JEE Main 2019 — 8 Apr Shift 1 (Previous Year Paper)

JEE Main · 2019 · with answers and explanations

questions
89
Total marks
356
Duration
180 minutes
Negative marking
−1

Subjects: Physics · Chemistry · Mathematics

Question 1

Physics · 4 marks · −1

In SI units, the dimensions of ϵ0μ0\sqrt{\dfrac{\epsilon_0}{\mu_0}} is:

  1. A.AT2M−1L−1AT^2M^{-1}L^{-1}
  2. B.A2T3M−1L−2A^2T^3M^{-1}L^{-2}
  3. C.A−1TML3A^{-1}TML^3
  4. D.AT−3ML3/2AT^{-3}ML^{3/2}

Correct answer: B

Question 2

Physics · 4 marks · −1

Ship A is sailing towards north-east with velocity v⃗=30i^+50j^\vec{v} = 30\hat{i} + 50\hat{j} km/hr where i^\hat{i} points east and j^\hat{j}, north. Ship B is at a distance of 80 km east and 150 km north of Ship A and is sailing towards west at 10 km/hr. A will be at minimum distance from B in:

  1. A.4.2 hrs.
  2. B.2.2 hrs.
  3. C.2.6 hrs.
  4. D.3.2 hrs.

Correct answer: C

Question 3

Physics · 4 marks · −1

Four particles A, B, C and D with masses mA=mm_A = m, mB=2mm_B = 2m, mC=3mm_C = 3m and mD=4mm_D = 4m are at the corners of a square. They have accelerations of equal magnitude with directions as shown. The acceleration of the centre of mass of the particles is:

Figure for question 3
  1. A.Zero
  2. B.a(i^+j^)a(\hat{i} + \hat{j})
  3. C.a5(i^+j^)\dfrac{a}{5}(\hat{i} + \hat{j})
  4. D.a5(i^−j^)\dfrac{a}{5}(\hat{i} - \hat{j})

Correct answer: D

Question 4

Physics · 4 marks · −1

A particle moves in one dimension from rest under the influence of a force that varies with the distance travelled by the particle as shown in the figure. The kinetic energy of the particle after it has travelled 3 m is:

Figure for question 4
  1. A.5 J
  2. B.6.5 J
  3. C.4 J
  4. D.2.5 J

Correct answer: B

Question 5

Physics · 4 marks · −1

A thin circular plate of mass M and radius R has its density varying as ρ(r)=ρ0r\rho(r) = \rho_0 r with ρ0\rho_0 as constant and r is the distance from its center. The moment of Inertia of the circular plate about an axis perpendicular to the plate and passing through its edge is I=aMR2I = aMR^2. The value of the coefficient a is:

  1. A.85\dfrac{8}{5}
  2. B.32\dfrac{3}{2}
  3. C.35\dfrac{3}{5}
  4. D.12\dfrac{1}{2}

Correct answer: A

Question 6

Physics · 4 marks · −1

Four identical particles of mass M are located at the corners of a square of side 'a'. What should be their speed if each of them revolves under the influence of others' gravitational field in a circular orbit circumscribing the square?

Figure for question 6
  1. A.1.21GMa1.21\sqrt{\dfrac{GM}{a}}
  2. B.1.35GMa1.35\sqrt{\dfrac{GM}{a}}
  3. C.1.41GMa1.41\sqrt{\dfrac{GM}{a}}
  4. D.1.16GMa1.16\sqrt{\dfrac{GM}{a}}

Correct answer: D

Question 7

Physics · 4 marks · −1

A boy's catapult is made of rubber cord which is 42 cm long, with 6 mm diameter of cross-section and of negligible mass. The boy keeps a stone weighing 0.02 kg on it and stretches the cord by 20 cm by applying a constant force. When released, the stone flies off with a velocity of 20 m s−1^{-1}. Neglect the change in the area of cross-section of the cord while stretched. The Young's modulus of rubber is closest to:

  1. A.10610^6 N m−2^{-2}
  2. B.10810^8 N m−2^{-2}
  3. C.10410^4 N m−2^{-2}
  4. D.10310^3 N m−2^{-2}

Correct answer: A

Question 8

Physics · 4 marks · −1

Water from a pipe is coming at a rate of 100 liters per minute. If the radius of the pipe is 5 cm, the Reynolds number for the flow is of the order of: (density of water = 1000 kg/m3^3, coefficient of viscosity of water = 1 mPa s)

  1. A.10410^4
  2. B.10310^3
  3. C.10610^6
  4. D.10210^2

Correct answer: A

Question 9

Physics · 4 marks · −1

Two identical beakers A and B contain equal volumes of two different liquids at 60°C each and left to cool down. Liquid in A has density of 8×1028 \times 10^2 kg/m3^3 and specific heat of 2000 J kg−1^{-1} K−1^{-1} while liquid in B has density of 10310^3 kg m−3^{-3} and specific heat of 4000 J kg−1^{-1} K−1^{-1}. Which of the following best describes their temperature versus time graph schematically? (assume the emissivity of both the beakers to be the same)

Figure for question 9
  1. A.Graph: T vs t starting at 60°C; curve A lies above curve B (B cools faster)
  2. B.Graph: T vs t starting at 60°C; curve B lies above curve A (A cools faster)
  3. C.Graph: T vs t starting at 60°C; a single common curve labelled "A and B"
  4. D.Graph: T vs t starting at 60°C; A and B both fall steeply, A slightly above B, both levelling off quickly

Correct answer: B

Question 10

Physics · 4 marks · −1

A thermally insulated vessel contains 150 g of water at 0°C. Then the air from the vessel is pumped out adiabatically. A fraction of water turns into ice and the rest evaporates at 0°C itself. The mass of evaporated water will be closest to: (Latent heat of vaporization of water = 2.10×1062.10 \times 10^6 J kg−1^{-1} and Latent heat of Fusion of water = 3.36×1053.36 \times 10^5 J kg−1^{-1})

  1. A.150 g
  2. B.20 g
  3. C.35 g
  4. D.130 g

Correct answer: B

Question 11

Physics · 4 marks · −1

A steel wire having a radius of 2.0 mm, carrying a load of 4 kg, is hanging from a ceiling. Given that g=3.1πg = 3.1\pi m s−2^{-2}, what will be the tensile stress that would be developed in the wire?

  1. A.5.2×1065.2\times10^6 N m−2^{-2}
  2. B.3.1×1063.1\times10^6 N m−2^{-2}
  3. C.6.2×1066.2\times10^6 N m−2^{-2}
  4. D.4.8×1064.8\times10^6 N m−2^{-2}

Correct answer: B

Question 12

Physics · 4 marks · −1

A wire of length 2L, is made by joining two wires A and B of same length but different radii r and 2r and made of the same material. It is vibrating at a frequency such that the joint of the two wires forms a node. If the number of antinodes in wire A is p and that in B is q then the ratio p : q is:

Figure for question 12
  1. A.1 : 2
  2. B.3 : 5
  3. C.4 : 9
  4. D.1 : 4

Correct answer: A

Question 13

Physics · 4 marks · −1

The bob of a simple pendulum has mass 2 g and a charge of 5.0 μC. It is at rest in a uniform horizontal electric field of intensity 2000 V/m. At equilibrium, the angle that the pendulum makes with the vertical is: (take g = 10 m/s2^2)

  1. A.tan⁡−1(0.5)\tan^{-1}(0.5)
  2. B.tan⁡−1(5.0)\tan^{-1}(5.0)
  3. C.tan⁡−1(2.0)\tan^{-1}(2.0)
  4. D.tan⁡−1(0.2)\tan^{-1}(0.2)

Correct answer: A

Question 14

Physics · 4 marks · −1

A solid conducting sphere, having a charge Q, is surrounded by an uncharged conducting hollow spherical shell. Let the potential difference between the surface of the solid sphere and that of the outer surface of the hollow shell be V. If the shell is now given a charge of −4Q-4Q, the new potential difference between the same two surfaces is:

  1. A.V
  2. B.2V
  3. C.−2V
  4. D.4V

Correct answer: A

Question 15

Physics · 4 marks · −1

Voltage rating of a parallel plate capacitor is 500 V. Its dielectric can withstand a maximum electric field of 10610^6 V/m. The plate area is 10−410^{-4} m2^2. What is the dielectric constant if the capacitance is 15 pF? (given ϵ0=8.86×10−12\epsilon_0 = 8.86\times10^{-12} C2^2/N m2^2)

  1. A.6.2
  2. B.3.8
  3. C.4.5
  4. D.8.5

Correct answer: D

Question 16

Physics · 4 marks · −1

For the circuit shown, with R1=1.0 ΩR_1 = 1.0\ \Omega, R2=2.0 ΩR_2 = 2.0\ \Omega, E1=2E_1 = 2 V and E2=E3=4E_2 = E_3 = 4 V, the potential difference between the points 'a' and 'b' is approximately (in V):

Figure for question 16
  1. A.3.7
  2. B.3.3
  3. C.2.7
  4. D.2.3

Correct answer: B

Question 17

Physics · 4 marks · −1

A circular coil having N turns and radius r carries a current I. It is held in the XZ plane in a magnetic field Bi^B\hat{i}. The torque on the coil due to the magnetic field is:

  1. A.Bπr2INB\pi r^2 IN
  2. B.Bπr2IN\dfrac{B\pi r^2 I}{N}
  3. C.Zero
  4. D.Br2IπN\dfrac{Br^2 I}{\pi N}

Correct answer: A

Question 18

Physics · 4 marks · −1

An alternating voltage v(t)=220sin⁡100πtv(t) = 220\sin 100\pi t volt is applied to a purely resistive load of 50 Ω. The time taken for the current to rise from half of the peak value to the peak value is:

  1. A.2.2 ms
  2. B.3.3 ms
  3. C.5 ms
  4. D.7.2 ms

Correct answer: B

Question 19

Physics · 4 marks · −1

A thin strip 10 cm long is on a U shaped wire of negligible resistance and it is connected to a spring of spring constant 0.5 N m−1^{-1} (see figure). The assembly is kept in a uniform magnetic field of 0.1 T. If the strip is pulled from its equilibrium position and released, the number of oscillations it performs before its amplitude decreases by a factor of e is N. If the mass of the strip is 50 grams, its resistance 10 Ω and air drag negligible, N will be close to:

Figure for question 19
  1. A.1000
  2. B.5000
  3. C.10000
  4. D.50000

Correct answer: B

Question 20

Physics · 4 marks · −1

A 20 Henry inductor coil is connected to a 10 ohm resistance in series as shown in figure. The time at which rate of dissipation of energy (Joule's heat) across resistance is equal to the rate at which magnetic energy is stored in the inductor, is:

Figure for question 20
  1. A.12ln⁡2\dfrac{1}{2}\ln 2
  2. B.2ln⁡22\ln 2
  3. C.2ln⁡2\dfrac{2}{\ln 2}
  4. D.ln⁡2\ln 2

Correct answer: B

Question 21

Physics · 4 marks · −1

A plane electromagnetic wave travels in free space along the x-direction. The electric field component of the wave at a particular point of space and time is E = 6 V m−1^{-1} along y-direction. Its corresponding magnetic field component, B would be:

  1. A.2×10−82\times10^{-8} T along z-direction
  2. B.6×10−86\times10^{-8} T along x-direction
  3. C.2×10−82\times10^{-8} T along y-direction
  4. D.6×10−86\times10^{-8} T along z-direction

Correct answer: A

Question 22

Physics · 4 marks · −1

An upright object is placed at a distance of 40 cm in front of a convergent lens of focal length 20 cm. A convergent mirror of focal length 10 cm is placed at a distance of 60 cm on the other side of the lens. The position and size of the final image will be:

  1. A.40 cm from the convergent mirror, same size as the object
  2. B.20 cm from the convergent mirror, same size as the object
  3. C.20 cm from the convergent mirror, twice the size of the object
  4. D.40 cm from the convergent lens, twice the size of the object

Correct answer: B

Question 23

Physics · 4 marks · −1

In an interference experiment the ratio of amplitudes of coherent waves is a1a2=13\dfrac{a_1}{a_2} = \dfrac{1}{3}. The ratio of maximum and minimum intensities of fringes will be:

  1. A.2
  2. B.4
  3. C.9
  4. D.18

Correct answer: B

Question 24

Physics · 4 marks · −1

In figure, the optical fiber is l=2l = 2 m long and has a diameter of d=20d = 20 μm. If a ray of light is incident on one end of the fiber at angle θ1=40°\theta_1 = 40°, the number of reflections it makes before emerging from the other end is close to: (refractive index of fiber is 1.31 and sin⁡40°=0.64\sin 40° = 0.64)

Figure for question 24
  1. A.57000
  2. B.66000
  3. C.55000
  4. D.45000

Correct answer: A

Question 25

Physics · 4 marks · −1

Two particles move at right angle to each other. Their de Broglie wavelengths are λ1\lambda_1 and λ2\lambda_2 respectively. The particles suffer perfectly inelastic collision. The de Broglie wavelength λ\lambda, of the final particle, is given by:

  1. A.λ=λ1+λ22\lambda = \dfrac{\lambda_1 + \lambda_2}{2}
  2. B.λ=λ1λ2\lambda = \sqrt{\lambda_1\lambda_2}
  3. C.2λ=1λ1+1λ2\dfrac{2}{\lambda} = \dfrac{1}{\lambda_1} + \dfrac{1}{\lambda_2}
  4. D.1λ2=1λ12+1λ22\dfrac{1}{\lambda^2} = \dfrac{1}{\lambda_1^2} + \dfrac{1}{\lambda_2^2}

Correct answer: D

Question 26

Physics · 4 marks · −1

Radiation coming from transitions n = 2 to n = 1 of hydrogen atoms fall on He+^+ ions in n = 1 and n = 2 states. The possible transition of helium ions as they absorb energy from the radiation is:

  1. A.n=2→n=5n = 2 \rightarrow n = 5
  2. B.n=1→n=4n = 1 \rightarrow n = 4
  3. C.n=2→n=3n = 2 \rightarrow n = 3
  4. D.n=2→n=4n = 2 \rightarrow n = 4

Correct answer: D

Question 27

Physics · 4 marks · −1

The reverse breakdown voltage of a Zener diode is 5.6 V in the given circuit. The current IzI_z through the Zener is:

Figure for question 27
  1. A.15 mA
  2. B.10 mA
  3. C.7 mA
  4. D.17 mA

Correct answer: B

Question 28

Physics · 4 marks · −1

The wavelength of the carrier waves in a modern optical fiber communication network is close to:

  1. A.1500 nm
  2. B.900 nm
  3. C.2400 nm
  4. D.600 nm

Correct answer: A

Question 29

Physics · 4 marks · −1

A 200 Ω resistor has a certain color code. If one replaces the red color by green in the code, the new resistance will be:

  1. A.100 Ω
  2. B.300 Ω
  3. C.400 Ω
  4. D.500 Ω

Correct answer: D

Question 30

Chemistry · 4 marks · −1

An organic compound neither reacts with neutral ferric chloride solution nor with Fehling solution. It however, reacts with Grignard reagent and gives positive iodoform test. The compound is:

Figure for question 30
  1. A.2-Hydroxyacetophenone (benzene ring bearing −COCH3-COCH_3 and an ortho −OH-OH)
  2. B.2-Methoxybenzaldehyde (benzene ring bearing −OCH3-OCH_3 and an ortho −CHO-CHO)
  3. C.1-(2-Methoxyphenyl)propan-1-one (benzene ring bearing −COC2H5-COC_2H_5 and an ortho −OCH3-OCH_3)
  4. D.1-[2-(1-Hydroxyethyl)phenyl]propan-1-one (benzene ring bearing −CH(OH)CH3-CH(OH)CH_3 and an ortho −COC2H5-COC_2H_5)

Correct answer: D

Question 31

Chemistry · 4 marks · −1

Maltose on treatment with dilute HCl gives:

  1. A.D-Galactose
  2. B.D-Glucose and D-Fructose
  3. C.D-Fructose
  4. D.D-Glucose

Correct answer: D

Question 32

Chemistry · 4 marks · −1

Coupling of benzene diazonium chloride with 1-naphthol in alkaline medium will give:

Figure for question 32
  1. A.4-(Phenylazo)-1-naphthol (azo group at C-4, para to the OH)
  2. B.2-(Phenylazo)-1-naphthol (azo group at C-2, ortho to the OH)
  3. C.3-(Phenylazo)-1-naphthol (azo group at C-3, meta to the OH)
  4. D.5-(Phenylazo)-1-naphthol (azo group on the other ring, at C-5)

Correct answer: A

Question 33

Chemistry · 4 marks · −1

The major product of the following reaction is: phthalic anhydride + chlorobenzene →(ii) H2O(i) AlCl3, heat\xrightarrow[\text{(ii) } H_2O]{\text{(i) } AlCl_3,\ \text{heat}}

Figure for question 33
  1. A.2-Chloroanthraquinone
  2. B.2-(4-Chlorobenzoyl)benzoic acid (Cl para to the carbonyl)
  3. C.2-(3-Chlorobenzoyl)benzoic acid (Cl meta to the carbonyl)
  4. D.1-Chloroanthraquinone

Correct answer: B

Question 34

Chemistry · 4 marks · −1

The major product of the following reaction is: 3-methoxystyrene (benzene ring bearing −OCH3-OCH_3 and a meta −CH=CH2-CH=CH_2) →heatConc. HBr (excess)\xrightarrow[\text{heat}]{\text{Conc. HBr (excess)}}

Figure for question 34
  1. A.3-(2-Bromoethyl)phenol (ring bearing −OH-OH and meta −CH2CH2Br-CH_2CH_2Br)
  2. B.3-(1-Bromoethyl)phenol (ring bearing −OH-OH and meta −CHBrCH3-CHBrCH_3)
  3. C.1-Bromo-3-(2-bromoethyl)benzene (ring bearing −Br-Br and meta −CH2CH2Br-CH_2CH_2Br)
  4. D.1-Bromo-3-(1-bromoethyl)benzene (ring bearing −Br-Br and meta −CHBrCH3-CHBrCH_3)

Correct answer: B

Question 35

Chemistry · 4 marks · −1

The major product of the following reaction is: C6H5COCH2BrC_6H_5COCH_2Br (phenacyl bromide) →MeOH, 25°CNaBH4\xrightarrow[\text{MeOH, 25°C}]{NaBH_4}

Figure for question 35
  1. A.2-Phenyloxirane (styrene oxide)
  2. B.C6H5CH(OH)CH2BrC_6H_5CH(OH)CH_2Br
  3. C.C6H5CH(OH)CH2OMeC_6H_5CH(OH)CH_2OMe
  4. D.C6H5CH=CHOMeC_6H_5CH=CHOMe

Correct answer: A

Explanation: NaBH4_4 reduces the ketone to an alkoxide, which displaces the neighbouring bromide intramolecularly to give the epoxide.

Question 36

Chemistry · 4 marks · −1

Which of the following amines can be prepared by Gabriel phthalimide reaction?

  1. A.neo-pentylamine
  2. B.n-butylamine
  3. C.t-butylamine
  4. D.triethylamine

Correct answer: B

Question 37

Chemistry · 4 marks · −1

The IUPAC name of the following compound is: H3C−CH(CH3)−CH(OH)−CH2−COOHH_3C-CH(CH_3)-CH(OH)-CH_2-COOH

  1. A.3-Hydroxy-4-methylpentanoic acid
  2. B.4-Methyl-3-hydroxypentanoic acid
  3. C.4,4-Dimethyl-3-hydroxybutanoic acid
  4. D.2-Methyl-3-hydroxypentan-5-oic acid

Correct answer: A

Question 38

Chemistry · 4 marks · −1

An organic compound 'X' showing the following solubility profile is: water - insoluble; 5% HCl - insoluble; 10% NaOH - soluble; 10% NaHCO3_3 - insoluble.

Figure for question 38
  1. A.Oleic acid
  2. B.m-Cresol
  3. C.o-Toluidine
  4. D.Benzamide

Correct answer: B

Question 39

Chemistry · 4 marks · −1

In the following compounds, the decreasing order of basic strength will be:

  1. A.(C2H5)2NH>C2H5NH2>NH3(C_2H_5)_2NH > C_2H_5NH_2 > NH_3
  2. B.NH3>C2H5NH2>(C2H5)2NHNH_3 > C_2H_5NH_2 > (C_2H_5)_2NH
  3. C.(C2H5)2NH>NH3>C2H5NH2(C_2H_5)_2NH > NH_3 > C_2H_5NH_2
  4. D.C2H5NH2>NH3>(C2H5)2NHC_2H_5NH_2 > NH_3 > (C_2H_5)_2NH

Correct answer: A

Question 40

Chemistry · 4 marks · −1

The size of the iso-electronic species Cl−^-, Ar and Ca2+^{2+} is affected by:

  1. A.Principal quantum number of valence shell
  2. B.nuclear charge
  3. C.azimuthal quantum number of valence shell
  4. D.electron-electron interaction in the outer orbitals

Correct answer: B

Question 41

Chemistry · 4 marks · −1

With respect to an ore, Ellingham diagram helps to predict the feasibility of its

  1. A.Thermal reduction
  2. B.Electrolysis
  3. C.Zone refining
  4. D.Vapour phase refining

Correct answer: A

Question 42

Chemistry · 4 marks · −1

100 mL of a water sample contains 0.81 g of calcium bicarbonate and 0.73 g of magnesium bicarbonate. The hardness of this water sample expressed in terms of equivalents of CaCO3_3 is: (molar mass of calcium bicarbonate is 162 g mol−1^{-1} and magnesium bicarbonate is 146 g mol−1^{-1})

  1. A.1,000 ppm
  2. B.10,000 ppm
  3. C.100 ppm
  4. D.5,000 ppm

Correct answer: B

Question 43

Chemistry · 4 marks · −1

The correct order of hydration enthalpies of alkali metal ions is:

  1. A.Li+>Na+>K+>Rb+>Cs+Li^+ > Na^+ > K^+ > Rb^+ > Cs^+
  2. B.Li+>Na+>K+>Cs+>Rb+Li^+ > Na^+ > K^+ > Cs^+ > Rb^+
  3. C.Na+>Li+>K+>Rb+>Cs+Na^+ > Li^+ > K^+ > Rb^+ > Cs^+
  4. D.Na+>Li+>K+>Cs+>Rb+Na^+ > Li^+ > K^+ > Cs^+ > Rb^+

Correct answer: A

Question 44

Chemistry · 4 marks · −1

Diborane (B2_2H6_6) reacts independently with O2_2 and H2_2O to produce, respectively:

  1. A.H3BO3H_3BO_3 and B2O3B_2O_3
  2. B.HBO2HBO_2 and H3BO3H_3BO_3
  3. C.B2O3B_2O_3 and H3BO3H_3BO_3
  4. D.B2O3B_2O_3 and [BH4]−[BH_4]^-

Correct answer: C

Question 45

Chemistry · 4 marks · −1

The lanthanide ion that would show colour is:

  1. A.Gd3+Gd^{3+}
  2. B.Sm3+Sm^{3+}
  3. C.La3+La^{3+}
  4. D.Lu3+Lu^{3+}

Correct answer: B

Question 46

Chemistry · 4 marks · −1

The following ligand is:

Figure for question 46
  1. A.bidentate
  2. B.tridentate
  3. C.tetradentate
  4. D.hexadentate

Correct answer: C

Question 47

Chemistry · 4 marks · −1

The correct order of the spin-only magnetic moment of metal ions in the following low-spin complexes, [V(CN)6]4−[V(CN)_6]^{4-}, [Fe(CN)6]4−[Fe(CN)_6]^{4-}, [Ru(NH3)6]3+[Ru(NH_3)_6]^{3+}, and [Cr(NH3)6]2+[Cr(NH_3)_6]^{2+}, is:

  1. A.V2+>Cr2+>Ru3+>Fe2+V^{2+} > Cr^{2+} > Ru^{3+} > Fe^{2+}
  2. B.V2+>Ru3+>Cr2+>Fe2+V^{2+} > Ru^{3+} > Cr^{2+} > Fe^{2+}
  3. C.Cr2+>Ru3+>Fe2+>V2+Cr^{2+} > Ru^{3+} > Fe^{2+} > V^{2+}
  4. D.Cr2+>V2+>Ru3+>Fe2+Cr^{2+} > V^{2+} > Ru^{3+} > Fe^{2+}

Correct answer: A

Question 48

Chemistry · 4 marks · −1

Which is wrong with respect to our responsibility as a human being to protect our environment?

  1. A.Setting up compost tin in gardens.
  2. B.Using plastic bags.
  3. C.Restricting the use of vehicles
  4. D.Avoiding the use of floodlighted facilities.

Correct answer: B

Question 49

Chemistry · 4 marks · −1

Assertion: Ozone is destroyed by CFCs in the upper stratosphere. Reason: Ozone holes increase the amount of UV radiation reaching the earth.

  1. A.Assertion and reason are correct, but the reason is not the explanation for the assertion.
  2. B.Assertion is false, but the reason is correct.
  3. C.Assertion and reason are both correct, and the reason is the correct explanation for the assertion.
  4. D.Assertion and reason are incorrect.

Correct answer: A

Question 50

Chemistry · 4 marks · −1

In order to oxidise a mixture of one mole of each of FeC2O4FeC_2O_4, Fe2(C2O4)3Fe_2(C_2O_4)_3, FeSO4FeSO_4 and Fe2(SO4)3Fe_2(SO_4)_3 in acidic medium, the number of moles of KMnO4_4 required is:

  1. A.1
  2. B.1.5
  3. C.2
  4. D.3

Correct answer: C

Question 51

Chemistry · 4 marks · −1

Element 'B' forms ccp structure and 'A' occupies half of the octahedral voids, while oxygen atoms occupy all the tetrahedral voids. The structure of bimetallic oxide is:

  1. A.A2BO4A_2BO_4
  2. B.AB2O4AB_2O_4
  3. C.A4B2OA_4B_2O
  4. D.A2B2OA_2B_2O

Correct answer: B

Question 52

Chemistry · 4 marks · −1

The quantum number of four electrons are given below: I. n=4,l=2,ml=−2,ms=−12n=4, l=2, m_l=-2, m_s=-\frac{1}{2}; II. n=3,l=2,ml=1,ms=+12n=3, l=2, m_l=1, m_s=+\frac{1}{2}; III. n=4,l=1,ml=0,ms=+12n=4, l=1, m_l=0, m_s=+\frac{1}{2}; IV. n=3,l=1,ml=1,ms=−12n=3, l=1, m_l=1, m_s=-\frac{1}{2}. The correct order of their increasing energies will be:

  1. A.I < II < III < IV
  2. B.I < III < II < IV
  3. C.IV < III < II < I
  4. D.IV < II < III < I

Correct answer: D

Question 53

Chemistry · 4 marks · −1

For silver, CpC_p (J K−1^{-1} mol−1^{-1}) =23+0.01T= 23 + 0.01T. If the temperature (T) of 3 moles of silver is raised from 300 K to 1000 K at 1 atm pressure, the value of ΔH\Delta H will be close to:

  1. A.13 kJ
  2. B.21 kJ
  3. C.16 kJ
  4. D.62 kJ

Correct answer: D

Question 54

Chemistry · 4 marks · −1

Which one of the following equations does not correctly represent the first law of thermodynamics for the given processes involving an ideal gas? (Assume non-expansion work is zero)

  1. A.Isothermal process: q=−wq = -w
  2. B.Cyclic process: q=−wq = -w
  3. C.Isochoric process: ΔU=q\Delta U = q
  4. D.Adiabatic process: ΔU=−w\Delta U = -w

Correct answer: D

Question 55

Chemistry · 4 marks · −1

The vapour pressures of pure liquids A and B are 400 and 600 mmHg, respectively at 298 K. On mixing the two liquids, the sum of their initial volumes is equal to the volume of the final mixture. The mole fraction of liquid B is 0.5 in the mixture. The vapour pressure of the final solution, the mole fractions of components A and B in vapour phase, respectively are:

  1. A.500 mmHg, 0.4, 0.6
  2. B.450 mmHg, 0.5, 0.5
  3. C.500 mmHg, 0.5, 0.5
  4. D.450 mmHg, 0.4, 0.6

Correct answer: A

Question 56

Chemistry · 4 marks · −1

If solubility product of Zr3(PO4)4Zr_3(PO_4)_4 is denoted by KspK_{sp} and its molar solubility is denoted by S, then which of the following relation between S and KspK_{sp} is correct?

  1. A.S=(Ksp144)1/6S = \left(\dfrac{K_{sp}}{144}\right)^{1/6}
  2. B.S=(Ksp929)1/9S = \left(\dfrac{K_{sp}}{929}\right)^{1/9}
  3. C.S=(Ksp6912)1/7S = \left(\dfrac{K_{sp}}{6912}\right)^{1/7}
  4. D.S=(Ksp216)1/7S = \left(\dfrac{K_{sp}}{216}\right)^{1/7}

Correct answer: C

Question 57

Chemistry · 4 marks · −1

Given that EO2/H2O⊖=+1.23E^\ominus_{O_2/H_2O} = +1.23 V; ES2O82−/SO42−⊖=2.05E^\ominus_{S_2O_8^{2-}/SO_4^{2-}} = 2.05 V; EBr2/Br−⊖=+1.09E^\ominus_{Br_2/Br^-} = +1.09 V; EAu3+/Au⊖=+1.4E^\ominus_{Au^{3+}/Au} = +1.4 V. The strongest oxidizing agent is:

  1. A.S2O82−S_2O_8^{2-}
  2. B.Au3+Au^{3+}
  3. C.Br2Br_2
  4. D.O2O_2

Correct answer: A

Question 58

Chemistry · 4 marks · −1

For the reaction 2A+B→C2A + B \rightarrow C, the values of initial rate at different reactant concentrations are given in the table below. The rate law for the reaction is: [A] (mol L−1^{-1}), [B] (mol L−1^{-1}), Initial rate (mol L−1^{-1} s−1^{-1}): (i) 0.05, 0.05, 0.045; (ii) 0.10, 0.05, 0.090; (iii) 0.20, 0.10, 0.72.

Figure for question 58
  1. A.Rate =k[A][B]= k[A][B]
  2. B.Rate =k[A]2[B]= k[A]^2[B]
  3. C.Rate =k[A][B]2= k[A][B]^2
  4. D.Rate =k[A]2[B]2= k[A]^2[B]^2

Correct answer: C

Question 59

Chemistry · 4 marks · −1

Adsorption of a gas follows Freundlich adsorption isotherm. x is the mass of the gas adsorbed on mass m of the adsorbent. The plot of log⁡xm\log\frac{x}{m} versus log⁡p\log p is shown in the given graph. xm\frac{x}{m} is proportional to:

Figure for question 59
  1. A.p2p^2
  2. B.p3/2p^{3/2}
  3. C.p2/3p^{2/3}
  4. D.p3p^3

Correct answer: C

Question 60

Mathematics · 4 marks · −1

If f(x)=log⁡e(1−x1+x)f(x) = \log_e\left(\dfrac{1-x}{1+x}\right), ∣x∣<1|x| < 1, then f(2x1+x2)f\left(\dfrac{2x}{1+x^2}\right) is equal to:

  1. A.2f(x2)2f(x^2)
  2. B.−2f(x)-2f(x)
  3. C.2f(x)2f(x)
  4. D.(f(x))2(f(x))^2

Correct answer: C

Question 61

Mathematics · 4 marks · −1

If α\alpha and β\beta be the roots of the equation x2−2x+2=0x^2 - 2x + 2 = 0, then the least value of n for which (αβ)n=1\left(\dfrac{\alpha}{\beta}\right)^n = 1 is:

  1. A.5
  2. B.4
  3. C.3
  4. D.2

Correct answer: B

Question 62

Mathematics · 4 marks · −1

The sum of the solutions of the equation ∣x−2∣+x(x−4)+2=0|\sqrt{x} - 2| + \sqrt{x}(\sqrt{x} - 4) + 2 = 0, (x>0)(x > 0) is equal to:

  1. A.4
  2. B.9
  3. C.10
  4. D.12

Correct answer: C

Question 63

Mathematics · 4 marks · −1

Let A=(cos⁡α−sin⁡αsin⁡αcos⁡α)A = \begin{pmatrix} \cos\alpha & -\sin\alpha \\ \sin\alpha & \cos\alpha \end{pmatrix}, (α∈R)(\alpha \in \mathbb{R}) such that A32=(0−110)A^{32} = \begin{pmatrix} 0 & -1 \\ 1 & 0 \end{pmatrix}. Then a value of α\alpha is:

  1. A.0
  2. B.π64\dfrac{\pi}{64}
  3. C.π32\dfrac{\pi}{32}
  4. D.π16\dfrac{\pi}{16}

Correct answer: B

Question 64

Mathematics · 4 marks · −1

The greatest value of c∈Rc \in \mathbb{R} for which the system of linear equations x−cy−cz=0x - cy - cz = 0, cx−y+cz=0cx - y + cz = 0, cx+cy−z=0cx + cy - z = 0 has a non-trivial solution, is:

  1. A.−1
  2. B.0
  3. C.12\dfrac{1}{2}
  4. D.2

Correct answer: C

Question 65

Mathematics · 4 marks · −1

All possible numbers are formed using the digits 1, 1, 2, 2, 2, 2, 3, 4, 4 taken all at a time. The number of such numbers in which the odd digits occupy even places is:

  1. A.160
  2. B.162
  3. C.175
  4. D.180

Correct answer: D

Question 66

Mathematics · 4 marks · −1

The sum of the co-efficients of all even degree terms in x in the expansion of (x+x3−1)6+(x−x3−1)6\left(x + \sqrt{x^3 - 1}\right)^6 + \left(x - \sqrt{x^3 - 1}\right)^6, (x>1)(x > 1) is equal to:

  1. A.24
  2. B.26
  3. C.29
  4. D.32

Correct answer: A

Question 67

Mathematics · 4 marks · −1

The sum of all natural numbers 'n' such that 100<n<200100 < n < 200 and H.C.F.(91,n)>1(91, n) > 1 is:

  1. A.3203
  2. B.3221
  3. C.3121
  4. D.3303

Correct answer: C

Question 68

Mathematics · 4 marks · −1

The sum of the series 2⋅20C0+5⋅20C1+8⋅20C2+11⋅20C3+…+62⋅20C202\cdot{}^{20}C_0 + 5\cdot{}^{20}C_1 + 8\cdot{}^{20}C_2 + 11\cdot{}^{20}C_3 + \ldots + 62\cdot{}^{20}C_{20} is equal to:

  1. A.2242^{24}
  2. B.2252^{25}
  3. C.2232^{23}
  4. D.2262^{26}

Correct answer: B

Question 69

Mathematics · 4 marks · −1

lim⁡x→0sin⁡2x2−1+cos⁡x\displaystyle\lim_{x\to 0} \frac{\sin^2 x}{\sqrt{2} - \sqrt{1 + \cos x}} equals:

  1. A.424\sqrt{2}
  2. B.4
  3. C.2\sqrt{2}
  4. D.222\sqrt{2}

Correct answer: A

Question 70

Mathematics · 4 marks · −1

If 2y=(cot⁡−1(3cos⁡x+sin⁡xcos⁡x−3sin⁡x))22y = \left(\cot^{-1}\left(\dfrac{\sqrt{3}\cos x + \sin x}{\cos x - \sqrt{3}\sin x}\right)\right)^2, x∈(0,π2)x \in \left(0, \dfrac{\pi}{2}\right) then dydx\dfrac{dy}{dx} is equal to:

  1. A.π6−x\dfrac{\pi}{6} - x
  2. B.π3−x\dfrac{\pi}{3} - x
  3. C.x−π6x - \dfrac{\pi}{6}
  4. D.2x−π32x - \dfrac{\pi}{3}

Correct answer: C

Question 71

Mathematics · 4 marks · −1

Let f:[0,2]→Rf: [0, 2] \rightarrow \mathbb{R} be a twice differentiable function such that f′′(x)>0f''(x) > 0, for all x∈(0,2)x \in (0, 2). If ϕ(x)=f(x)+f(2−x)\phi(x) = f(x) + f(2 - x), then ϕ\phi is:

  1. A.increasing on (0, 1) and decreasing on (1, 2).
  2. B.decreasing on (0, 1) and increasing on (1, 2).
  3. C.increasing on (0, 2)
  4. D.decreasing on (0, 2)

Correct answer: B

Question 72

Mathematics · 4 marks · −1

If S1S_1 and S2S_2 are respectively the sets of local minimum and local maximum points of the function, f(x)=9x4+12x3−36x2+25f(x) = 9x^4 + 12x^3 - 36x^2 + 25, x∈Rx \in \mathbb{R}, then:

  1. A.S1={−2,0}; S2={1}S_1 = \{-2, 0\};\ S_2 = \{1\}
  2. B.S1={−2,1}; S2={0}S_1 = \{-2, 1\};\ S_2 = \{0\}
  3. C.S1={−1}; S2={0,2}S_1 = \{-1\};\ S_2 = \{0, 2\}
  4. D.S1={−2}; S2={0,1}S_1 = \{-2\};\ S_2 = \{0, 1\}

Correct answer: B

Question 73

Mathematics · 4 marks · −1

∫sin⁡5x2sin⁡x2 dx\displaystyle\int \frac{\sin\frac{5x}{2}}{\sin\frac{x}{2}}\,dx is equal to: (where c is a constant of integration.)

  1. A.x+2sin⁡x+sin⁡2x+cx + 2\sin x + \sin 2x + c
  2. B.x+2sin⁡x+2sin⁡2x+cx + 2\sin x + 2\sin 2x + c
  3. C.2x+sin⁡x+sin⁡2x+c2x + \sin x + \sin 2x + c
  4. D.2x+sin⁡x+2sin⁡2x+c2x + \sin x + 2\sin 2x + c

Correct answer: A

Question 74

Mathematics · 4 marks · −1

If f(x)=2−xcos⁡x2+xcos⁡xf(x) = \dfrac{2 - x\cos x}{2 + x\cos x} and g(x)=log⁡exg(x) = \log_e x, (x>0)(x > 0) then the value of the integral ∫−π/4π/4g(f(x)) dx\displaystyle\int_{-\pi/4}^{\pi/4} g(f(x))\,dx is:

  1. A.log⁡e2\log_e 2
  2. B.log⁡e3\log_e 3
  3. C.log⁡e1\log_e 1
  4. D.log⁡ee\log_e e

Correct answer: C

Question 75

Mathematics · 4 marks · −1

The area (in sq. units) of the region A={(x,y)∈R×R∣0≤x≤3, 0≤y≤4, y≤x2+3x}A = \{(x, y) \in \mathbb{R}\times\mathbb{R} \mid 0 \le x \le 3,\ 0 \le y \le 4,\ y \le x^2 + 3x\} is:

  1. A.8
  2. B.263\dfrac{26}{3}
  3. C.596\dfrac{59}{6}
  4. D.536\dfrac{53}{6}

Correct answer: C

Question 76

Mathematics · 4 marks · −1

Let y=y(x)y = y(x) be the solution of the differential equation, (x2+1)2dydx+2x(x2+1)y=1(x^2 + 1)^2\dfrac{dy}{dx} + 2x(x^2 + 1)y = 1 such that y(0)=0y(0) = 0. If a y(1)=π32\sqrt{a}\,y(1) = \dfrac{\pi}{32}, then the value of 'a' is:

  1. A.116\dfrac{1}{16}
  2. B.12\dfrac{1}{2}
  3. C.1
  4. D.14\dfrac{1}{4}

Correct answer: A

Question 77

Mathematics · 4 marks · −1

Let O(0, 0) and A(0, 1) be two fixed points. Then the locus of a point P such that the perimeter of ΔAOP\Delta AOP is 4, is:

  1. A.9x2−8y2+8y=169x^2 - 8y^2 + 8y = 16
  2. B.9x2+8y2−8y=169x^2 + 8y^2 - 8y = 16
  3. C.8x2−9y2+9y=188x^2 - 9y^2 + 9y = 18
  4. D.8x2+9y2−9y=188x^2 + 9y^2 - 9y = 18

Correct answer: B

Question 78

Mathematics · 4 marks · −1

A point on the straight line, 3x+5y=153x + 5y = 15 which is equidistant from the coordinate axes will lie only in:

  1. A.1st, 2nd and 4th quadrants
  2. B.1st quadrant
  3. C.1st and 2nd quadrants
  4. D.4th quadrant

Correct answer: C

Question 79

Mathematics · 4 marks · −1

The sum of the squares of the lengths of the chords intercepted on the circle, x2+y2=16x^2 + y^2 = 16, by the lines, x+y=nx + y = n, n∈Nn \in N, where N is the set of all natural numbers, is:

  1. A.105
  2. B.210
  3. C.320
  4. D.160

Correct answer: B

Question 80

Mathematics · 4 marks · −1

The shortest distance between the line y=xy = x and the curve y2=x−2y^2 = x - 2 is:

  1. A.1142\dfrac{11}{4\sqrt{2}}
  2. B.742\dfrac{7}{4\sqrt{2}}
  3. C.78\dfrac{7}{8}
  4. D.2

Correct answer: B

Question 81

Mathematics · 4 marks · −1

If the tangents on the ellipse 4x2+y2=84x^2 + y^2 = 8 at the points (1, 2) and (a, b) are perpendicular to each other, then a2a^2 is equal to:

  1. A.217\dfrac{2}{17}
  2. B.12817\dfrac{128}{17}
  3. C.417\dfrac{4}{17}
  4. D.6417\dfrac{64}{17}

Correct answer: A

Question 82

Mathematics · 4 marks · −1

The length of the perpendicular from the point (2, −1, 4) on the straight line, x+310=y−2−7=z1\dfrac{x+3}{10} = \dfrac{y-2}{-7} = \dfrac{z}{1} is:

  1. A.less than 2
  2. B.greater than 2 but less than 3
  3. C.greater than 3 but less than 4
  4. D.greater than 4

Correct answer: C

Question 83

Mathematics · 4 marks · −1

The equation of a plane containing the line of intersection of the planes 2x−y−4=02x - y - 4 = 0 and y+2z−4=0y + 2z - 4 = 0 and passing through the point (1, 1, 0) is:

  1. A.x−y−z=0x - y - z = 0
  2. B.x+3y+z=4x + 3y + z = 4
  3. C.x−3y−2z=−2x - 3y - 2z = -2
  4. D.2x−z=22x - z = 2

Correct answer: A

Question 84

Mathematics · 4 marks · −1

The magnitude of the projection of the vector 2i^+3j^+k^2\hat{i} + 3\hat{j} + \hat{k} on the vector perpendicular to the plane containing the vectors i^+j^+k^\hat{i} + \hat{j} + \hat{k} and i^+2j^+3k^\hat{i} + 2\hat{j} + 3\hat{k}, is:

  1. A.363\sqrt{6}
  2. B.32\dfrac{\sqrt{3}}{2}
  3. C.6\sqrt{6}
  4. D.32\sqrt{\dfrac{3}{2}}

Correct answer: D

Question 85

Mathematics · 4 marks · −1

The mean and variance of seven observations are 8 and 16, respectively. If 5 of the observations are 2, 4, 10, 12, 14, then the product of the remaining two observations is:

  1. A.40
  2. B.49
  3. C.45
  4. D.48

Correct answer: D

Question 86

Mathematics · 4 marks · −1

Let A and B be two non-null events such that A⊂BA \subset B. Then, which of the following statements is always correct?

  1. A.P(A∣B)=1P(A|B) = 1
  2. B.P(A∣B)≤P(A)P(A|B) \le P(A)
  3. C.P(A∣B)≥P(A)P(A|B) \ge P(A)
  4. D.P(A∣B)=P(B)−P(A)P(A|B) = P(B) - P(A)

Correct answer: C

Question 87

Mathematics · 4 marks · −1

If cos⁡(α+β)=35\cos(\alpha + \beta) = \dfrac{3}{5}, sin⁡(α−β)=513\sin(\alpha - \beta) = \dfrac{5}{13} and 0<α,β<π40 < \alpha, \beta < \dfrac{\pi}{4}, then tan⁡(2α)\tan(2\alpha) is equal to:

  1. A.2116\dfrac{21}{16}
  2. B.6316\dfrac{63}{16}
  3. C.6352\dfrac{63}{52}
  4. D.3352\dfrac{33}{52}

Correct answer: B

Question 88

Mathematics · 4 marks · −1

If α=cos⁡−1(35)\alpha = \cos^{-1}\left(\dfrac{3}{5}\right), β=tan⁡−1(13)\beta = \tan^{-1}\left(\dfrac{1}{3}\right), where 0<α,β<π20 < \alpha, \beta < \dfrac{\pi}{2}, then α−β\alpha - \beta is equal to:

  1. A.tan⁡−1(914)\tan^{-1}\left(\dfrac{9}{14}\right)
  2. B.sin⁡−1(9510)\sin^{-1}\left(\dfrac{9}{5\sqrt{10}}\right)
  3. C.cos⁡−1(9510)\cos^{-1}\left(\dfrac{9}{5\sqrt{10}}\right)
  4. D.tan⁡−1(9510)\tan^{-1}\left(\dfrac{9}{5\sqrt{10}}\right)

Correct answer: B

Question 89

Mathematics · 4 marks · −1

The contrapositive of the statement "If you are born in India, then you are a citizen of India", is:

  1. A.If you are born in India, then you are not a citizen of India.
  2. B.If you are a citizen of India, then you are born in India.
  3. C.If you are not born in India, then you are not a citizen of India.
  4. D.If you are not a citizen of India, then you are not born in India.

Correct answer: D

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