{-1}]

  1. A.8.4
  2. B.0.84
  3. C.16.8
  4. D.33.6

Correct answer: A

Question 48

Chemistry · 4 marks · −1

Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line of H-atom is suitable for this purpose? [RH=1×105R_H=1\times10^{5} cm−1^{-1}, h=6.6×10−34h=6.6\times10^{-34} J s, c=3×108c=3\times10^{8} m s−1^{-1}]

  1. A.Lyman, ∞→1\infty\to1
  2. B.Balmer, ∞→2\infty\to2
  3. C.Paschen, 5→35\to3
  4. D.Paschen, ∞→3\infty\to3

Correct answer: D

Question 49

Chemistry · 4 marks · −1

For the chemical reaction X⇌YX \rightleftharpoons Y, the standard reaction Gibbs energy depends on temperature TT (in K) as ΔrG∘ (in kJ mol−1)=120−38T\Delta_rG^\circ\ (\text{in kJ mol}^{-1}) = 120-\frac{3}{8}T. The major component of the reaction mixture at TT is:

  1. A.X if T=350T=350 K
  2. B.Y if T=300T=300 K
  3. C.X if T=315T=315 K
  4. D.Y if T=280T=280 K

Correct answer: C

Question 50

Chemistry · 4 marks · −1

Two blocks of the same metal having same mass and at temperature T1T_1 and T2T_2, respectively, are brought in contact with each other and allowed to attain thermal equilibrium at constant pressure. The change in entropy, ΔS\Delta S, for this process is:

  1. A.2Cpln⁡(T1+T24T1T2)2C_p\ln\left(\frac{T_1+T_2}{4T_1T_2}\right)
  2. B.Cpln⁡[(T1+T2)24T1T2]C_p\ln\left[\frac{(T_1+T_2)^2}{4T_1T_2}\right]
  3. C.2Cpln⁡[T1+T22T1T2]2C_p\ln\left[\frac{T_1+T_2}{2T_1T_2}\right]
  4. D.2Cpln⁡[(T1+T2)1/2T1T2]2C_p\ln\left[\frac{(T_1+T_2)^{1/2}}{T_1T_2}\right]

Correct answer: B

Question 51

Chemistry · 4 marks · −1

The freezing point of a diluted milk sample is found to be −0.2∘-0.2^\circC, while it should have been −0.5∘-0.5^\circC for pure milk. How much water has been added to pure milk to make the diluted sample?

  1. A.1 cup of water to 2 cups of pure milk
  2. B.2 cups of water to 3 cups of pure milk
  3. C.3 cups of water to 2 cups of pure milk
  4. D.1 cup of water to 3 cups of pure milk

Correct answer: C

Question 52

Chemistry · 4 marks · −1

Consider the reaction N2(g)+3H2(g)⇌2NH3(g)\text{N}_2(g)+3\text{H}_2(g)\rightleftharpoons2\text{NH}_3(g). The equilibrium constant of the above reaction is KpK_p. If pure ammonia is left to dissociate, the partial pressure of ammonia at equilibrium is given by (Assume that pNH3≪ptotalp_{\text{NH}_3}\ll p_{\text{total}} at equilibrium)

  1. A.Kp1/2P216\frac{K_p^{1/2}P^2}{16}
  2. B.33/2Kp1/2P24\frac{3^{3/2}K_p^{1/2}P^2}{4}
  3. C.Kp1/2P24\frac{K_p^{1/2}P^2}{4}
  4. D.33/2Kp1/2P216\frac{3^{3/2}K_p^{1/2}P^2}{16}

Correct answer: D

Question 53

Chemistry · 4 marks · −1

For the cell Zn(s)|Zn2+^{2+}(aq)||Mx+^{x+}(aq)|M(s), different half cells and their standard electrode potentials are given below:<br>Au3+^{3+}(aq)/Au(s): 1.40 V; Ag+^+(aq)/Ag(s): 0.80 V; Fe3+^{3+}(aq)/Fe2+^{2+}(aq): 0.77 V; Fe2+^{2+}(aq)/Fe(s): −0.44-0.44 V.<br>If EZn2+/Zn∘=−0.76E^\circ_{\text{Zn}^{2+}/\text{Zn}}=-0.76 V, which cathode will give a maximum value of Ecell∘E^\circ_{\text{cell}} per electron transferred?

  1. A.Au3+^{3+}/Au
  2. B.Ag+^+/Ag
  3. C.Fe3+^{3+}/Fe2+^{2+}
  4. D.Fe2+^{2+}/Fe

Correct answer: B

Question 54

Chemistry · 4 marks · −1

If a reaction follows the Arrhenius equation, the plot ln⁡k\ln k vs 1RT\frac{1}{RT} gives straight line with a gradient (−y)(-y) unit. The energy required to activate the reactant is:

  1. A.yRyR unit
  2. B.yy unit
  3. C.−y-y unit
  4. D.y/Ry/R unit

Correct answer: B

Question 55

Chemistry · 4 marks · −1

An example of solid sol is:

  1. A.Gem stones
  2. B.Paint
  3. C.Butter
  4. D.Hair cream

Correct answer: A

Question 56

Mathematics · 4 marks · −1

Let f:R→Rf:\mathbb{R}\to\mathbb{R} be defined by f(x)=x1+x2f(x)=\frac{x}{1+x^2}, x∈Rx\in\mathbb{R}. Then the range of ff is:

  1. A.R−[−12,12]\mathbb{R}-\left[-\frac12,\frac12\right]
  2. B.R−[−1,1]\mathbb{R}-[-1,1]
  3. C.(−1,1)−{0}(-1,1)-\{0\}
  4. D.[−12,12]\left[-\frac12,\frac12\right]

Correct answer: D

Question 57

Mathematics · 4 marks · −1

If one real root of the quadratic equation 81x2+kx+256=081x^2+kx+256=0 is cube of the other root, then a value of kk is:

  1. A.−300-300
  2. B.100
  3. C.144
  4. D.−81-81

Correct answer: A

Question 58

Mathematics · 4 marks · −1

Let (−2−13i)3=x+iy27\left(-2-\frac{1}{3}i\right)^3=\frac{x+iy}{27} (i=−1)(i=\sqrt{-1}), where xx and yy are real numbers, then y−xy-x equals:

  1. A.91
  2. B.85
  3. C.−91-91
  4. D.−85-85

Correct answer: A

Question 59

Mathematics · 4 marks · −1

Let A=(02qrpq−rp−qr)A=\begin{pmatrix}0&2q&r\\p&q&-r\\p&-q&r\end{pmatrix}. If AAT=I3AA^T=I_3, then ∣p∣|p| is:

  1. A.12\frac{1}{\sqrt2}
  2. B.13\frac{1}{\sqrt3}
  3. C.15\frac{1}{\sqrt5}
  4. D.16\frac{1}{\sqrt6}

Correct answer: A

Question 60

Mathematics · 4 marks · −1

If the system of linear equations<br>2x+2y+3z=a2x+2y+3z=a<br>3x−y+5z=b3x-y+5z=b<br>x−3y+2z=cx-3y+2z=c<br>where a,b,ca,b,c are non-zero real numbers, has more than one solution, then:

  1. A.b+c−a=0b+c-a=0
  2. B.b−c+a=0b-c+a=0
  3. C.b−c−a=0b-c-a=0
  4. D.a+b+c=0a+b+c=0

Correct answer: C

Question 61

Mathematics · 4 marks · −1

The sum of the real values of xx for which the middle term in the binomial expansion of (x33+3x)8\left(\frac{x^3}{3}+\frac{3}{x}\right)^8 equals 5670 is:

  1. A.0
  2. B.4
  3. C.6
  4. D.8

Correct answer: A

Question 62

Mathematics · 4 marks · −1

Let a1,a2,…,a10a_1,a_2,\ldots,a_{10} be a G.P. If a3a1=25\frac{a_3}{a_1}=25, then a9a5\frac{a_9}{a_5} equals:

  1. A.2(52)2(5^2)
  2. B.4(52)4(5^2)
  3. C.535^3
  4. D.545^4

Correct answer: D

Question 63

Mathematics · 4 marks · −1

The sum of an infinite geometric series with positive terms is 3 and the sum of the cubes of its terms is 2719\frac{27}{19}. Then the common ratio of this series is:

  1. A.49\frac49
  2. B.29\frac29
  3. C.13\frac13
  4. D.23\frac23

Correct answer: D

Question 64

Mathematics · 4 marks · −1

The value of rr for which 20Cr 20C0+20Cr−1 20C1+20Cr−2 20C2+⋯+20C0 20Cr{}^{20}C_r\,{}^{20}C_0+{}^{20}C_{r-1}\,{}^{20}C_1+{}^{20}C_{r-2}\,{}^{20}C_2+\cdots+{}^{20}C_0\,{}^{20}C_r is maximum, is:

  1. A.11
  2. B.15
  3. C.10
  4. D.20

Correct answer: D

Question 65

Mathematics · 4 marks · −1

Let [x][x] denote the greatest integer less than or equal to xx. Then: lim⁡x→0tan⁡(πsin⁡2x)+(∣x∣−sin⁡(x[x]))2x2\lim\limits_{x\to0}\frac{\tan(\pi\sin^2x)+\left(|x|-\sin(x[x])\right)^2}{x^2}:

  1. A.equals π\pi
  2. B.equals 0
  3. C.equals π+1\pi+1
  4. D.does not exist

Correct answer: D

Question 66

Mathematics · 4 marks · −1

If xlog⁡e(log⁡ex)−x2+y2=4x\log_e(\log_e x)-x^2+y^2=4 (y>0)(y>0), then dydx\frac{dy}{dx} at x=ex=e is equal to:

  1. A.(2e−1)24+e2\frac{(2e-1)}{2\sqrt{4+e^2}}
  2. B.e4+e2\frac{e}{\sqrt{4+e^2}}
  3. C.(1+2e)24+e2\frac{(1+2e)}{2\sqrt{4+e^2}}
  4. D.(1+2e)4+e2\frac{(1+2e)}{\sqrt{4+e^2}}

Correct answer: A

Question 67

Mathematics · 4 marks · −1

Let f(x)={−1,−2≤x<0x2−1,0≤x≤2f(x)=\begin{cases}-1, & -2\le x<0\\ x^2-1, & 0\le x\le2\end{cases} and g(x)=∣f(x)∣+f(∣x∣)g(x)=|f(x)|+f(|x|). Then, in the interval (−2,2)(-2,2), gg is:

  1. A.not continuous
  2. B.not differentiable at one point
  3. C.not differentiable at two points
  4. D.differentiable at all points

Correct answer: B

Question 68

Mathematics · 4 marks · −1

The maximum value of the function f(x)=3x3−18x2+27x−40f(x)=3x^3-18x^2+27x-40 on the set S={x∈R:x2+30≤11x}S=\{x\in\mathbb{R}: x^2+30\le11x\} is:

  1. A.122
  2. B.−122-122
  3. C.222
  4. D.−222-222

Correct answer: A

Question 69

Mathematics · 4 marks · −1

If ∫1−x2x4 dx=A(x)(1−x2)m+C\int\frac{\sqrt{1-x^2}}{x^4}\,dx=A(x)\left(\sqrt{1-x^2}\right)^m+C, for a suitable chosen integer mm and a function A(x)A(x), where CC is a constant of integration, then (A(x))m(A(x))^m equals:

  1. A.19x4\frac{1}{9x^4}
  2. B.−13x3\frac{-1}{3x^3}
  3. C.−127x9\frac{-1}{27x^9}
  4. D.127x6\frac{1}{27x^6}

Correct answer: C

Question 70

Mathematics · 4 marks · −1

The value of the integral ∫−22sin⁡2x[xπ]+12 dx\int_{-2}^{2}\frac{\sin^2x}{\left[\frac{x}{\pi}\right]+\frac12}\,dx (where [x][x] denotes the greatest integer less than or equal to xx) is:

  1. A.4−sin⁡44-\sin4
  2. B.0
  3. C.4
  4. D.sin⁡4\sin4

Correct answer: B

Question 71

Mathematics · 4 marks · −1

The area (in sq. units) of the region bounded by the curve x2=4yx^2=4y and the straight line x=4y−2x=4y-2 is:

  1. A.34\frac34
  2. B.98\frac98
  3. C.54\frac54
  4. D.78\frac78

Correct answer: B

Question 72

Mathematics · 4 marks · −1

If y(x)y(x) is the solution of the differential equation dydx+(2x+1x)y=e−2x\frac{dy}{dx}+\left(\frac{2x+1}{x}\right)y=e^{-2x}, x>0x>0, where y(1)=12e−2y(1)=\frac12e^{-2}, then:

  1. A.y(log⁡e2)=log⁡e24y(\log_e2)=\frac{\log_e2}{4}
  2. B.y(log⁡e2)=log⁡e4y(\log_e2)=\log_e4
  3. C.y(x)y(x) is decreasing in (0,1)(0,1)
  4. D.y(x)y(x) is decreasing in (12,1)\left(\frac12,1\right)

Correct answer: D

Question 73

Mathematics · 4 marks · −1

Two circles with equal radii are intersecting at the points (0,1)(0,1) and (0,−1)(0,-1). The tangent at the point (0,1)(0,1) to one of the circles passes through the centre of the other circle. Then the distance between the centres of these circles is:

  1. A.222\sqrt2
  2. B.1
  3. C.2
  4. D.2\sqrt2

Correct answer: C

Question 74

Mathematics · 4 marks · −1

The straight line x+2y=1x+2y=1 meets the coordinate axes at A and B. A circle is drawn through A, B and the origin. Then the sum of perpendicular distances from A and B on the tangent to the circle at the origin is:

  1. A.454\sqrt5
  2. B.54\frac{\sqrt5}{4}
  3. C.252\sqrt5
  4. D.52\frac{\sqrt5}{2}

Correct answer: D

Question 75

Mathematics · 4 marks · −1

A square is inscribed in the circle x2+y2−6x+8y−103=0x^2+y^2-6x+8y-103=0 with its sides parallel to the coordinate axes. Then the distance of the vertex of this square which is nearest to the origin is:

  1. A.6
  2. B.41\sqrt{41}
  3. C.13
  4. D.137\sqrt{137}

Correct answer: B

Question 76

Mathematics · 4 marks · −1

The direction ratios of normal to the plane through the points (0,−1,0)(0,-1,0) and (0,0,1)(0,0,1) and making an angle π4\frac{\pi}{4} with the plane y−z+5=0y-z+5=0 are:

  1. A.2,1,−1\sqrt2,1,-1
  2. B.23,1,−12\sqrt3,1,-1
  3. C.2,−1,12,-1,1
  4. D.2,2,−22,\sqrt2,-\sqrt2

Correct answer: A

Question 77

Mathematics · 4 marks · −1

Let a⃗=i^+2j^+4k^\vec a=\hat i+2\hat j+4\hat k, b⃗=i^+λj^+4k^\vec b=\hat i+\lambda\hat j+4\hat k and c⃗=2i^+4j^+(λ2−1)k^\vec c=2\hat i+4\hat j+(\lambda^2-1)\hat k be coplanar vectors. Then the non-zero vector a⃗×c⃗\vec a\times\vec c is:

  1. A.−10i^−5j^-10\hat i-5\hat j
  2. B.−14i^−5j^-14\hat i-5\hat j
  3. C.−10i^+5j^-10\hat i+5\hat j
  4. D.−14i^+5j^-14\hat i+5\hat j

Correct answer: C

Question 78

Mathematics · 4 marks · −1

The outcome of each of 30 items was observed; 10 items gave an outcome 12−d\frac12-d each, 10 items gave outcome 12\frac12 each and the remaining 10 items gave outcome 12+d\frac12+d each. If the variance of this outcome data is 43\frac43 then ∣d∣|d| equals:

  1. A.2\sqrt2
  2. B.2
  3. C.52\frac{\sqrt5}{2}
  4. D.23\frac23

Correct answer: A

Question 79

Mathematics · 4 marks · −1

Two integers are selected at random from the set {1,2,…,11}\{1,2,\ldots,11\}. Given that the sum of selected numbers is even, the conditional probability that both the numbers are even is:

  1. A.25\frac25
  2. B.12\frac12
  3. C.35\frac35
  4. D.710\frac{7}{10}

Correct answer: A

Question 80

Mathematics · 4 marks · −1

Let fk(x)=1k(sin⁡kx+cos⁡kx)f_k(x)=\frac1k\left(\sin^kx+\cos^kx\right) for k=1,2,3,…k=1,2,3,\ldots Then for all x∈Rx\in\mathbb{R}, the value of f4(x)−f6(x)f_4(x)-f_6(x) is equal to:

  1. A.112\frac{1}{12}
  2. B.−112\frac{-1}{12}
  3. C.14\frac14
  4. D.512\frac{5}{12}

Correct answer: A

Question 81

Mathematics · 4 marks · −1

In a triangle, the sum of lengths of two sides is xx and the product of the lengths of the same two sides is yy. If x2−c2=yx^2-c^2=y, where cc is the length of the third side of the triangle, then the circumradius of the triangle is:

  1. A.c3\frac c3
  2. B.c3\frac{c}{\sqrt3}
  3. C.y3\frac{y}{\sqrt3}
  4. D.32y\frac32y

Correct answer: B

Question 82

Mathematics · 4 marks · −1

If qq is false and p∧q↔rp\wedge q\leftrightarrow r is true, then which one of the following statements is a tautology?

  1. A.p∧rp\wedge r
  2. B.p∨rp\vee r
  3. C.(p∧r)→(p∨r)(p\wedge r)\to(p\vee r)
  4. D.(p∨r)→(p∧r)(p\vee r)\to(p\wedge r)

Correct answer: C

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