JEE Main 2019 — 12 Jan Shift 1 (Previous Year Paper)

JEE Main · 2019 · with answers and explanations

questions
89
Total marks
356
Duration
180 minutes
Negative marking
−1

Subjects: Physics · Chemistry · Mathematics

Question 1

Physics · 4 marks · −1

The least count of the main scale of a screw gauge is 1 mm. The minimum number of divisions on its circular scale required to measure 5 μ\mum diameter of a wire is:

  1. A.50
  2. B.100
  3. C.200
  4. D.500

Correct answer: C

Question 2

Physics · 4 marks · −1

A person standing on an open ground hears the sound of a jet aeroplane, coming from north at an angle 60∘60^\circ with ground level. But he finds the aeroplane right vertically above his position. If vv is the speed of sound, speed of the plane is:

  1. A.vv
  2. B.v2\frac{v}{2}
  3. C.32v\frac{\sqrt3}{2}v
  4. D.2v3\frac{2v}{\sqrt3}

Correct answer: B

Question 3

Physics · 4 marks · −1

A passenger train of length 60 m travels at a speed of 80 km/hr. Another freight train of length 120 m travels at a speed of 30 km/hr. The ratio of times taken by the passenger train to completely cross the freight train when: (i) they are moving in the same direction, and (ii) in the opposite directions is:

  1. A.2511\frac{25}{11}
  2. B.115\frac{11}{5}
  3. C.52\frac52
  4. D.32\frac32

Correct answer: B

Question 4

Physics · 4 marks · −1

A simple pendulum, made of a string of length ll and a bob of mass mm, is released from a small angle θ0\theta_0. It strikes a block of mass M, kept on a horizontal surface at its lowest point of oscillations, elastically. It bounces back and goes up to an angle θ1\theta_1. Then M is given by:

  1. A.m2(θ0−θ1θ0+θ1)\frac m2\left(\frac{\theta_0-\theta_1}{\theta_0+\theta_1}\right)
  2. B.m2(θ0+θ1θ0−θ1)\frac m2\left(\frac{\theta_0+\theta_1}{\theta_0-\theta_1}\right)
  3. C.m(θ0+θ1θ0−θ1)m\left(\frac{\theta_0+\theta_1}{\theta_0-\theta_1}\right)
  4. D.m(θ0−θ1θ0+θ1)m\left(\frac{\theta_0-\theta_1}{\theta_0+\theta_1}\right)

Correct answer: C

Question 5

Physics · 4 marks · −1

A satellite of mass M is in a circular orbit of radius R about the centre of the earth. A meteorite of the same mass, falling towards the earth, collides with the satellite completely inelastically. The speeds of the satellite and the meteorite are the same, just before the collision. The subsequent motion of the combined body will be:

  1. A.in the same circular orbit of radius R
  2. B.in a circular orbit of a different radius
  3. C.in an elliptical orbit
  4. D.such that it escapes to infinity

Correct answer: C

Question 6

Physics · 4 marks · −1

The position vector of the centre of mass r⃗cm\vec r_{cm} of an asymmetric uniform bar of negligible area of cross-section as shown in figure is:

Figure for question 6
  1. A.r⃗cm=138Lx^+58Ly^\vec r_{cm}=\frac{13}{8}L\hat x+\frac58L\hat y
  2. B.r⃗cm=58Lx^+138Ly^\vec r_{cm}=\frac58L\hat x+\frac{13}{8}L\hat y
  3. C.r⃗cm=118Lx^+38Ly^\vec r_{cm}=\frac{11}{8}L\hat x+\frac38L\hat y
  4. D.r⃗cm=38Lx^+118Ly^\vec r_{cm}=\frac38L\hat x+\frac{11}{8}L\hat y

Correct answer: A

Question 7

Physics · 4 marks · −1

Let the moment of inertia of a hollow cylinder of length 30 cm (inner radius 10 cm and outer radius 20 cm), about its axis be I. The radius of a thin cylinder of the same mass such that its moment of inertia about its axis is also I, is:

  1. A.14 cm
  2. B.12 cm
  3. C.18 cm
  4. D.16 cm

Correct answer: D

Question 8

Physics · 4 marks · −1

A straight rod of length L extends from x=ax=a to x=L+ax=L+a. The gravitational force it exerts on a point mass mm at x=0x=0, if the mass per unit length of the rod is A+Bx2A+Bx^2, is given by:

  1. A.Gm[A(1a+L−1a)+BL]Gm\left[A\left(\frac{1}{a+L}-\frac1a\right)+BL\right]
  2. B.Gm[A(1a−1a+L)+BL]Gm\left[A\left(\frac1a-\frac{1}{a+L}\right)+BL\right]
  3. C.Gm[A(1a+L−1a)−BL]Gm\left[A\left(\frac{1}{a+L}-\frac1a\right)-BL\right]
  4. D.Gm[A(1a−1a+L)−BL]Gm\left[A\left(\frac1a-\frac{1}{a+L}\right)-BL\right]

Correct answer: B

Question 9

Physics · 4 marks · −1

A cylinder of radius R is surrounded by a cylindrical shell of inner radius R and outer radius 2R. The thermal conductivity of the material of the inner cylinder is K1K_1 and that of the outer cylinder is K2K_2. Assuming no loss of heat, the effective thermal conductivity of the system for heat flowing along the length of the cylinder is:

  1. A.K1+K2K_1+K_2
  2. B.K1+K22\frac{K_1+K_2}{2}
  3. C.K1+3K24\frac{K_1+3K_2}{4}
  4. D.2K1+3K25\frac{2K_1+3K_2}{5}

Correct answer: C

Question 10

Physics · 4 marks · −1

For the given cyclic process CAB as shown for a gas, the work done is:

Figure for question 10
  1. A.30 J
  2. B.10 J
  3. C.5 J
  4. D.1 J

Correct answer: B

Question 11

Physics · 4 marks · −1

An ideal gas occupies a volume of 2 m3^3 at a pressure of 3×1063\times10^{6} Pa. The energy of the gas is:

  1. A.10810^{8} J
  2. B.3×1023\times10^{2} J
  3. C.9×1069\times10^{6} J
  4. D.6×1046\times10^{4} J

Correct answer: C

Question 12

Physics · 4 marks · −1

Two light identical springs of spring constant kk are attached horizontally at the two ends of a uniform horizontal rod AB of length ll and mass mm. The rod is pivoted at its centre 'O' and can rotate freely in horizontal plane. The other ends of the two springs are fixed to rigid supports as shown in figure. The rod is gently pushed through a small angle and released. The frequency of resulting oscillation is:

Figure for question 12
  1. A.12π2km\frac{1}{2\pi}\sqrt{\frac{2k}{m}}
  2. B.12πkm\frac{1}{2\pi}\sqrt{\frac km}
  3. C.12π3km\frac{1}{2\pi}\sqrt{\frac{3k}{m}}
  4. D.12π6km\frac{1}{2\pi}\sqrt{\frac{6k}{m}}

Correct answer: D

Question 13

Physics · 4 marks · −1

A travelling harmonic wave is represented by the equation y(x,t)=10−3sin⁡(50t+2x)y(x,t)=10^{-3}\sin(50t+2x), where xx and yy are in meter and tt is in seconds. Which of the following is a correct statement about the wave?

  1. A.The wave is propagating along the positive xx-axis with speed 25 m s−1^{-1}.
  2. B.The wave is propagating along the negative xx-axis with speed 25 m s−1^{-1}.
  3. C.The wave is propagating along the positive xx-axis with speed 100 m s−1^{-1}.
  4. D.The wave is propagating along the negative xx-axis with speed 100 m s−1^{-1}.

Correct answer: B

Question 14

Physics · 4 marks · −1

In the figure shown, after the switch 'S' is turned from position 'A' to position 'B', the energy dissipated in the circuit in terms of capacitance 'C' and total charge 'Q' is:

Figure for question 14
  1. A.34Q2C\frac34\frac{Q^2}{C}
  2. B.18Q2C\frac18\frac{Q^2}{C}
  3. C.58Q2C\frac58\frac{Q^2}{C}
  4. D.38Q2C\frac38\frac{Q^2}{C}

Correct answer: D

Question 15

Physics · 4 marks · −1

Determine the electric dipole moment of the system of three charges, placed on the vertices of an equilateral triangle, as shown in the figure:

Figure for question 15
  1. A.(ql)i^+j^2(ql)\frac{\hat i+\hat j}{\sqrt2}
  2. B.−3qlj^-\sqrt3ql\hat j
  3. C.2qlj^2ql\hat j
  4. D.3qlj^−i^2\sqrt3ql\frac{\hat j-\hat i}{\sqrt2}

Correct answer: B

Question 16

Physics · 4 marks · −1

There is a uniform spherically symmetric surface charge density at a distance R0R_0 from the origin. The charge distribution is initially at rest and starts expanding because of mutual repulsion. The figure that represents best the speed V(R(t))V(R(t)) of the distribution as a function of its instantaneous radius R(t)R(t) is:

Figure for question 16
  1. A.Graph: V starts at zero at R0R_0 and increases ever more steeply (concave up, unbounded).
  2. B.Graph: V rises from zero at R0R_0 to a maximum and then decreases.
  3. C.Graph: V rises from zero at R0R_0 steeply at first and then levels off towards a constant value V0V_0 (concave down, saturating).
  4. D.Graph: V rises slowly, then steeply, then levels off (S-shaped curve).

Correct answer: C

Question 17

Physics · 4 marks · −1

An ideal battery of 4 V and resistance R are connected in series in the primary circuit of a potentiometer of length 1 m and resistance 5 Ω5\ \Omega. The value of R, to give a potential difference of 5 mV across 10 cm of potentiometer wire, is:

  1. A.480 Ω480\ \Omega
  2. B.490 Ω490\ \Omega
  3. C.495 Ω495\ \Omega
  4. D.395 Ω395\ \Omega

Correct answer: D

Question 18

Physics · 4 marks · −1

Two electric bulbs, rated at (25 W, 220 V) and (100 W, 220 V), are connected in series across a 220 V voltage source. If the 25 W and 100 W bulbs draw powers P1P_1 and P2P_2 respectively, then:

  1. A.P1=9P_1=9 W, P2=16P_2=16 W
  2. B.P1=16P_1=16 W, P2=9P_2=9 W
  3. C.P1=16P_1=16 W, P2=4P_2=4 W
  4. D.P1=4P_1=4 W, P2=16P_2=16 W

Correct answer: C

Question 19

Physics · 4 marks · −1

As shown in the figure, two infinitely long, identical wires are bent by 90∘90^\circ and placed in such a way that the segments LP and QM are along the xx-axis, while segments PS and QN are parallel to the yy-axis. If OP = OQ = 4 cm, and the magnitude of the magnetic field at O is 10−410^{-4} T, and the two wires carry equal currents (see figure), the magnitude of the current in each wire and the direction of the magnetic field at O will be (μ0=4π×10−7\mu_0=4\pi\times10^{-7} N A−2^{-2}):

Figure for question 19
  1. A.20 A, perpendicular into the page
  2. B.20 A, perpendicular out of the page
  3. C.40 A, perpendicular into the page
  4. D.40 A, perpendicular out of the page

Correct answer: A

Question 20

Physics · 4 marks · −1

A proton and an α\alpha-particle (with their masses in the ratio of 1 : 4 and charges in the ratio of 1 : 2) are accelerated from rest through a potential difference V. If a uniform magnetic field (B) is set up perpendicular to their velocities, the ratio of the radii rp:rαr_p:r_\alpha of the circular paths described by them will be:

  1. A.1 : 2
  2. B.1:21:\sqrt2
  3. C.1 : 3
  4. D.1:31:\sqrt3

Correct answer: B

Question 21

Physics · 4 marks · −1

In the figure shown, a circuit contains two identical resistors with resistance R=5 ΩR=5\ \Omega and an inductance with L=2L=2 mH. An ideal battery of 15 V is connected in the circuit. What will be the current through the battery long after the switch is closed?

Figure for question 21
  1. A.5.5 A
  2. B.7.5 A
  3. C.6 A
  4. D.3 A

Correct answer: C

Question 22

Physics · 4 marks · −1

A light wave is incident normally on a glass slab of refractive index 1.5. If 4% of light gets reflected and the amplitude of the electric field of the incident light is 30 V/m, then the amplitude of the electric field for the wave propagating in the glass medium will be:

  1. A.10 V/m
  2. B.24 V/m
  3. C.6 V/m
  4. D.30 V/m

Correct answer: B

Question 23

Physics · 4 marks · −1

What is the position and nature of image formed by lens combination shown in figure? (f1,f2f_1,f_2 are focal lengths)

Figure for question 23
  1. A.40 cm from point B at right; real
  2. B.70 cm from point B at left; virtual
  3. C.70 cm from point B at right; real
  4. D.203\frac{20}{3} cm from point B at right, real

Correct answer: C

Question 24

Physics · 4 marks · −1

A point source of light, S is placed at a distance L in front of the centre of plane mirror of width d which is hanging vertically on a wall. A man walks in front of the mirror along a line parallel to the mirror, at a distance 2L as shown below. The distance over which the man can see the image of the light source in the mirror is:

Figure for question 24
  1. A.d2\frac d2
  2. B.3d
  3. C.2d
  4. D.d

Correct answer: B

Question 25

Physics · 4 marks · −1

A particle A of mass mm and charge qq is accelerated by a potential difference of 50 V. Another particle B of mass 4m4m and charge qq is accelerated by a potential difference of 2500 V. The ratio of de-Broglie wavelengths λAλB\frac{\lambda_A}{\lambda_B} is close to:

  1. A.4.47
  2. B.10.00
  3. C.0.07
  4. D.14.14

Correct answer: D

Question 26

Physics · 4 marks · −1

A particle of mass mm moves in a circular orbit in a central potential field U(r)=12kr2U(r)=\frac12kr^2. If Bohr's quantization conditions are applied, radii of possible orbits and energy levels vary with quantum number nn as:

  1. A.rn∝n2r_n\propto n^2, En∝1n2E_n\propto\frac{1}{n^2}
  2. B.rn∝nr_n\propto n, En∝nE_n\propto n
  3. C.rn∝nr_n\propto\sqrt n, En∝1nE_n\propto\frac1n
  4. D.rn∝nr_n\propto\sqrt n, En∝nE_n\propto n

Correct answer: D

Question 27

Physics · 4 marks · −1

The output of the given logic circuit is:

Figure for question 27
  1. A.ABˉ+AˉBA\bar B+\bar AB
  2. B.ABˉA\bar B
  3. C.AˉB\bar AB
  4. D.AB+AB‾AB+\overline{AB}

Correct answer: B

Question 28

Physics · 4 marks · −1

A 100 V carrier wave is made to vary between 160 V and 40 V by a modulating signal. What is the modulation index?

  1. A.0.3
  2. B.0.6
  3. C.0.5
  4. D.0.4

Correct answer: B

Question 29

Physics · 4 marks · −1

The galvanometer deflection, when key K1K_1 is closed but K2K_2 is open, equals θ0\theta_0 (see figure). On closing K2K_2 also and adjusting R2R_2 to 5 Ω5\ \Omega, the deflection in galvanometer becomes θ05\frac{\theta_0}{5}. The resistance of the galvanometer is, then, given by [Neglect the internal resistance of battery]:

Figure for question 29
  1. A.22 Ω22\ \Omega
  2. B.12 Ω12\ \Omega
  3. C.5 Ω5\ \Omega
  4. D.25 Ω25\ \Omega

Correct answer: A

Question 30

Physics · 4 marks · −1

In a meter bridge, the wire of length 1 m has a non-uniform cross-section such that, the variation dRdl\frac{dR}{dl} of its resistance R with length ll is dRdl∝1l\frac{dR}{dl}\propto\frac{1}{\sqrt l}. Two equal resistances are connected as shown in the figure. The galvanometer has zero deflection when the jockey is at point P. What is the length AP?

Figure for question 30
  1. A.0.2 m
  2. B.0.25 m
  3. C.0.3 m
  4. D.0.35 m

Correct answer: B

Question 31

Chemistry · 4 marks · −1

Poly-β\beta-hydroxybutyrate-co-β\beta-hydroxyvalerate (PHBV) is a copolymer of ______.

  1. A.2-hydroxybutanoic acid and 3-hydroxypentanoic acid
  2. B.3-hydroxybutanoic acid and 3-hydroxypentanoic acid
  3. C.3-hydroxybutanoic acid and 2-hydroxypentanoic acid
  4. D.3-hydroxybutanoic acid and 4-hydroxypentanoic acid

Correct answer: B

Question 32

Chemistry · 4 marks · −1

In the following reaction: Aldehyde + Alcohol →HCl\xrightarrow{\text{HCl}} Acetal. Aldehydes: HCHO, CH3_3CHO; Alcohols: t^tBuOH, MeOH. The best combination is:

  1. A.HCHO and MeOH
  2. B.HCHO and t^tBuOH
  3. C.CH3_3CHO and t^tBuOH
  4. D.CH3_3CHO and MeOH

Correct answer: A

Question 33

Chemistry · 4 marks · −1

The increasing order of reactivity of the following compounds towards reaction with alkyl halides directly is: (A) benzamide (B) phthalimide (C) 2-aminobenzonitrile (D) aniline

Figure for question 33
  1. A.(B) < (A) < (D) < (C)
  2. B.(A) < (B) < (C) < (D)
  3. C.(A) < (C) < (D) < (B)
  4. D.(B) < (A) < (C) < (D)

Correct answer: D

Question 34

Chemistry · 4 marks · −1

CH3CH2−C(OH)(Ph)−CH3\text{CH}_3\text{CH}_2-\text{C(OH)(Ph)}-\text{CH}_3 cannot be prepared by:

  1. A.PhCOCH3_3 + CH3_3CH2_2MgX
  2. B.CH3_3CH2_2COCH3_3 + PhMgX
  3. C.PhCOCH2_2CH3_3 + CH3_3MgX
  4. D.HCHO + PhCH(CH3_3)CH2_2MgX

Correct answer: D

Question 35

Chemistry · 4 marks · −1

In the following reactions, products A and B are: CH3CO−C(CH3)2−CH2CH2CHO→dil NaOH[A]\text{CH}_3\text{CO}-\text{C(CH}_3)_2-\text{CH}_2\text{CH}_2\text{CHO}\xrightarrow{\text{dil NaOH}}[A]; [A]→ΔH3O+[B][A]\xrightarrow[\Delta]{\text{H}_3\text{O}^+}[B]

Figure for question 35
  1. A.A = 5-hydroxy-2,2-dimethylcyclohexan-1-one; B = 6,6-dimethylcyclohex-2-en-1-one (C=C conjugated with C=O)
  2. B.A = 5-hydroxy-2,2-dimethylcyclohexan-1-one; B = 6,6-dimethylcyclohex-3-en-1-one (C=C not conjugated)
  3. C.A = cyclobutane bearing OH, two CH3_3 groups on one carbon, a CH3_3 and a CHO; B = the corresponding cyclobutene-carbaldehyde
  4. D.A = same cyclobutanol-aldehyde as option 3; B = the exocyclic methylene (C=CH2_2) cyclobutane-carbaldehyde

Correct answer: A

Question 36

Chemistry · 4 marks · −1

The major product of the following reaction is: [benzofuranone-type lactone: benzene ring fused to a five-membered lactone (ring O attached to the benzene, C=O on the CH2_2 side) and bearing a CN group ortho to the ring oxygen] →(ii) H3O+(i) DIBAL-H\xrightarrow[\text{(ii) H}_3\text{O}^+]{\text{(i) DIBAL-H}}

Figure for question 36
  1. A.Lactone intact, CN converted to CHO
  2. B.Benzene ring bearing CHO, OH (phenol) and CH2_2CHO on three adjacent carbons
  3. C.Benzene ring bearing CH=NH, OH and CH2_2CH2_2OH on adjacent carbons
  4. D.Dihydrobenzofuran (cyclic ether) bearing CHO

Correct answer: B

Question 37

Chemistry · 4 marks · −1

The major product of the following reaction is: 1-methoxy-3-(but-3-en-1-yl)benzene →(2) AlCl3 (anhyd.)(1) Cl2/CCl4\xrightarrow[\text{(2) AlCl}_3\ (\text{anhyd.})]{\text{(1) Cl}_2/\text{CCl}_4}

Figure for question 37
  1. A.Indane bearing a CH2_2Cl group at C-1, with OCH3_3 on the benzene carbon adjacent to the ring fusion
  2. B.Indane bearing a CH2_2Cl group at C-1, with OCH3_3 para to the C-1 ring-fusion carbon
  3. C.Tetralin (tetrahydronaphthalene) bearing Cl at C-2, with OCH3_3 adjacent to the ring fusion
  4. D.Tetralin bearing Cl at C-2, with OCH3_3 para to the ring fusion

Correct answer: B

Question 38

Chemistry · 4 marks · −1

Among the following compounds most basic amino acid is:

  1. A.Histidine
  2. B.Serine
  3. C.Lysine
  4. D.Asparagine

Correct answer: C

Question 39

Chemistry · 4 marks · −1

The correct order for acid strength of compounds CH≡\equivCH, CH3_3-C≡\equivCH and CH2_2=CH2_2 is as follows:

  1. A.HC≡\equivCH > CH3_3-C≡\equivCH > CH2_2=CH2_2
  2. B.CH3_3-C≡\equivCH > CH≡\equivCH > CH2_2=CH2_2
  3. C.CH3_3-C≡\equivCH > CH2_2=CH2_2 > HC≡\equivCH
  4. D.CH≡\equivCH > CH2_2=CH2_2 > CH3_3-C≡\equivCH

Correct answer: A

Question 40

Chemistry · 4 marks · −1

Among the following four aromatic compounds, which one will have the lowest melting point?

Figure for question 40
  1. A.Naphthalene
  2. B.2-Naphthol
  3. C.Phthalic acid (benzene-1,2-dicarboxylic acid)
  4. D.2,3-Diacetylnaphthalene (drawn with the two acetyl groups on adjacent carbons)

Correct answer: A

Question 41

Chemistry · 4 marks · −1

The element with Z = 120 (not yet discovered) will be an/a:

  1. A.alkali metal
  2. B.alkaline earth metal
  3. C.transition metal
  4. D.inner-transition metal

Correct answer: B

Question 42

Chemistry · 4 marks · −1

In the Hall-Heroult process, aluminium is formed at the cathode. The cathode is made out of:

  1. A.Platinum
  2. B.Pure aluminium
  3. C.Copper
  4. D.Carbon

Correct answer: D

Question 43

Chemistry · 4 marks · −1

The hardness of a water sample (in terms of equivalents of CaCO3_3) containing 10−310^{-3} M CaSO4_4 is: (molar mass of CaSO4_4 = 136 g mol−1^{-1})

  1. A.90 ppm
  2. B.100 ppm
  3. C.10 ppm
  4. D.50 ppm

Correct answer: B

Question 44

Chemistry · 4 marks · −1

A metal on combustion in excess air forms X. X upon hydrolysis with water yields H2_2O2_2 and O2_2 along with another product. The metal is:

  1. A.Li
  2. B.Na
  3. C.Rb
  4. D.Mg

Correct answer: C

Question 45

Chemistry · 4 marks · −1

Iodine reacts with concentrated HNO3_3 to yield Y along with other products. The oxidation state of iodine in Y, is:

  1. A.1
  2. B.3
  3. C.5
  4. D.7

Correct answer: C

Question 46

Chemistry · 4 marks · −1

The pair of metal ions that can give a spin-only magnetic moment of 3.9 BM for the complex [M(H2_2O)6_6]Cl2_2, is:

  1. A.Cr2+^{2+} and Mn2+^{2+}
  2. B.V2+^{2+} and Fe2+^{2+}
  3. C.V2+^{2+} and Co2+^{2+}
  4. D.Co2+^{2+} and Fe2+^{2+}

Correct answer: C

Question 47

Chemistry · 4 marks · −1

The metal d-orbitals that are directly facing the ligands in K3_3[Co(CN)6_6] are:

  1. A.dxyd_{xy} and dx2−y2d_{x^2-y^2}
  2. B.dxyd_{xy}, dxzd_{xz} and dyzd_{yz}
  3. C.dxzd_{xz}, dyzd_{yz} and dz2d_{z^2}
  4. D.dx2−y2d_{x^2-y^2} and dz2d_{z^2}

Correct answer: D

Question 48

Chemistry · 4 marks · −1

Mn2_2(CO)10_{10} is an organometallic compound due to the presence of:

  1. A.Mn-C bond
  2. B.Mn-Mn bond
  3. C.C-O bond
  4. D.Mn-O bond

Correct answer: A

Question 49

Chemistry · 4 marks · −1

Water samples with BOD values of 4 ppm and 18 ppm, respectively, are:

  1. A.Clean and Clean
  2. B.Highly polluted and Clean
  3. C.Clean and Highly polluted
  4. D.Highly polluted and Highly polluted

Correct answer: C

Question 50

Chemistry · 4 marks · −1

The molecule that has minimum/no role in the formation of photochemical smog, is:

  1. A.O3_3
  2. B.N2_2
  3. C.NO
  4. D.CH2_2=O

Correct answer: B

Question 51

Chemistry · 4 marks · −1

The volume of gas A is twice than that of gas B. The compressibility factor of gas A is thrice than that of gas B at same temperature. The pressures of the gases for equal number of moles are:

  1. A.PA=2PBP_A=2P_B
  2. B.PA=3PBP_A=3P_B
  3. C.2PA=3PB2P_A=3P_B
  4. D.3PA=2PB3P_A=2P_B

Correct answer: C

Question 52

Chemistry · 4 marks · −1

What is the work function of the metal if the light of wavelength 4000 Å generates photoelectrons of velocity 6×1056\times10^{5} m s−1^{-1} from it? (Mass of electron =9×10−31=9\times10^{-31} kg, Velocity of light =3×108=3\times10^{8} m s−1^{-1}, Planck's constant =6.626×10−34=6.626\times10^{-34} J s, Charge of electron =1.6×10−19=1.6\times10^{-19} J eV−1^{-1})

  1. A.4.0 eV
  2. B.2.1 eV
  3. C.0.9 eV
  4. D.3.1 eV

Correct answer: B

Question 53

Chemistry · 4 marks · −1

Two solids dissociate as follows: A(s)⇌B(g)+C(g)\text{A(s)}\rightleftharpoons\text{B(g)}+\text{C(g)}; KP1=xK_{P_1}=x atm2^2 and D(s)⇌C(g)+E(g)\text{D(s)}\rightleftharpoons\text{C(g)}+\text{E(g)}; KP2=yK_{P_2}=y atm2^2. The total pressure when both the solids dissociate simultaneously is:

  1. A.x+y\sqrt{x+y} atm
  2. B.(x+y)(x+y) atm
  3. C.2(x+y)2\left(\sqrt{x+y}\right) atm
  4. D.x2+y2x^2+y^2 atm

Correct answer: C

Question 54

Chemistry · 4 marks · −1

For a diatomic ideal gas in a closed system, which of the following plots does not correctly describe the relation between various thermodynamic quantities?

Figure for question 54
  1. A.Graph: U versus T - straight line with a steeper segment in the middle (slope increases stepwise).
  2. B.Graph: CvC_v versus T - constant, then rising to a higher constant plateau (step).
  3. C.Graph: CpC_p versus P - straight line increasing with P.
  4. D.Graph: CvC_v versus V - horizontal line (constant).

Correct answer: C

Question 55

Chemistry · 4 marks · −1

Freezing point of a 4% aqueous solution of X is equal to freezing point of 12% aqueous solution of Y. If molecular weight of X is A, then molecular weight of Y is:

  1. A.A
  2. B.2A
  3. C.3A
  4. D.4A

Correct answer: C

Question 56

Chemistry · 4 marks · −1

In a chemical reaction, A+2B⇌K2C+D\text{A}+2\text{B}\overset{K}{\rightleftharpoons}2\text{C}+\text{D}, the initial concentration of B was 1.5 times of the concentration of A, but the equilibrium concentrations of A and B were found to be equal. The equilibrium constant (K) for the aforesaid chemical reaction is:

  1. A.14\frac14
  2. B.4
  3. C.1
  4. D.16

Correct answer: B

Question 57

Chemistry · 4 marks · −1

The standard electrode potential E⊖E^\ominus and its temperature coefficient (dE⊖dT)\left(\frac{dE^\ominus}{dT}\right) for a cell are 2 V and −5×10−4-5\times10^{-4} V K−1^{-1} at 300 K respectively. The cell reaction is Zn(s)+Cu2+(aq)→Zn2+(aq)+Cu(s)\text{Zn(s)}+\text{Cu}^{2+}(\text{aq})\to\text{Zn}^{2+}(\text{aq})+\text{Cu(s)}. The standard reaction enthalpy (ΔrH⊖\Delta_rH^\ominus) at 300 K in kJ mol−1^{-1} is, [Use R=8R=8 J K−1^{-1} mol−1^{-1} and F=96,000F=96{,}000 C mol−1^{-1}]

  1. A.−412.8-412.8
  2. B.206.4
  3. C.−384.0-384.0
  4. D.192.0

Correct answer: A

Question 58

Chemistry · 4 marks · −1

Decomposition of X exhibits a rate constant of 0.05 μ\mug/year. How many years are required for the decomposition of 5 μ\mug of X into 2.5 μ\mug?

  1. A.20
  2. B.50
  3. C.25
  4. D.40

Correct answer: B

Question 59

Chemistry · 4 marks · −1

Given: critical temperatures (K) - H2_2: 33, CH4_4: 190, CO2_2: 304, SO2_2: 630. On the basis of data given above, predict which of the following gases shows least adsorption on a definite amount of charcoal?

  1. A.SO2_2
  2. B.CO2_2
  3. C.CH4_4
  4. D.H2_2

Correct answer: D

Question 60

Mathematics · 4 marks · −1

Let S={1,2,3,…,100}S=\{1,2,3,\ldots,100\}. The number of non-empty subsets A of S such that the product of elements in A is even is:

  1. A.2100−12^{100}-1
  2. B.250−12^{50}-1
  3. C.250(250−1)2^{50}(2^{50}-1)
  4. D.250+12^{50}+1

Correct answer: C

Question 61

Mathematics · 4 marks · −1

If z−αz+α\frac{z-\alpha}{z+\alpha} (α∈R)(\alpha\in\mathbb{R}) is a purely imaginary number and ∣z∣=2|z|=2, then a value of α\alpha is:

  1. A.12\frac12
  2. B.2
  3. C.2\sqrt2
  4. D.1

Correct answer: B

Question 62

Mathematics · 4 marks · −1

If λ\lambda be the ratio of the roots of the quadratic equation in xx, 3m2x2+m(m−4)x+2=03m^2x^2+m(m-4)x+2=0, then the least value of mm for which λ+1λ=1\lambda+\frac1\lambda=1, is:

  1. A.4−324-3\sqrt2
  2. B.4−234-2\sqrt3
  3. C.2−32-\sqrt3
  4. D.−2+2-2+\sqrt2

Correct answer: A

Question 63

Mathematics · 4 marks · −1

Let P=[100310931]P=\begin{bmatrix}1&0&0\\3&1&0\\9&3&1\end{bmatrix} and Q=[qij]Q=[q_{ij}] be two 3×33\times3 matrices such that Q−P5=I3Q-P^5=I_3. Then q21+q31q32\frac{q_{21}+q_{31}}{q_{32}} is equal to:

  1. A.9
  2. B.10
  3. C.15
  4. D.135

Correct answer: B

Question 64

Mathematics · 4 marks · −1

An ordered pair (α,β)(\alpha,\beta) for which the system of linear equations<br>(1+α)x+βy+z=2(1+\alpha)x+\beta y+z=2<br>αx+(1+β)y+z=3\alpha x+(1+\beta)y+z=3<br>αx+βy+2z=2\alpha x+\beta y+2z=2<br>has a unique solution, is:

  1. A.(1,−3)(1,-3)
  2. B.(−3,1)(-3,1)
  3. C.(−4,2)(-4,2)
  4. D.(2,4)(2,4)

Correct answer: D

Question 65

Mathematics · 4 marks · −1

Consider three boxes, each containing 10 balls labelled 1,2,…,101,2,\ldots,10. Suppose one ball is randomly drawn from each of the boxes. Denote by nin_i, the label of the ball drawn from the ithi^{\text{th}} box, (i=1,2,3)(i=1,2,3). Then, the number of ways in which the balls can be chosen such that n1<n2<n3n_1<n_2<n_3 is:

  1. A.120
  2. B.164
  3. C.82
  4. D.240

Correct answer: A

Question 66

Mathematics · 4 marks · −1

A ratio of the 5th term from the beginning to the 5th term from the end in the binomial expansion of (21/3+12(3)1/3)10\left(2^{1/3}+\frac{1}{2(3)^{1/3}}\right)^{10} is:

  1. A.1:2(6)1/31:2(6)^{1/3}
  2. B.2(36)1/3:12(36)^{1/3}:1
  3. C.4(36)1/3:14(36)^{1/3}:1
  4. D.1:4(16)1/31:4(16)^{1/3}

Correct answer: C

Question 67

Mathematics · 4 marks · −1

The product of three consecutive terms of a G.P. is 512. If 4 is added to each of the first and the second of these terms, the three terms now form an A.P. Then the sum of the original three terms of the given G.P. is:

  1. A.36
  2. B.32
  3. C.28
  4. D.24

Correct answer: C

Question 68

Mathematics · 4 marks · −1

Let Sk=1+2+3+…+kkS_k=\frac{1+2+3+\ldots+k}{k}. If S12+S22+⋯+S102=512AS_1^2+S_2^2+\cdots+S_{10}^2=\frac{5}{12}A, then A is equal to:

  1. A.156
  2. B.283
  3. C.301
  4. D.303

Correct answer: D

Question 69

Mathematics · 4 marks · −1

lim⁡x→π/4cot⁡3x−tan⁡xcos⁡(x+π4)\lim\limits_{x\to\pi/4}\frac{\cot^3x-\tan x}{\cos\left(x+\frac{\pi}{4}\right)} is:

  1. A.424\sqrt2
  2. B.4
  3. C.828\sqrt2
  4. D.8

Correct answer: D

Question 70

Mathematics · 4 marks · −1

For x>1x>1, if (2x)2y=4e2x−2y(2x)^{2y}=4e^{2x-2y}, then (1+log⁡e2x)2dydx(1+\log_e2x)^2\frac{dy}{dx} is equal to:

  1. A.xlog⁡e2x+log⁡e2x\frac{x\log_e2x+\log_e2}{x}
  2. B.log⁡e2x\log_e2x
  3. C.xlog⁡e2x−log⁡e2x\frac{x\log_e2x-\log_e2}{x}
  4. D.xlog⁡e2xx\log_e2x

Correct answer: C

Question 71

Mathematics · 4 marks · −1

Let S be the set of all points in (−π,π)(-\pi,\pi) at which the function, f(x)=min⁡{sin⁡x,cos⁡x}f(x)=\min\{\sin x,\cos x\} is not differentiable. Then S is a subset of which of the following?

  1. A.{−π2,−π4,π4,π2}\left\{-\frac\pi2,-\frac\pi4,\frac\pi4,\frac\pi2\right\}
  2. B.{−3π4,−π4,3π4,π4}\left\{-\frac{3\pi}{4},-\frac\pi4,\frac{3\pi}{4},\frac\pi4\right\}
  3. C.{−3π4,−π2,π2,3π4}\left\{-\frac{3\pi}{4},-\frac\pi2,\frac\pi2,\frac{3\pi}{4}\right\}
  4. D.{−π4,0,π4}\left\{-\frac\pi4,0,\frac\pi4\right\}

Correct answer: B

Question 72

Mathematics · 4 marks · −1

The maximum area (in sq. units) of a rectangle having its base on the xx-axis and its other two vertices on the parabola, y=12−x2y=12-x^2 such that the rectangle lies inside the parabola, is:

  1. A.36
  2. B.32
  3. C.20220\sqrt2
  4. D.18318\sqrt3

Correct answer: B

Question 73

Mathematics · 4 marks · −1

The integral ∫cos⁡(log⁡ex) dx\int\cos(\log_ex)\,dx is equal to: (where C is a constant of integration)

  1. A.x[cos⁡(log⁡ex)+sin⁡(log⁡ex)]+Cx\left[\cos(\log_ex)+\sin(\log_ex)\right]+C
  2. B.x[cos⁡(log⁡ex)−sin⁡(log⁡ex)]+Cx\left[\cos(\log_ex)-\sin(\log_ex)\right]+C
  3. C.x2[sin⁡(log⁡ex)−cos⁡(log⁡ex)]+C\frac x2\left[\sin(\log_ex)-\cos(\log_ex)\right]+C
  4. D.x2[cos⁡(log⁡ex)+sin⁡(log⁡ex)]+C\frac x2\left[\cos(\log_ex)+\sin(\log_ex)\right]+C

Correct answer: D

Question 74

Mathematics · 4 marks · −1

Let ff and gg be continuous functions on [0,a][0,a] such that f(x)=f(a−x)f(x)=f(a-x) and g(x)+g(a−x)=4g(x)+g(a-x)=4, then ∫0af(x)g(x) dx\int_0^af(x)g(x)\,dx is equal to:

  1. A.∫0af(x) dx\int_0^af(x)\,dx
  2. B.2∫0af(x) dx2\int_0^af(x)\,dx
  3. C.4∫0af(x) dx4\int_0^af(x)\,dx
  4. D.−3∫0af(x) dx-3\int_0^af(x)\,dx

Correct answer: B

Question 75

Mathematics · 4 marks · −1

The area (in sq. units) of the region bounded by the parabola, y=x2+2y=x^2+2 and the lines, y=x+1y=x+1, x=0x=0 and x=3x=3, is:

  1. A.152\frac{15}{2}
  2. B.212\frac{21}{2}
  3. C.174\frac{17}{4}
  4. D.154\frac{15}{4}

Correct answer: A

Question 76

Mathematics · 4 marks · −1

Let y=y(x)y=y(x) be the solution of the differential equation, xdydx+y=xlog⁡exx\frac{dy}{dx}+y=x\log_ex, (x>1)(x>1). If 2y(2)=log⁡e4−12y(2)=\log_e4-1, then y(e)y(e) is equal to:

  1. A.e4\frac e4
  2. B.e24\frac{e^2}{4}
  3. C.−e2-\frac e2
  4. D.−e22-\frac{e^2}{2}

Correct answer: A

Question 77

Mathematics · 4 marks · −1

If the straight line, 2x−3y+17=02x-3y+17=0 is perpendicular to the line passing through the points (7,17)(7,17) and (15,β)(15,\beta), then β\beta equals:

  1. A.−5-5
  2. B.353\frac{35}{3}
  3. C.5
  4. D.−353-\frac{35}{3}

Correct answer: C

Question 78

Mathematics · 4 marks · −1

If a variable line, 3x+4y−λ=03x+4y-\lambda=0 is such that the two circles x2+y2−2x−2y+1=0x^2+y^2-2x-2y+1=0 and x2+y2−18x−2y+78=0x^2+y^2-18x-2y+78=0 are on its opposite sides, then the set of all values of λ\lambda is the interval:

  1. A.(23,31)(23,31)
  2. B.(2,17)(2,17)
  3. C.[13,23][13,23]
  4. D.[12,21][12,21]

Correct answer: D

Question 79

Mathematics · 4 marks · −1

Let C1C_1 and C2C_2 be the centres of the circles x2+y2−2x−2y−2=0x^2+y^2-2x-2y-2=0 and x2+y2−6x−6y+14=0x^2+y^2-6x-6y+14=0 respectively. If P and Q are the points of intersection of these circles, then the area (in sq. units) of the quadrilateral PC1QC2PC_1QC_2 is:

  1. A.4
  2. B.6
  3. C.8
  4. D.9

Correct answer: A

Question 80

Mathematics · 4 marks · −1

Let P(4,−4)P(4,-4) and Q(9,6)Q(9,6) be two points on the parabola, y2=4xy^2=4x and let X be any point on the arc POQ of this parabola, where O is the vertex of this parabola, such that the area of ΔPXQ\Delta PXQ is maximum. Then this maximum area (in sq. units) is:

  1. A.1252\frac{125}{2}
  2. B.6254\frac{625}{4}
  3. C.1254\frac{125}{4}
  4. D.752\frac{75}{2}

Correct answer: C

Question 81

Mathematics · 4 marks · −1

If the vertices of a hyperbola be at (−2,0)(-2,0) and (2,0)(2,0) and one of its foci be at (−3,0)(-3,0), then which one of the following points does not lie on this hyperbola?

  1. A.(4,15)(4,\sqrt{15})
  2. B.(26,5)(2\sqrt6,5)
  3. C.(6,52)(6,5\sqrt2)
  4. D.(−6,210)(-6,2\sqrt{10})

Correct answer: C

Question 82

Mathematics · 4 marks · −1

The perpendicular distance from the origin to the plane containing the two lines, x+23=y−25=z+57\frac{x+2}{3}=\frac{y-2}{5}=\frac{z+5}{7} and x−11=y−44=z+47\frac{x-1}{1}=\frac{y-4}{4}=\frac{z+4}{7}, is:

  1. A.11
  2. B.11611\sqrt6
  3. C.116\frac{11}{\sqrt6}
  4. D.6116\sqrt{11}

Correct answer: C

Question 83

Mathematics · 4 marks · −1

A tetrahedron has vertices P(1,2,1)P(1,2,1), Q(2,1,3)Q(2,1,3), R(−1,1,2)R(-1,1,2) and O(0,0,0)O(0,0,0). The angle between the faces OPQ and PQR is:

  1. A.cos⁡−1(1935)\cos^{-1}\left(\frac{19}{35}\right)
  2. B.cos⁡−1(1731)\cos^{-1}\left(\frac{17}{31}\right)
  3. C.cos⁡−1(935)\cos^{-1}\left(\frac{9}{35}\right)
  4. D.cos⁡−1(731)\cos^{-1}\left(\frac{7}{31}\right)

Correct answer: A

Question 84

Mathematics · 4 marks · −1

The sum of the distinct real values of μ\mu, for which the vectors, μi^+j^+k^\mu\hat i+\hat j+\hat k, i^+μj^+k^\hat i+\mu\hat j+\hat k, i^+j^+μk^\hat i+\hat j+\mu\hat k are co-planar, is:

  1. A.0
  2. B.−1-1
  3. C.1
  4. D.2

Correct answer: B

Question 85

Mathematics · 4 marks · −1

If the sum of the deviations of 50 observations from 30 is 50, then the mean of these observations is:

  1. A.50
  2. B.51
  3. C.30
  4. D.31

Correct answer: D

Question 86

Mathematics · 4 marks · −1

In a random experiment, a fair die is rolled until two fours are obtained in succession. The probability that the experiment will end in the fifth throw of the die is equal to:

  1. A.20065\frac{200}{6^5}
  2. B.15065\frac{150}{6^5}
  3. C.22565\frac{225}{6^5}
  4. D.17565\frac{175}{6^5}

Correct answer: D

Question 87

Mathematics · 4 marks · −1

The maximum value of 3cos⁡θ+5sin⁡(θ−π6)3\cos\theta+5\sin\left(\theta-\frac\pi6\right) for any real value of θ\theta is:

  1. A.792\frac{\sqrt{79}}{2}
  2. B.19\sqrt{19}
  3. C.31\sqrt{31}
  4. D.34\sqrt{34}

Correct answer: B

Question 88

Mathematics · 4 marks · −1

Considering only the principal values of inverse functions, the set A={x≥0:tan⁡−1(2x)+tan⁡−1(3x)=π4}A=\left\{x\ge0:\tan^{-1}(2x)+\tan^{-1}(3x)=\frac\pi4\right\}

  1. A.is an empty set
  2. B.is a singleton
  3. C.contains two elements
  4. D.contains more than two elements

Correct answer: B

Question 89

Mathematics · 4 marks · −1

The Boolean expression ((p∧q)∨(p∨∼q))∧(∼p∧∼q)((p\wedge q)\vee(p\vee\sim q))\wedge(\sim p\wedge\sim q) is equivalent to:

  1. A.p∧(∼q)p\wedge(\sim q)
  2. B.p∨(∼q)p\vee(\sim q)
  3. C.(∼p)∧(∼q)(\sim p)\wedge(\sim q)
  4. D.p∧qp\wedge q

Correct answer: C

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