JEE Main 2019 — 11 Jan Shift 2 (Previous Year Paper)

JEE Main · 2019 · with answers and explanations

questions
88
Total marks
352
Duration
180 minutes
Negative marking
−1

Subjects: Physics · Chemistry · Mathematics

Question 1

Physics · 4 marks · −1

If speed (V), acceleration (A) and force (F) are considered as fundamental units, the dimension of Young's modulus will be:

  1. A.V−4A2FV^{-4}A^{2}F
  2. B.V−4A−2FV^{-4}A^{-2}F
  3. C.V−2A2F2V^{-2}A^{2}F^{2}
  4. D.V−2A2F−2V^{-2}A^{2}F^{-2}

Correct answer: A

Question 2

Physics · 4 marks · −1

A particle moves from the point (2.0i^+4.0j^)(2.0\hat i+4.0\hat j) m, at t=0t=0, with an initial velocity (5.0i^+4.0j^) m s−1(5.0\hat i+4.0\hat j)\ \text{m s}^{-1}. It is acted upon by a constant force which produces a constant acceleration (4.0i^+4.0j^) m s−2(4.0\hat i+4.0\hat j)\ \text{m s}^{-2}. What is the distance of the particle from the origin at time 2 s?

  1. A.20220\sqrt2 m
  2. B.15 m
  3. C.10210\sqrt2 m
  4. D.5 m

Correct answer: A

Question 3

Physics · 4 marks · −1

The magnitude of torque on a particle of mass 1 kg is 2.5 Nm about the origin. If the force acting on it is 1 N, and the distance of the particle from the origin is 5 m, the angle between the force and the position vector is (in radians):

  1. A.π3\frac{\pi}{3}
  2. B.π6\frac{\pi}{6}
  3. C.π4\frac{\pi}{4}
  4. D.π8\frac{\pi}{8}

Correct answer: B

Question 4

Physics · 4 marks · −1

A particle of mass mm is moving in a straight line with momentum pp. Starting at time t=0t=0, a force F=ktF=kt acts in the same direction on the moving particle during time interval TT so that its momentum changes from pp to 3p3p. Here kk is a constant. The value of TT is:

  1. A.2pk\sqrt{\frac{2p}{k}}
  2. B.2pk2\sqrt{\frac{p}{k}}
  3. C.2kp2\sqrt{\frac{k}{p}}
  4. D.2kp\sqrt{\frac{2k}{p}}

Correct answer: B

Question 5

Physics · 4 marks · −1

A particle of mass mm and charge qq is in an electric and magnetic field given by E⃗=2i^+3j^\vec E=2\hat i+3\hat j; B⃗=4j^+6k^\vec B=4\hat j+6\hat k. The charged particle is shifted from the origin to the point P(x=1; y=1)P(x=1;\ y=1) along a straight path. The magnitude of the total work done is:

  1. A.5q5q
  2. B.(2.5)q(2.5)q
  3. C.(0.15)q(0.15)q
  4. D.(0.35)q(0.35)q

Correct answer: A

Question 6

Physics · 4 marks · −1

A string is wound around a hollow cylinder of mass 5 kg and radius 0.5 m. If the string is now pulled with a horizontal force of 40 N, and the cylinder is rolling without slipping on a horizontal surface (see figure), then the angular acceleration of the cylinder will be (Neglect the mass and thickness of the string):

Figure for question 6
  1. A.10 rad/s2^2
  2. B.12 rad/s2^2
  3. C.16 rad/s2^2
  4. D.20 rad/s2^2

Correct answer: C

Question 7

Physics · 4 marks · −1

A circular disc D1D_1 of mass MM and radius RR has two identical discs D2D_2 and D3D_3 of the same mass MM and radius RR attached rigidly at its opposite ends (see figure). The moment of inertia of the system about the axis OO′OO', passing through the centre of D1D_1, as shown in the figure, will be:

Figure for question 7
  1. A.MR2MR^2
  2. B.23MR2\frac23MR^2
  3. C.3MR23MR^2
  4. D.45MR2\frac45MR^2

Correct answer: C

Question 8

Physics · 4 marks · −1

The mass and the diameter of a planet are three times the respective values for the Earth. The period of oscillation of a simple pendulum on the Earth is 2 s. The period of oscillation of the same pendulum on the planet would be:

  1. A.32\frac32 s
  2. B.32\frac{\sqrt3}{2} s
  3. C.23\frac{2}{\sqrt3} s
  4. D.232\sqrt3 s

Correct answer: D

Question 9

Physics · 4 marks · −1

When 100 g of a liquid A at 100∘100^\circC is added to 50 g of a liquid B at temperature 75∘75^\circC, the temperature of the mixture becomes 90∘90^\circC. The temperature of the mixture, if 100 g of liquid A at 100∘100^\circC is added to 50 g of liquid B at 50∘50^\circC, will be:

  1. A.60∘60^\circC
  2. B.70∘70^\circC
  3. C.80∘80^\circC
  4. D.85∘85^\circC

Correct answer: C

Question 10

Physics · 4 marks · −1

In a process, temperature and volume of one mole of an ideal monoatomic gas are varied according to the relation VT=KVT=K, where KK is a constant. In this process the temperature of the gas is increased by ΔT\Delta T. The amount of heat absorbed by gas is (RR is gas constant):

  1. A.12RΔT\frac12R\Delta T
  2. B.12KRΔT\frac12KR\Delta T
  3. C.2K3ΔT\frac{2K}{3}\Delta T
  4. D.32RΔT\frac32R\Delta T

Correct answer: A

Question 11

Physics · 4 marks · −1

A metal ball of mass 0.1 kg is heated upto 500∘500^\circC and dropped into a vessel of heat capacity 800 J K−1^{-1} and containing 0.5 kg water. The initial temperature of water and vessel is 30∘30^\circC. What is the approximate percentage increment in the temperature of the water? [Specific Heat Capacities of water and metal are, respectively, 4200 J kg−1^{-1}K−1^{-1} and 400 J kg−1^{-1}K−1^{-1}]

  1. A.30%
  2. B.25%
  3. C.15%
  4. D.20%

Correct answer: D

Question 12

Physics · 4 marks · −1

A pendulum is executing simple harmonic motion and its maximum kinetic energy is K1K_1. If the length of the pendulum is doubled and it performs simple harmonic motion with the same amplitude as in the first case, its maximum kinetic energy is K2K_2. Then:

  1. A.K2=K1K_2=K_1
  2. B.K2=2K1K_2=2K_1
  3. C.K2=K12K_2=\frac{K_1}{2}
  4. D.K2=K14K_2=\frac{K_1}{4}

Correct answer: C

Question 13

Physics · 4 marks · −1

A simple pendulum of length 1 m is oscillating with an angular frequency 10 rad/s. The support of the pendulum starts oscillating up and down with a small angular frequency of 1 rad/s and an amplitude of 10−210^{-2} m. The relative change in the angular frequency of the pendulum is best given by:

  1. A.10−110^{-1} rad/s
  2. B.10−310^{-3} rad/s
  3. C.10−510^{-5} rad/s
  4. D.1 rad/s

Correct answer: B

Question 14

Physics · 4 marks · −1

Seven capacitors, each of capacitance 2 μ2\ \muF, are to be connected in a configuration to obtain an effective capacitance of (613) μ\left(\frac{6}{13}\right)\ \muF. Which of the combinations, shown in figures below, will achieve the desired value?

Figure for question 14
  1. A.Figure: 5 capacitors in parallel, followed in series by 2 capacitors.
  2. B.Figure: 4 capacitors in parallel, followed in series by 3 capacitors.
  3. C.Figure: 3 capacitors in parallel, followed in series by 4 capacitors.
  4. D.Figure: 2 capacitors in parallel, followed in series by 5 capacitors.

Correct answer: C

Question 15

Physics · 4 marks · −1

An electric field of 1000 V/m is applied to an electric dipole at angle of 45∘45^\circ. The value of electric dipole moment is 10−2910^{-29} C m. What is the potential energy of the electric dipole?

  1. A.−7×10−27-7\times10^{-27} J
  2. B.−10×10−29-10\times10^{-29} J
  3. C.−9×10−20-9\times10^{-20} J
  4. D.−20×10−18-20\times10^{-18} J

Correct answer: A

Question 16

Physics · 4 marks · −1

Two rods A and B of identical dimensions are at temperature 30∘30^\circC. If A is heated upto 180∘180^\circC and B upto T∘T^\circC, then the new lengths are the same. If the ratio of the coefficients of linear expansion of A and B is 4 : 3, then the value of TT is:

  1. A.200∘200^\circC
  2. B.230∘230^\circC
  3. C.250∘250^\circC
  4. D.270∘270^\circC

Correct answer: B

Question 17

Physics · 4 marks · −1

In the experimental set up of metre bridge shown in the figure, the null point is obtained at a distance of 40 cm from A. If a 10 Ω10\ \Omega resistor is connected in series with R1R_1, the null point shifts by 10 cm. The resistance that should be connected in parallel with (R1+10) Ω(R_1+10)\ \Omega such that the null point shifts back to its initial position is:

Figure for question 17
  1. A.60 Ω60\ \Omega
  2. B.40 Ω40\ \Omega
  3. C.30 Ω30\ \Omega
  4. D.20 Ω20\ \Omega

Correct answer: A

Question 18

Physics · 4 marks · −1

In the circuit shown, the potential difference between A and B is:

Figure for question 18
  1. A.2 V
  2. B.3 V
  3. C.6 V
  4. D.1 V

Correct answer: A

Question 19

Physics · 4 marks · −1

A paramagnetic substance in the form of a cube with sides 1 cm has a magnetic dipole moment of 20×10−620\times10^{-6} J/T when a magnetic intensity of 60×10360\times10^{3} A/m is applied. Its magnetic susceptibility is:

  1. A.3.3×10−23.3\times10^{-2}
  2. B.4.3×10−24.3\times10^{-2}
  3. C.2.3×10−22.3\times10^{-2}
  4. D.3.3×10−43.3\times10^{-4}

Correct answer: D

Question 20

Physics · 4 marks · −1

The region between y=0y=0 and y=dy=d contains a magnetic field B⃗=Bz^\vec B=B\hat z. A particle of mass mm and charge qq enters the region with a velocity v⃗=vi^\vec v=v\hat i. If d=mv2qBd=\frac{mv}{2qB}, the acceleration of the charged particle at the point of its emergence at the other side is:

  1. A.qvBm(32i^+12j^)\frac{qvB}{m}\left(\frac{\sqrt3}{2}\hat i+\frac12\hat j\right)
  2. B.qvBm(12i^−32j^)\frac{qvB}{m}\left(\frac12\hat i-\frac{\sqrt3}{2}\hat j\right)
  3. C.qvBm(i^+j^2)\frac{qvB}{m}\left(\frac{\hat i+\hat j}{\sqrt2}\right)
  4. D.qvBm(−j^+i^2)\frac{qvB}{m}\left(\frac{-\hat j+\hat i}{\sqrt2}\right)

Correct answer: A

Question 21

Physics · 4 marks · −1

A copper wire is wound on a wooden frame, whose shape is that of an equilateral triangle. If the linear dimension of each side of the frame is increased by a factor of 3, keeping the number of turns of the coil per unit length of the frame the same, then the self inductance of the coil:

  1. A.increases by a factor of 3
  2. B.decreases by a factor of 9
  3. C.increases by a factor of 27
  4. D.decreases by a factor of 939\sqrt3

Correct answer: C

Question 22

Physics · 4 marks · −1

A 27 mW laser beam has a cross-sectional area of 10 mm2^2. The magnitude of the maximum electric field in this electromagnetic wave is given by: [Given permittivity of space ϵ0=9×10−12\epsilon_0=9\times10^{-12} SI units, Speed of light c=3×108c=3\times10^{8} m/s]

  1. A.1.4 kV/m
  2. B.1 kV/m
  3. C.2 kV/m
  4. D.0.7 kV/m

Correct answer: A

Question 23

Physics · 4 marks · −1

A monochromatic light is incident at a certain angle on an equilateral triangular prism and suffers minimum deviation. If the refractive index of the material of the prism is 3\sqrt3, then the angle of incidence is:

  1. A.45∘45^\circ
  2. B.30∘30^\circ
  3. C.60∘60^\circ
  4. D.90∘90^\circ

Correct answer: C

Question 24

Physics · 4 marks · −1

In a photoelectric experiment, the wavelength of the light incident on a metal is changed from 300 nm to 400 nm. The decrease in the stopping potential is close to: (hce=1240\frac{hc}{e}=1240 nm-V)

  1. A.1.0 V
  2. B.2.0 V
  3. C.0.5 V
  4. D.1.5 V

Correct answer: A

Question 25

Physics · 4 marks · −1

In a hydrogen like atom, when an electron jumps from the M-shell to the L-shell, the wavelength of emitted radiation is λ\lambda. If an electron jumps from N-shell to the L-shell, the wavelength of emitted radiation will be:

  1. A.1625λ\frac{16}{25}\lambda
  2. B.2516λ\frac{25}{16}\lambda
  3. C.2027λ\frac{20}{27}\lambda
  4. D.2720λ\frac{27}{20}\lambda

Correct answer: C

Question 26

Physics · 4 marks · −1

The circuit shown below contains two ideal diodes, each with a forward resistance of 50 Ω50\ \Omega. If the battery voltage is 6 V, the current through the 100 Ω100\ \Omega resistance (in Amperes) is:

Figure for question 26
  1. A.0.020
  2. B.0.027
  3. C.0.030
  4. D.0.036

Correct answer: A

Question 27

Physics · 4 marks · −1

An amplitude modulated signal is plotted below: [graph of V(t)V(t) with maximum amplitude 10 V, minimum amplitude 8 V, envelope period 100 μ\mus and carrier period 8 μ\mus]. Which one of the following best describes the above signal?

Figure for question 27
  1. A.(9+sin⁡(2.5π×105t))sin⁡(2π×104t)(9+\sin(2.5\pi\times10^{5}t))\sin(2\pi\times10^{4}t) V
  2. B.(1+9sin⁡(2π×104t))sin⁡(2.5π×105t)(1+9\sin(2\pi\times10^{4}t))\sin(2.5\pi\times10^{5}t) V
  3. C.(9+sin⁡(4π×104t))sin⁡(5π×105t)(9+\sin(4\pi\times10^{4}t))\sin(5\pi\times10^{5}t) V
  4. D.(9+sin⁡(2π×104t))sin⁡(2.5π×105t)(9+\sin(2\pi\times10^{4}t))\sin(2.5\pi\times10^{5}t) V

Correct answer: D

Question 28

Physics · 4 marks · −1

A galvanometer having a resistance of 20 Ω20\ \Omega and 30 divisions on both sides has figure of merit 0.005 ampere/division. The resistance that should be connected in series such that it can be used as a voltmeter upto 15 volt, is:

  1. A.80 Ω80\ \Omega
  2. B.100 Ω100\ \Omega
  3. C.120 Ω120\ \Omega
  4. D.125 Ω125\ \Omega

Correct answer: A

Question 29

Physics · 4 marks · −1

A thermometer graduated according to a linear scale reads a value x0x_0 when in contact with boiling water, and x0/3x_0/3 when in contact with ice. What is the temperature of an object in ∘^\circC, if this thermometer in the contact with the object reads x0/2x_0/2?

  1. A.60
  2. B.25
  3. C.35
  4. D.40

Correct answer: B

Question 30

Chemistry · 4 marks · −1

Which of the following compounds reacts with ethylmagnesium bromide and also decolourizes bromine water solution:

Figure for question 30
  1. A.2-Vinylphenol (benzene ring with OH and an adjacent CH=CH2_2)
  2. B.Cyclohexene ring bearing CN and CH2_2CO2_2CH3_3 on adjacent carbons
  3. C.2-Acetylbenzonitrile (benzene ring with CN and an adjacent COCH3_3)
  4. D.2-Methoxystyrene (benzene ring with OCH3_3 and an adjacent CH=CH2_2)

Correct answer: A

Question 31

Chemistry · 4 marks · −1

The correct match between Item I and Item II is:<br>Item I: (A) Ester test (B) Carbylamine test (C) Phthalein dye test<br>Item II: (P) Tyr (Q) Asp (R) Ser (S) Lys

  1. A.(A)→\to(Q); (B)→\to(S); (C)→\to(R)
  2. B.(A)→\to(Q); (B)→\to(S); (C)→\to(P)
  3. C.(A)→\to(R); (B)→\to(Q); (C)→\to(P)
  4. D.(A)→\to(R); (B)→\to(S); (C)→\to(Q)

Correct answer: B

Question 32

Chemistry · 4 marks · −1

The homopolymer formed from 4-hydroxybutanoic acid is:

  1. A.[−O-C(=O)(CH2)3−O−]n\left[-\text{O-C(=O)(CH}_2)_3-\text{O}-\right]_n
  2. B.[−C(=O)(CH2)2C(=O)−]n\left[-\text{C(=O)(CH}_2)_2\text{C(=O)}-\right]_n
  3. C.[−C(=O)(CH2)2C(=O)-O−]n\left[-\text{C(=O)(CH}_2)_2\text{C(=O)-O}-\right]_n
  4. D.[−C(=O)(CH2)3−O−]n\left[-\text{C(=O)(CH}_2)_3-\text{O}-\right]_n

Correct answer: D

Question 33

Chemistry · 4 marks · −1

In the following compound (adenine, with sites labelled: (a) the exocyclic NH2_2, (b) and (c) the two pyrimidine-ring N atoms, (d) the imidazole-ring N=, (e) the imidazole N-H), the favourable site/s for protonation is/are:

Figure for question 33
  1. A.(a)
  2. B.(a) and (e)
  3. C.(b), (c) and (d)
  4. D.(a) and (d)

Correct answer: C

Question 34

Chemistry · 4 marks · −1

A compound 'X' on treatment with Br2_2/NaOH, provided C3_3H9_9N, which gives positive carbylamine test. Compound 'X' is:

  1. A.CH3_3CH2_2COCH2_2NH2_2
  2. B.CH3_3CH2_2CH2_2CONH2_2
  3. C.CH3_3CON(CH3_3)2_2
  4. D.CH3_3COCH2_2NHCH3_3

Correct answer: B

Question 35

Chemistry · 4 marks · −1

The major product obtained in the following reaction is: [cyclohexane ring bearing COOH, CH=CH2_2, COCH3_3 and NO2_2 groups] →LiAlH4 (excess)\xrightarrow{\text{LiAlH}_4\ (\text{excess})}

Figure for question 35
  1. A.COOH reduced to CH2_2OH and COCH3_3 reduced to CH(OH)CH3_3; NO2_2 and CH=CH2_2 unchanged
  2. B.COOH unchanged, COCH3_3 reduced to CH(OH)CH3_3; NO2_2 and CH=CH2_2 unchanged
  3. C.CH2_2OH, CH(OH)CH3_3, NH2_2, and the vinyl group reduced to ethyl
  4. D.CH2_2OH, CH(OH)CH3_3 and NH2_2 (NO2_2 reduced); CH=CH2_2 unchanged

Correct answer: D

Question 36

Chemistry · 4 marks · −1

The major product of the following reaction is: 3-(but-3-en-1-yl)phenol →(2) AlCl3 (anhyd.)(1) HCl\xrightarrow[\text{(2) AlCl}_3\ (\text{anhyd.})]{\text{(1) HCl}}

Figure for question 36
  1. A.Indane with a methyl group at C-1 and OH on the benzene ring adjacent (ortho) to the ring fusion near C-1
  2. B.Same indane skeleton as option 1 but with Cl in place of OH
  3. C.Indane with a methyl group at C-1 and OH on the benzene ring para to the C-1 ring-fusion carbon (1-methylindan-5-ol type)
  4. D.Same indane skeleton as option 3 but with Cl in place of OH

Correct answer: C

Question 37

Chemistry · 4 marks · −1

The major product obtained in the following conversion is: 2-(but-2-enoyl)phenyl acetate →MeOHBr2 (1 eqv.)\xrightarrow[\text{MeOH}]{\text{Br}_2\ (1\ \text{eqv.})}

Figure for question 37
  1. A.Ring-brominated: Br ortho to the acetoxy group, side chain unchanged
  2. B.Ring-brominated: Br para to the acetoxy group, side chain unchanged
  3. C.Ar-CO-CH(Br)-CH(OMe)-CH3_3 (Br on the carbon next to C=O, OMe on the next carbon)
  4. D.Ar-CO-CH(OMe)-CH(Br)-CH3_3 (OMe on the carbon next to C=O, Br on the next carbon)

Correct answer: C

Question 38

Chemistry · 4 marks · −1

Which of the following compounds will produce a precipitate with AgNO3_3?

Figure for question 38
  1. A.Bromobenzene
  2. B.Bromocyclohexane
  3. C.3-Bromopyridine
  4. D.7-Bromocyclohepta-1,3,5-triene (tropylium bromide)

Correct answer: D

Question 39

Chemistry · 4 marks · −1

The correct match between Item I and Item II is:<br>Item I: (A) Allosteric effect (B) Competitive inhibitor (C) Receptor (D) Poison<br>Item II: (P) Molecule binding to the active site of enzyme (Q) Molecule crucial for communication in the body (R) Molecule binding to a site other than the active site of enzyme (S) Molecule binding to the enzyme covalently

  1. A.(A)→\to(P); (B)→\to(R); (C)→\to(Q); (D)→\to(S)
  2. B.(A)→\to(P); (B)→\to(R); (C)→\to(S); (D)→\to(Q)
  3. C.(A)→\to(R); (B)→\to(P); (C)→\to(Q); (D)→\to(S)
  4. D.(A)→\to(R); (B)→\to(P); (C)→\to(S); (D)→\to(Q)

Correct answer: C

Question 40

Chemistry · 4 marks · −1

The correct option with respect to the Pauling electronegativity values of the elements is:

  1. A.Te > Se
  2. B.P > S
  3. C.Si < Al
  4. D.Ga < Ge

Correct answer: D

Question 41

Chemistry · 4 marks · −1

The reaction that does NOT define calcination is:

  1. A.Fe2O3⋅xH2O→ΔFe2O3+xH2O\text{Fe}_2\text{O}_3\cdot x\text{H}_2\text{O}\xrightarrow{\Delta}\text{Fe}_2\text{O}_3+x\text{H}_2\text{O}
  2. B.ZnCO3→ΔZnO+CO2\text{ZnCO}_3\xrightarrow{\Delta}\text{ZnO}+\text{CO}_2
  3. C.CaCO3⋅MgCO3→ΔCaO+MgO+2CO2\text{CaCO}_3\cdot\text{MgCO}_3\xrightarrow{\Delta}\text{CaO}+\text{MgO}+2\text{CO}_2
  4. D.2Cu2S+3O2→Δ2Cu2O+2SO22\text{Cu}_2\text{S}+3\text{O}_2\xrightarrow{\Delta}2\text{Cu}_2\text{O}+2\text{SO}_2

Correct answer: D

Question 42

Chemistry · 4 marks · −1

The hydride that is NOT electron deficient is:

  1. A.SiH4_4
  2. B.AlH3_3
  3. C.B2_2H6_6
  4. D.GaH3_3

Correct answer: A

Question 43

Chemistry · 4 marks · −1

Match the following items in column I with the corresponding items in column II.<br>Column I: (i) Na2_2CO$_3\cdot10H10H_2O(ii)Mg(HCOO (ii) Mg(HCO_3))_2$ (iii) NaOH (iv) Ca3_3Al2_2O6_6<br>Column II: (A) Portland cement ingredient (B) Castner-Kellner process (C) Solvay process (D) Temporary hardness

  1. A.(i)→\to(B); (ii)→\to(C); (iii)→\to(A); (iv)→\to(D)
  2. B.(i)→\to(C); (ii)→\to(B); (iii)→\to(D); (iv)→\to(A)
  3. C.(i)→\to(C); (ii)→\to(D); (iii)→\to(B); (iv)→\to(A)
  4. D.(i)→\to(D); (ii)→\to(A); (iii)→\to(B); (iv)→\to(C)

Correct answer: C

Question 44

Chemistry · 4 marks · −1

A‾→4KOH, O22B‾ (Green)+2H2O\underline{A}\xrightarrow{4\text{KOH},\ \text{O}_2}2\underline{B}\ (\text{Green})+2\text{H}_2\text{O}<br>3B‾→4HCl2C‾ (Purple)+MnO2+2H2O3\underline{B}\xrightarrow{4\text{HCl}}2\underline{C}\ (\text{Purple})+\text{MnO}_2+2\text{H}_2\text{O}<br>2C‾→H2O, KI2A‾+2KOH+D‾2\underline{C}\xrightarrow{\text{H}_2\text{O},\ \text{KI}}2\underline{A}+2\text{KOH}+\underline{D}<br>In the above sequence of reactions, A‾\underline{A} and D‾\underline{D}, respectively, are:

  1. A.KI and K2_2MnO4_4
  2. B.MnO2_2 and KIO3_3
  3. C.KIO3_3 and MnO2_2
  4. D.KI and KMnO4_4

Correct answer: B

Question 45

Chemistry · 4 marks · −1

The number of bridging CO ligand(s) and Co-Co bond(s) in Co2_2(CO)8_8, respectively are:

  1. A.0 and 2
  2. B.2 and 0
  3. C.2 and 1
  4. D.4 and 0

Correct answer: C

Question 46

Chemistry · 4 marks · −1

The coordination number of Th in K4_4[Th(C2_2O4_4)4_4(OH2_2)2_2] is: (C2_2O42−_4^{2-} = Oxalato)

  1. A.6
  2. B.8
  3. C.10
  4. D.14

Correct answer: C

Question 47

Chemistry · 4 marks · −1

Taj Mahal is being slowly disfigured and discoloured. This is primarily due to:

  1. A.soil pollution
  2. B.global warming
  3. C.acid rain
  4. D.water pollution

Correct answer: C

Question 48

Chemistry · 4 marks · −1

The higher concentration of which gas in air can cause stiffness of flower buds?

  1. A.SO2_2
  2. B.CO2_2
  3. C.NO2_2
  4. D.CO

Correct answer: A

Question 49

Chemistry · 4 marks · −1

25 ml of the given HCl solution requires 30 mL of 0.1 M sodium carbonate solution. What is the volume of this HCl solution required to titrate 30 mL of 0.2 M aqueous NaOH solution?

  1. A.25 mL
  2. B.50 mL
  3. C.75 mL
  4. D.12.5 mL

Correct answer: A

Question 50

Chemistry · 4 marks · −1

The radius of the largest sphere which fits properly at the centre of the edge of a body centred cubic unit cell is: (Edge length is represented by aa)

  1. A.0.134 a
  2. B.0.067 a
  3. C.0.027 a
  4. D.0.047 a

Correct answer: B

Question 51

Chemistry · 4 marks · −1

The de Broglie wavelength (λ\lambda) associated with a photoelectron varies with the frequency (ν\nu) of the incident radiation as, [ν0\nu_0 is threshold frequency]:

  1. A.λ∝1(ν−ν0)1/2\lambda\propto\frac{1}{(\nu-\nu_0)^{1/2}}
  2. B.λ∝1(ν−ν0)\lambda\propto\frac{1}{(\nu-\nu_0)}
  3. C.λ∝1(ν−ν0)1/4\lambda\propto\frac{1}{(\nu-\nu_0)^{1/4}}
  4. D.λ∝1(ν−ν0)3/2\lambda\propto\frac{1}{(\nu-\nu_0)^{3/2}}

Correct answer: A

Question 52

Chemistry · 4 marks · −1

The standard reaction Gibbs energy for a chemical reaction at an absolute temperature TT is given by ΔrG∘=A−BT\Delta_rG^\circ=A-BT, where A and B are non-zero constants. Which of the following is TRUE about this reaction?

  1. A.Endothermic if A>0A>0
  2. B.Exothermic if B<0B<0
  3. C.Endothermic if A<0A<0 and B>0B>0
  4. D.Exothermic if A>0A>0 and B<0B<0

Correct answer: A

Question 53

Chemistry · 4 marks · −1

The reaction, MgO(s)+C(s)→Mg(s)+CO(g)\text{MgO(s)}+\text{C(s)}\to\text{Mg(s)}+\text{CO(g)}, for which ΔrH∘=+491.1\Delta_rH^\circ=+491.1 kJ mol−1^{-1} and ΔrS∘=198.0\Delta_rS^\circ=198.0 J K−1^{-1} mol−1^{-1}, is not feasible at 298 K. Temperature above which reaction will be feasible is:

  1. A.2040.5 K
  2. B.2480.3 K
  3. C.2380.5 K
  4. D.1890.0 K

Correct answer: B

Question 54

Chemistry · 4 marks · −1

K2_2HgI4_4 is 40% ionised in aqueous solution. The value of its van't Hoff factor (ii) is:

  1. A.1.6
  2. B.1.8
  3. C.2.0
  4. D.2.2

Correct answer: B

Question 55

Chemistry · 4 marks · −1

For the equilibrium, 2H2O⇌H3O++OH−2\text{H}_2\text{O}\rightleftharpoons\text{H}_3\text{O}^++\text{OH}^-, the value of ΔG∘\Delta G^\circ at 298 K is approximately:

  1. A.−100-100 kJ mol−1^{-1}
  2. B.−80-80 kJ mol−1^{-1}
  3. C.80 kJ mol−1^{-1}
  4. D.100 kJ mol−1^{-1}

Correct answer: C

Question 56

Chemistry · 4 marks · −1

Given the equilibrium constant KCK_C of the reaction: Cu(s)+2Ag+(aq)→Cu2+(aq)+2Ag(s)\text{Cu(s)}+2\text{Ag}^+(\text{aq})\to\text{Cu}^{2+}(\text{aq})+2\text{Ag(s)} is 10×101510\times10^{15}, calculate the Ecell∘E^\circ_{\text{cell}} of this reaction at 298 K. [2.303RTF2.303\frac{RT}{F} at 298 K =0.059=0.059 V]

  1. A.0.04736 V
  2. B.0.4736 V
  3. C.0.04736 mV
  4. D.0.4736 mV

Correct answer: B

Question 57

Chemistry · 4 marks · −1

The reaction 2X→B2X\to B is a zeroth order reaction. If the initial concentration of X is 0.2 M, the half-life is 6 h. When the initial concentration of X is 0.5 M, the time required to reach its final concentration of 0.2 M will be:

  1. A.7.2 h
  2. B.18.0 h
  3. C.9.0 h
  4. D.12.0 h

Correct answer: B

Question 58

Chemistry · 4 marks · −1

Among the colloids cheese (C), milk (M) and smoke (S), the correct combination of the dispersed phase and dispersion medium, respectively is:

  1. A.C: solid in liquid; M: liquid in liquid; S: gas in solid
  2. B.C: solid in liquid; M: solid in liquid; S: solid in gas
  3. C.C: liquid in solid; M: liquid in solid; S: solid in gas
  4. D.C: liquid in solid; M: liquid in liquid; S: solid in gas

Correct answer: D

Question 59

Mathematics · 4 marks · −1

Let a function f:(0,∞)→(0,∞)f:(0,\infty)\to(0,\infty) be defined by f(x)=∣1−1x∣f(x)=\left|1-\frac1x\right|. Then ff is:

  1. A.injective only
  2. B.not injective but it is surjective
  3. C.neither injective nor surjective
  4. D.both injective as well as surjective

Correct answer: B

Question 60

Mathematics · 4 marks · −1

Let zz be a complex number such that ∣z∣+z=3+i|z|+z=3+i (where i=−1i=\sqrt{-1}). Then ∣z∣|z| is equal to:

  1. A.53\frac53
  2. B.54\frac54
  3. C.343\frac{\sqrt{34}}{3}
  4. D.414\frac{\sqrt{41}}{4}

Correct answer: A

Question 61

Mathematics · 4 marks · −1

Let α\alpha and β\beta be the roots of the quadratic equation x2sin⁡θ−x(sin⁡θcos⁡θ+1)+cos⁡θ=0x^2\sin\theta-x(\sin\theta\cos\theta+1)+\cos\theta=0 (0<θ<45∘)(0<\theta<45^\circ), and α<β\alpha<\beta. Then ∑n=0∞(αn+(−1)nβn)\sum_{n=0}^{\infty}\left(\alpha^n+\frac{(-1)^n}{\beta^n}\right) is equal to:

  1. A.11+cos⁡θ−11−sin⁡θ\frac{1}{1+\cos\theta}-\frac{1}{1-\sin\theta}
  2. B.11−cos⁡θ−11+sin⁡θ\frac{1}{1-\cos\theta}-\frac{1}{1+\sin\theta}
  3. C.11+cos⁡θ+11−sin⁡θ\frac{1}{1+\cos\theta}+\frac{1}{1-\sin\theta}
  4. D.11−cos⁡θ+11+sin⁡θ\frac{1}{1-\cos\theta}+\frac{1}{1+\sin\theta}

Correct answer: D

Question 62

Mathematics · 4 marks · −1

Let A and B be two invertible matrices of order 3×33\times3. If det⁡(ABAT)=8\det(ABA^T)=8 and det⁡(AB−1)=8\det(AB^{-1})=8, then det⁡(BA−1BT)\det(BA^{-1}B^T) is equal to:

  1. A.1
  2. B.14\frac14
  3. C.16
  4. D.116\frac{1}{16}

Correct answer: D

Question 63

Mathematics · 4 marks · −1

If ∣a−b−c2a2a2bb−c−a2b2c2cc−a−b∣=(a+b+c)(x+a+b+c)2\begin{vmatrix}a-b-c&2a&2a\\2b&b-c-a&2b\\2c&2c&c-a-b\end{vmatrix}=(a+b+c)(x+a+b+c)^2, x≠0x\ne0 and a+b+c≠0a+b+c\ne0, then xx is equal to:

  1. A.abcabc
  2. B.2(a+b+c)2(a+b+c)
  3. C.−(a+b+c)-(a+b+c)
  4. D.−2(a+b+c)-2(a+b+c)

Correct answer: D

Question 64

Mathematics · 4 marks · −1

The number of functions ff from {1,2,3,…,20}\{1,2,3,\ldots,20\} onto {1,2,3,…,20}\{1,2,3,\ldots,20\} such that f(k)f(k) is a multiple of 3, whenever kk is a multiple of 4, is:

  1. A.5!×6!5!\times6!
  2. B.56×155^6\times15
  3. C.65×(15)!6^5\times(15)!
  4. D.(15)!×6!(15)!\times6!

Correct answer: D

Question 65

Mathematics · 4 marks · −1

Let (x+10)50+(x−10)50=a0+a1x+a2x2+…+a50x50(x+10)^{50}+(x-10)^{50}=a_0+a_1x+a_2x^2+\ldots+a_{50}x^{50}, for all x∈Rx\in\mathbb{R}; then a2a0\frac{a_2}{a_0} is equal to:

  1. A.12.75
  2. B.12.50
  3. C.12.25
  4. D.12.00

Correct answer: C

Question 66

Mathematics · 4 marks · −1

If 19th term of a non-zero A.P. is zero, then its (49th term) : (29th term) is:

  1. A.4 : 1
  2. B.1 : 3
  3. C.2 : 1
  4. D.3 : 1

Correct answer: D

Question 67

Mathematics · 4 marks · −1

Let Sn=1+q+q2+…+qnS_n=1+q+q^2+\ldots+q^n and Tn=1+(q+12)+(q+12)2+…+(q+12)nT_n=1+\left(\frac{q+1}{2}\right)+\left(\frac{q+1}{2}\right)^2+\ldots+\left(\frac{q+1}{2}\right)^n where qq is a real number and q≠1q\ne1. If 101C1+101C2⋅S1+…+101C101⋅S100=αT100{}^{101}C_1+{}^{101}C_2\cdot S_1+\ldots+{}^{101}C_{101}\cdot S_{100}=\alpha T_{100}, then α\alpha is equal to:

  1. A.202
  2. B.200
  3. C.21002^{100}
  4. D.2992^{99}

Correct answer: C

Question 68

Mathematics · 4 marks · −1

lim⁡x→0xcot⁡(4x)sin⁡2xcot⁡2(2x)\lim\limits_{x\to0}\frac{x\cot(4x)}{\sin^2x\cot^2(2x)} is equal to:

  1. A.2
  2. B.0
  3. C.1
  4. D.4

Correct answer: C

Question 69

Mathematics · 4 marks · −1

Let K be the set of all real values of xx where the function f(x)=sin⁡∣x∣−∣x∣+2(x−π)cos⁡∣x∣f(x)=\sin|x|-|x|+2(x-\pi)\cos|x| is not differentiable. Then the set K is equal to:

  1. A.{0}\{0\}
  2. B.{π}\{\pi\}
  3. C.{0,π}\{0,\pi\}
  4. D.ϕ\phi (an empty set)

Correct answer: D

Question 70

Mathematics · 4 marks · −1

Let f(x)=xa2+x2−d−xb2+(d−x)2f(x)=\frac{x}{\sqrt{a^2+x^2}}-\frac{d-x}{\sqrt{b^2+(d-x)^2}}, x∈Rx\in\mathbb{R}, where aa, bb and dd are non-zero real constants. Then:

  1. A.ff is an increasing function of xx
  2. B.ff is neither increasing nor decreasing function of xx
  3. C.ff is a decreasing function of xx
  4. D.f′f' is not a continuous function of xx

Correct answer: A

Question 71

Mathematics · 4 marks · −1

Let x,yx,y be positive real numbers and m,nm,n positive integers. The maximum value of the expression xmyn(1+x2m)(1+y2n)\frac{x^my^n}{(1+x^{2m})(1+y^{2n})} is:

  1. A.14\frac14
  2. B.1
  3. C.m+n6mn\frac{m+n}{6mn}
  4. D.12\frac12

Correct answer: A

Question 72

Mathematics · 4 marks · −1

If ∫x+12x−1 dx=f(x)2x−1+C\int\frac{x+1}{\sqrt{2x-1}}\,dx=f(x)\sqrt{2x-1}+C, where C is a constant of integration, then f(x)f(x) is equal to:

  1. A.13(x+1)\frac13(x+1)
  2. B.23(x+2)\frac23(x+2)
  3. C.23(x−4)\frac23(x-4)
  4. D.13(x+4)\frac13(x+4)

Correct answer: D

Question 73

Mathematics · 4 marks · −1

The integral ∫π/6π/4dxsin⁡2x (tan⁡5x+cot⁡5x)\int_{\pi/6}^{\pi/4}\frac{dx}{\sin2x\,(\tan^5x+\cot^5x)} equals:

  1. A.110(π4−tan⁡−1(193))\frac{1}{10}\left(\frac{\pi}{4}-\tan^{-1}\left(\frac{1}{9\sqrt3}\right)\right)
  2. B.15(π4−tan⁡−1(133))\frac15\left(\frac{\pi}{4}-\tan^{-1}\left(\frac{1}{3\sqrt3}\right)\right)
  3. C.π40\frac{\pi}{40}
  4. D.120tan⁡−1(193)\frac{1}{20}\tan^{-1}\left(\frac{1}{9\sqrt3}\right)

Correct answer: A

Question 74

Mathematics · 4 marks · −1

The area (in sq. units) in the first quadrant bounded by the parabola, y=x2+1y=x^2+1, the tangent to it at the point (2,5)(2,5) and the coordinate axes is:

  1. A.3724\frac{37}{24}
  2. B.83\frac83
  3. C.18724\frac{187}{24}
  4. D.143\frac{14}{3}

Correct answer: A

Question 75

Mathematics · 4 marks · −1

The solution of the differential equation, dydx=(x−y)2\frac{dy}{dx}=(x-y)^2, when y(1)=1y(1)=1, is:

  1. A.−log⁡e∣1−x+y1+x−y∣=2(x−1)-\log_e\left|\frac{1-x+y}{1+x-y}\right|=2(x-1)
  2. B.log⁡e∣2−y2−x∣=2(y−1)\log_e\left|\frac{2-y}{2-x}\right|=2(y-1)
  3. C.log⁡e∣2−x2−y∣=x−y\log_e\left|\frac{2-x}{2-y}\right|=x-y
  4. D.−log⁡e∣1+x−y1−x+y∣=x+y−2-\log_e\left|\frac{1+x-y}{1-x+y}\right|=x+y-2

Correct answer: A

Question 76

Mathematics · 4 marks · −1

If in a parallelogram ABDC, the coordinates of A, B and C are respectively (1,2)(1,2), (3,4)(3,4) and (2,5)(2,5), then the equation of the diagonal AD is:

  1. A.5x+3y−11=05x+3y-11=0
  2. B.5x−3y+1=05x-3y+1=0
  3. C.3x−5y+7=03x-5y+7=0
  4. D.3x+5y−13=03x+5y-13=0

Correct answer: B

Question 77

Mathematics · 4 marks · −1

Let the length of the latus rectum of an ellipse with its major axis along xx-axis and centre at the origin, be 8. If the distance between the foci of this ellipse is equal to the length of its minor axis, then which one of the following points lies on it?

  1. A.(42,22)(4\sqrt2,2\sqrt2)
  2. B.(42,23)(4\sqrt2,2\sqrt3)
  3. C.(43,23)(4\sqrt3,2\sqrt3)
  4. D.(43,22)(4\sqrt3,2\sqrt2)

Correct answer: D

Question 78

Mathematics · 4 marks · −1

A circle cuts a chord of length 4a4a on the xx-axis and passes through a point on the yy-axis, distant 2b2b from the origin. Then the locus of the centre of this circle, is:

  1. A.a straight line
  2. B.an ellipse
  3. C.a parabola
  4. D.a hyperbola

Correct answer: C

Question 79

Mathematics · 4 marks · −1

If the area of the triangle whose one vertex is at the vertex of the parabola, y2+4(x−a2)=0y^2+4(x-a^2)=0 and the other two vertices are the points of intersection of the parabola and yy-axis, is 250 sq. units, then a value of aa is:

  1. A.5(21/3)5(2^{1/3})
  2. B.(10)2/3(10)^{2/3}
  3. C.5
  4. D.555\sqrt5

Correct answer: C

Question 80

Mathematics · 4 marks · −1

If a hyperbola has length of its conjugate axis equal to 5 and the distance between its foci is 13, then the eccentricity of the hyperbola is:

  1. A.136\frac{13}{6}
  2. B.2
  3. C.138\frac{13}{8}
  4. D.1312\frac{13}{12}

Correct answer: D

Question 81

Mathematics · 4 marks · −1

Two lines x−31=y+13=z−6−1\frac{x-3}{1}=\frac{y+1}{3}=\frac{z-6}{-1} and x+57=y−2−6=z−34\frac{x+5}{7}=\frac{y-2}{-6}=\frac{z-3}{4} intersect at the point R. The reflection of R in the xyxy-plane has coordinates:

  1. A.(2,−4,−7)(2,-4,-7)
  2. B.(2,4,7)(2,4,7)
  3. C.(2,−4,7)(2,-4,7)
  4. D.(−2,4,7)(-2,4,7)

Correct answer: A

Question 82

Mathematics · 4 marks · −1

If the point (2,α,β)(2,\alpha,\beta) lies on the plane which passes through the points (3,4,2)(3,4,2) and (7,0,6)(7,0,6) and is perpendicular to the plane 2x−5y=152x-5y=15, then 2α−3β2\alpha-3\beta is equal to:

  1. A.17
  2. B.12
  3. C.5
  4. D.7

Correct answer: D

Question 83

Mathematics · 4 marks · −1

Let 3i^+j^\sqrt3\hat i+\hat j, i^+3j^\hat i+\sqrt3\hat j and βi^+(1−β)j^\beta\hat i+(1-\beta)\hat j respectively be the position vectors of the points A, B and C with respect to the origin O. If the distance of C from the bisector of the acute angle between OA and OB is 32\frac{3}{\sqrt2}, then the sum of all possible values of β\beta is:

  1. A.1
  2. B.2
  3. C.3
  4. D.4

Correct answer: A

Question 84

Mathematics · 4 marks · −1

A bag contains 30 white balls and 10 red balls. 16 balls are drawn one by one randomly from the bag with replacement. If X be the number of white balls drawn, then (mean of Xstandard deviation of X)\left(\frac{\text{mean of X}}{\text{standard deviation of X}}\right) is equal to:

  1. A.323\sqrt2
  2. B.433\frac{4\sqrt3}{3}
  3. C.434\sqrt3
  4. D.4

Correct answer: C

Question 85

Mathematics · 4 marks · −1

Let S={1,2,…,20}S=\{1,2,\ldots,20\}. A subset B of S is said to be \"nice\", if the sum of the elements of B is 203. Then the probability that a randomly chosen subset of S is \"nice\" is:

  1. A.5220\frac{5}{2^{20}}
  2. B.6220\frac{6}{2^{20}}
  3. C.4220\frac{4}{2^{20}}
  4. D.7220\frac{7}{2^{20}}

Correct answer: A

Question 86

Mathematics · 4 marks · −1

Given b+c11=c+a12=a+b13\frac{b+c}{11}=\frac{c+a}{12}=\frac{a+b}{13} for a ΔABC\Delta ABC with usual notation. If cos⁡Aα=cos⁡Bβ=cos⁡Cγ\frac{\cos A}{\alpha}=\frac{\cos B}{\beta}=\frac{\cos C}{\gamma}, then the ordered triad (α,β,γ)(\alpha,\beta,\gamma) has a value:

  1. A.(3,4,5)(3,4,5)
  2. B.(19,7,25)(19,7,25)
  3. C.(7,19,25)(7,19,25)
  4. D.(5,12,13)(5,12,13)

Correct answer: C

Question 87

Mathematics · 4 marks · −1

All xx satisfying the inequality (cot⁡−1x)2−7(cot⁡−1x)+10>0(\cot^{-1}x)^2-7(\cot^{-1}x)+10>0, lie in the interval:

  1. A.(cot⁡5,cot⁡4)(\cot5,\cot4)
  2. B.(cot⁡2,∞)(\cot2,\infty)
  3. C.(−∞,cot⁡5)∪(cot⁡4,cot⁡2)(-\infty,\cot5)\cup(\cot4,\cot2)
  4. D.(−∞,cot⁡5)∪(cot⁡2,∞)(-\infty,\cot5)\cup(\cot2,\infty)

Correct answer: B

Question 88

Mathematics · 4 marks · −1

Contrapositive of the statement \"If two numbers are not equal, then their squares are not equal.\" is:

  1. A.If the squares of two numbers are equal, then the numbers are not equal.
  2. B.If the squares of two numbers are not equal, then the numbers are not equal.
  3. C.If the squares of two numbers are not equal, then the numbers are equal.
  4. D.If the squares of two numbers are equal, then the numbers are equal.

Correct answer: D

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