JEE Main 2019 — 9 Apr Shift 1 (Previous Year Paper)

JEE Main · 2019 · with answers and explanations

questions
88
Total marks
352
Duration
180 minutes
Negative marking
−1

Subjects: Physics · Chemistry · Mathematics

Question 1

Physics · 4 marks · −1

In the density measurement of a cube, the mass and edge length are measured as (10.00±0.10)(10.00 \pm 0.10) kg and (0.10±0.01)(0.10 \pm 0.01) m, respectively. The error in the measurement of density is:

  1. A.0.10 kg/m3^3
  2. B.0.07 kg/m3^3
  3. C.0.31 kg/m3^3
  4. D.0.01 kg/m3^3

Correct answer: C

Question 2

Physics · 4 marks · −1

The stream of a river is flowing with a speed of 2 km/h. A swimmer can swim at a speed of 4 km/h. What should be the direction of the swimmer with respect to the flow of the river to cross the river straight?

  1. A.150°
  2. B.60°
  3. C.90°
  4. D.120°

Correct answer: D

Question 3

Physics · 4 marks · −1

A ball is thrown vertically up (taken as +z-axis) from the ground. The correct momentum-height (p-h) diagram is:

Figure for question 3
  1. A.Curved (parabolic) p-h graph from +p on the p-axis to the h-axis and on to -p, with arrows running from -p up to +p (reverse sense)
  2. B.Straight-line (triangular) p-h graph from +p to the h-axis and to -p
  3. C.Curved (parabolic) p-h graph starting at +p on the p-axis, reaching p = 0 at maximum height on the h-axis and continuing to -p, arrows running from +p to -p
  4. D.Straight-line (triangular) p-h graph with arrows from +p to -p

Correct answer: C

Question 4

Physics · 4 marks · −1

A body of mass 2 kg makes an elastic collision with a second body at rest and continues to move in the original direction but with one fourth of its original speed. What is the mass of the second body?

  1. A.1.5 kg
  2. B.1.2 kg
  3. C.1.0 kg
  4. D.1.8 kg

Correct answer: B

Question 5

Physics · 4 marks · −1

A uniform cable of mass 'M' and length 'L' is placed on a horizontal surface such that its (1n)th\left(\frac{1}{n}\right)^{th} part is hanging below the edge of the surface. To lift the hanging part of the cable upto the surface, the work done should be:

  1. A.MgLn2\dfrac{MgL}{n^2}
  2. B.2MgLn2\dfrac{2MgL}{n^2}
  3. C.MgL2n2\dfrac{MgL}{2n^2}
  4. D.nMgLnMgL

Correct answer: C

Question 6

Physics · 4 marks · −1

A stationary horizontal disc is free to rotate about its axis. When a torque is applied on it, its kinetic energy as a function of θ\theta, where θ\theta is the angle by which it has rotated, is given as kθ2k\theta^2. If its moment of inertia is I then the angular acceleration of the disc is:

  1. A.kIθ\dfrac{k}{I}\theta
  2. B.2kIθ\dfrac{2k}{I}\theta
  3. C.k2Iθ\dfrac{k}{2I}\theta
  4. D.[option 4 not visible in the NTA portal image]

Correct answer: B

Question 7

Physics · 4 marks · −1

A solid sphere of mass 'M' and radius 'a' is surrounded by a uniform concentric spherical shell of thickness 2a and mass 2M. The gravitational field at distance '3a' from the centre will be:

  1. A.GM9a2\dfrac{GM}{9a^2}
  2. B.2GM9a2\dfrac{2GM}{9a^2}
  3. C.GM3a2\dfrac{GM}{3a^2}
  4. D.2GM3a2\dfrac{2GM}{3a^2}

Correct answer: C

Question 8

Physics · 4 marks · −1

For a given gas at 1 atm pressure, rms speed of the molecules is 200 m/s at 127°C. At 2 atm pressure and at 227°C, the rms speed of the molecules will be:

  1. A.1005100\sqrt{5} m/s
  2. B.80580\sqrt{5} m/s
  3. C.100 m/s
  4. D.80 m/s

Correct answer: A

Question 9

Physics · 4 marks · −1

A simple pendulum oscillating in air has period T. The bob of the pendulum is completely immersed in a non-viscous liquid. The density of the liquid is 116\frac{1}{16}th of the material of the bob. If the bob is inside liquid all the time, its period of oscillation in this liquid is:

  1. A.2T1102T\sqrt{\dfrac{1}{10}}
  2. B.4T1154T\sqrt{\dfrac{1}{15}}
  3. C.4T1144T\sqrt{\dfrac{1}{14}}
  4. D.2T1142T\sqrt{\dfrac{1}{14}}

Correct answer: B

Question 10

Physics · 4 marks · −1

Following figure shows two processes A and B for a gas. If ΔQA\Delta Q_A and ΔQB\Delta Q_B are the amount of heat absorbed by the system in two cases, and ΔUA\Delta U_A and ΔUB\Delta U_B are changes in internal energies, respectively, then:

Figure for question 10
  1. A.ΔQA=ΔQB\Delta Q_A = \Delta Q_B; ΔUA=ΔUB\Delta U_A = \Delta U_B
  2. B.ΔQA>ΔQB\Delta Q_A > \Delta Q_B, ΔUA>ΔUB\Delta U_A > \Delta U_B
  3. C.ΔQA>ΔQB\Delta Q_A > \Delta Q_B, ΔUA=ΔUB\Delta U_A = \Delta U_B
  4. D.ΔQA<ΔQB\Delta Q_A < \Delta Q_B, ΔUA<ΔUB\Delta U_A < \Delta U_B

Correct answer: C

Question 11

Physics · 4 marks · −1

An HCl molecule has rotational, translational and vibrational motions. If the rms velocity of HCl molecules in its gaseous phase is vˉ\bar{v}, m is its mass and kBk_B is Boltzmann constant, then its temperature will be:

  1. A.mvˉ27kB\dfrac{m\bar{v}^2}{7k_B}
  2. B.mvˉ25kB\dfrac{m\bar{v}^2}{5k_B}
  3. C.mvˉ23kB\dfrac{m\bar{v}^2}{3k_B}
  4. D.mvˉ26kB\dfrac{m\bar{v}^2}{6k_B}

Correct answer: C

Question 12

Physics · 4 marks · −1

A string is clamped at both the ends and it is vibrating in its 4th^{th} harmonic. The equation of the stationary wave is Y=0.3sin⁡(0.157x)cos⁡(200πt)Y = 0.3\sin(0.157x)\cos(200\pi t). The length of the string is: (All quantities are in SI units.)

  1. A.80 m
  2. B.60 m
  3. C.40 m
  4. D.20 m

Correct answer: A

Question 13

Physics · 4 marks · −1

The pressure wave, P=0.01sin⁡[1000t−3x]P = 0.01\sin[1000t - 3x] N m−2^{-2}, corresponds to the sound produced by a vibrating blade on a day when atmospheric temperature is 0°C. On some other day when temperature is T, the speed of sound produced by the same blade and at the same frequency is found to be 336 m s−1^{-1}. Approximate value of T is:

  1. A.12°C
  2. B.11°C
  3. C.15°C
  4. D.4°C

Correct answer: D

Question 14

Physics · 4 marks · −1

A capacitor with capacitance 5 μF is charged to 5 μC. If the plates are pulled apart to reduce the capacitance to 2 μF, how much work is done?

  1. A.6.25×10−66.25\times10^{-6} J
  2. B.2.16×10−62.16\times10^{-6} J
  3. C.2.55×10−62.55\times10^{-6} J
  4. D.3.75×10−63.75\times10^{-6} J

Correct answer: D

Question 15

Physics · 4 marks · −1

A system of three charges are placed as shown in the figure: If D≫dD \gg d, the potential energy of the system is best given by:

Figure for question 15
  1. A.14πϵ0[+q2d+qQdD2]\dfrac{1}{4\pi\epsilon_0}\left[+\dfrac{q^2}{d} + \dfrac{qQd}{D^2}\right]
  2. B.14πϵ0[−q2d−qQd2D2]\dfrac{1}{4\pi\epsilon_0}\left[-\dfrac{q^2}{d} - \dfrac{qQd}{2D^2}\right]
  3. C.14πϵ0[−q2d+2qQdD2]\dfrac{1}{4\pi\epsilon_0}\left[-\dfrac{q^2}{d} + \dfrac{2qQd}{D^2}\right]
  4. D.14πϵ0[−q2d−qQdD2]\dfrac{1}{4\pi\epsilon_0}\left[-\dfrac{q^2}{d} - \dfrac{qQd}{D^2}\right]

Correct answer: D

Question 16

Physics · 4 marks · −1

A wire of resistance R is bent to form a square ABCD as shown in the figure. The effective resistance between E and C is: (E is mid-point of arm CD)

Figure for question 16
  1. A.34R\dfrac{3}{4}R
  2. B.116R\dfrac{1}{16}R
  3. C.764R\dfrac{7}{64}R
  4. D.R

Correct answer: C

Question 17

Physics · 4 marks · −1

Determine the charge on the capacitor in the following circuit:

Figure for question 17
  1. A.2 μC
  2. B.200 μC
  3. C.60 μC
  4. D.10 μC

Correct answer: B

Question 18

Physics · 4 marks · −1

A rectangular coil (Dimension 5 cm × 2.5 cm) with 100 turns, carrying a current of 3 A in the clock-wise direction, is kept centered at the origin and in the X-Z plane. A magnetic field of 1 T is applied along X-axis. If the coil is tilted through 45° about Z-axis, then the torque on the coil is:

  1. A.0.27 Nm
  2. B.0.55 Nm
  3. C.0.38 Nm
  4. D.0.42 Nm

Correct answer: A

Question 19

Physics · 4 marks · −1

A rigid square loop of side 'a' and carrying current I2I_2 is lying on a horizontal surface near a long current I1I_1 carrying wire in the same plane as shown in figure. The net force on the loop due to the wire will be:

Figure for question 19
  1. A.Zero
  2. B.Attractive and equal to μ0I1I23π\dfrac{\mu_0 I_1 I_2}{3\pi}
  3. C.Repulsive and equal to μ0I1I24π\dfrac{\mu_0 I_1 I_2}{4\pi}
  4. D.Repulsive and equal to μ0I1I22π\dfrac{\mu_0 I_1 I_2}{2\pi}

Correct answer: C

Question 20

Physics · 4 marks · −1

The total number of turns and cross-section area in a solenoid is fixed. However, its length L is varied by adjusting the separation between windings. The inductance of solenoid will be proportional to:

  1. A.L
  2. B.L2L^2
  3. C.1/L21/L^2
  4. D.1/L1/L

Correct answer: D

Question 21

Physics · 4 marks · −1

The magnetic field of a plane electromagnetic wave is given by: B⃗=B0i^[cos⁡(kz−ωt)]+B1j^cos⁡(kz+ωt)\vec{B} = B_0\hat{i}[\cos(kz - \omega t)] + B_1\hat{j}\cos(kz + \omega t) where B0=3×10−5B_0 = 3\times10^{-5} T and B1=2×10−6B_1 = 2\times10^{-6} T. The rms value of the force experienced by a stationary charge Q=10−4Q = 10^{-4} C at z = 0 is closest to:

  1. A.0.6 N
  2. B.3×10−23\times10^{-2} N
  3. C.0.9 N
  4. D.0.1 N

Correct answer: A

Question 22

Physics · 4 marks · −1

A concave mirror for face viewing has focal length of 0.4 m. The distance at which you hold the mirror from your face in order to see your image upright with a magnification of 5 is:

  1. A.0.16 m
  2. B.1.60 m
  3. C.0.32 m
  4. D.0.24 m

Correct answer: C

Question 23

Physics · 4 marks · −1

Taking the wavelength of first Balmer line in hydrogen spectrum (n = 3 to n = 2) as 660 nm, the wavelength of the 2nd^{nd} Balmer line (n = 4 to n = 2) will be:

  1. A.488.9 nm
  2. B.889.2 nm
  3. C.388.9 nm
  4. D.642.7 nm

Correct answer: A

Question 24

Physics · 4 marks · −1

The electric field of light wave is given as E⃗=10−3cos⁡(2πx5×10−7−2π×6×1014t)x^ NC\vec{E} = 10^{-3}\cos\left(\dfrac{2\pi x}{5\times10^{-7}} - 2\pi\times6\times10^{14}t\right)\hat{x}\ \frac{\text{N}}{\text{C}}. This light falls on a metal plate of work function 2 eV. The stopping potential of the photo-electrons is: Given, E (in eV) =12375λ(in A˚)= \dfrac{12375}{\lambda(\text{in Å})}

  1. A.0.72 V
  2. B.0.48 V
  3. C.2.48 V
  4. D.2.0 V

Correct answer: B

Question 25

Physics · 4 marks · −1

An NPN transistor is used in common emitter configuration as an amplifier with 1 kΩ load resistance. Signal voltage of 10 mV is applied across the base-emitter. This produces a 3 mA change in the collector current and 15 μA change in the base current of the amplifier. The input resistance and voltage gain are:

  1. A.0.33 kΩ, 300
  2. B.0.33 kΩ, 1.5
  3. C.0.67 kΩ, 300
  4. D.0.67 kΩ, 200

Correct answer: C

Question 26

Physics · 4 marks · −1

A signal Acos⁡ωtA\cos\omega t is transmitted using v0sin⁡ω0tv_0\sin\omega_0 t as carrier wave. The correct amplitude modulated (AM) signal is:

  1. A.v0sin⁡ω0t+Acos⁡ωtv_0\sin\omega_0 t + A\cos\omega t
  2. B.(v0+A)cos⁡ωtsin⁡ω0t(v_0 + A)\cos\omega t\sin\omega_0 t
  3. C.v0sin⁡ω0t+A2sin⁡(ω0−ω)t+A2sin⁡(ω0+ω)tv_0\sin\omega_0 t + \dfrac{A}{2}\sin(\omega_0 - \omega)t + \dfrac{A}{2}\sin(\omega_0 + \omega)t
  4. D.v0sin⁡[ω0(1+0.01Asin⁡ωt)t]v_0\sin[\omega_0(1 + 0.01A\sin\omega t)t]

Correct answer: C

Question 27

Physics · 4 marks · −1

If 'M' is the mass of water that rises in a capillary tube of radius 'r', then mass of water which will rise in a capillary tube of radius '2r' is:

  1. A.4 M
  2. B.2 M
  3. C.M
  4. D.M2\dfrac{M}{2}

Correct answer: B

Question 28

Physics · 4 marks · −1

A moving coil galvanometer has resistance 50 Ω and it indicates full deflection at 4 mA current. A voltmeter is made using this galvanometer and a 5 kΩ resistance. The maximum voltage, that can be measured using this voltmeter, will be close to:

  1. A.10 V
  2. B.15 V
  3. C.20 V
  4. D.40 V

Correct answer: C

Question 29

Chemistry · 4 marks · −1

The major product of the following reaction is: CH3CH=CHCO2CH3→LiAlH4CH_3CH=CHCO_2CH_3 \xrightarrow{LiAlH_4}

  1. A.CH3CH2CH2CO2CH3CH_3CH_2CH_2CO_2CH_3
  2. B.CH3CH=CHCH2OHCH_3CH=CHCH_2OH
  3. C.CH3CH2CH2CH2OHCH_3CH_2CH_2CH_2OH
  4. D.CH3CH2CH2CHOCH_3CH_2CH_2CHO

Correct answer: B

Question 30

Chemistry · 4 marks · −1

The increasing order of reactivity of the following compounds towards aromatic electrophilic substitution reaction is: chlorobenzene (A), anisole (B, C6H5OMeC_6H_5OMe), toluene (C, C6H5MeC_6H_5Me), benzonitrile (D, C6H5CNC_6H_5CN)

  1. A.A < B < C < D
  2. B.D < A < C < B
  3. C.D < B < A < C
  4. D.B < C < A < D

Correct answer: B

Question 31

Chemistry · 4 marks · −1

The major product of the following reaction is: CH3C≡CH→(ii) DI(i) DCl (1 equiv.)CH_3C\equiv CH \xrightarrow[\text{(ii) DI}]{\text{(i) DCl (1 equiv.)}}

  1. A.CH3CD2CH(Cl)(I)CH_3CD_2CH(Cl)(I)
  2. B.CH3CD(I)CHD(Cl)CH_3CD(I)CHD(Cl)
  3. C.CH3CD(Cl)CHD(I)CH_3CD(Cl)CHD(I)
  4. D.CH3C(I)(Cl)CHD2CH_3C(I)(Cl)CHD_2

Correct answer: D

Question 32

Chemistry · 4 marks · −1

Which of the following statements is not true about sucrose?

  1. A.On hydrolysis, it produces glucose and fructose
  2. B.It is a non reducing sugar
  3. C.The glycosidic linkage is present between C1C_1 of α-glucose and C1C_1 of β-fructose
  4. D.It is also named as invert sugar

Correct answer: C

Question 33

Chemistry · 4 marks · −1

The major product of the following reaction is: 4-hydroxycyclohexan-1-one →2. KOH (alc.)1. PBr3\xrightarrow[\text{2. KOH (alc.)}]{\text{1. PBr}_3}

Figure for question 33
  1. A.Phenol
  2. B.Cyclohex-2-en-1-one (C=C conjugated with C=O)
  3. C.5-Hydroxycyclohex-2-en-1-one
  4. D.Cyclohex-3-en-1-one (C=C not conjugated with C=O)

Correct answer: B

Question 34

Chemistry · 4 marks · −1

The major product of the following reaction is: 4−ClC6H4−CH2−CH(Cl)−CH3→(2) Free radical polymerisation(1) KOH (alc.)4-ClC_6H_4-CH_2-CH(Cl)-CH_3 \xrightarrow[\text{(2) Free radical polymerisation}]{\text{(1) KOH (alc.)}}

Figure for question 34
  1. A.−[CH2−CH(CH2C6H4Cl)]n−-[CH_2-CH(CH_2C_6H_4Cl)]_n- (polymer of 3-(4-chlorophenyl)propene)
  2. B.−[CH(CH3)−CH(C6H4Cl)]n−-[CH(CH_3)-CH(C_6H_4Cl)]_n- (polymer of 1-(4-chlorophenyl)propene)
  3. C.−[CH2−CH(CH2C6H4OH)]n−-[CH_2-CH(CH_2C_6H_4OH)]_n-
  4. D.−[CH(CH3)−CH(C6H4OH)]n−-[CH(CH_3)-CH(C_6H_4OH)]_n-

Correct answer: B

Question 35

Chemistry · 4 marks · −1

The major product of the following reaction is: ethylbenzene →(ii) H3O+(i) alkaline KMnO4\xrightarrow[\text{(ii) H}_3\text{O}^+]{\text{(i) alkaline KMnO}_4}

  1. A.C6H5COCH3C_6H_5COCH_3
  2. B.C6H5COOHC_6H_5COOH
  3. C.C6H5CH2CHOC_6H_5CH_2CHO
  4. D.C6H5CH2COOHC_6H_5CH_2COOH

Correct answer: B

Question 36

Chemistry · 4 marks · −1

The organic compound that gives following qualitative analysis is: Test / Inference - (a) Dil. HCl: Insoluble; (b) NaOH solution: soluble; (c) Br2_2/water: Decolourization

  1. A.Cyclohexanol
  2. B.Aniline
  3. C.Phenol
  4. D.Cyclohexylamine

Correct answer: C

Question 37

Chemistry · 4 marks · −1

The correct IUPAC name of the following compound is: benzene ring with −NO2-NO_2 at the top, −CH3-CH_3 at the bottom (para to NO2NO_2) and −Cl-Cl adjacent to the CH3CH_3

  1. A.5-chloro-4-methyl-1-nitrobenzene
  2. B.2-chloro-1-methyl-4-nitrobenzene
  3. C.2-methyl-5-nitro-1-chlorobenzene
  4. D.3-chloro-4-methyl-1-nitrobenzene

Correct answer: B

Question 38

Chemistry · 4 marks · −1

Aniline dissolved in dilute HCl is reacted with sodium nitrite at 0°C. This solution was added dropwise to a solution containing equimolar mixture of aniline and phenol in dil. HCl. The structure of the major product is:

  1. A.C6H5−N=N−NH−C6H5C_6H_5-N=N-NH-C_6H_5
  2. B.C6H5−N=N−O−C6H5C_6H_5-N=N-O-C_6H_5
  3. C.C6H5−N=N−C6H4−NH2C_6H_5-N=N-C_6H_4-NH_2 (para)
  4. D.C6H5−N=N−C6H4−OHC_6H_5-N=N-C_6H_4-OH (para)

Correct answer: C

Question 39

Chemistry · 4 marks · −1

The element having greatest difference between its first and second ionization energies, is:

  1. A.K
  2. B.Ca
  3. C.Ba
  4. D.Sc

Correct answer: A

Question 40

Chemistry · 4 marks · −1

The ore that contains the metal in the form of fluoride is:

  1. A.sphalerite
  2. B.cryolite
  3. C.magnetite
  4. D.malachite

Correct answer: B

Question 41

Chemistry · 4 marks · −1

The number of water molecule(s) not coordinated to copper ion directly in CuSO4⋅5H2OCuSO_4\cdot5H_2O, is:

  1. A.1
  2. B.2
  3. C.3
  4. D.4

Correct answer: A

Question 42

Chemistry · 4 marks · −1

Magnesium powder burns in air to give:

  1. A.MgO only
  2. B.Mg(NO3)2Mg(NO_3)_2 and Mg3N2Mg_3N_2
  3. C.MgO and Mg3N2Mg_3N_2
  4. D.MgO and Mg(NO3)2Mg(NO_3)_2

Correct answer: C

Question 43

Chemistry · 4 marks · −1

The correct order of the oxidation states of nitrogen in NO, N2_2O, NO2_2 and N2_2O3_3 is:

  1. A.NO2<NO<N2O3<N2ONO_2 < NO < N_2O_3 < N_2O
  2. B.NO2<N2O3<NO<N2ONO_2 < N_2O_3 < NO < N_2O
  3. C.N2O<NO<N2O3<NO2N_2O < NO < N_2O_3 < NO_2
  4. D.N2O<N2O3<NO<NO2N_2O < N_2O_3 < NO < NO_2

Correct answer: C

Question 44

Chemistry · 4 marks · −1

C60C_{60}, an allotrope of carbon contains:

  1. A.20 hexagons and 12 pentagons.
  2. B.12 hexagons and 20 pentagons.
  3. C.16 hexagons and 16 pentagons.
  4. D.18 hexagons and 14 pentagons.

Correct answer: A

Question 45

Chemistry · 4 marks · −1

Match the catalysts (Column I) with products (Column II). Column I (Catalyst): (A) V2O5V_2O_5; (B) TiCl4/Al(Me)3TiCl_4/Al(Me)_3; (C) PdCl2PdCl_2; (D) Iron Oxide. Column II (Product): (i) Polyethylene; (ii) ethanal; (iii) H2SO4H_2SO_4; (iv) NH3NH_3

  1. A.(A)-(ii); (B)-(iii); (C)-(i); (D)-(iv)
  2. B.(A)-(iv); (B)-(iii); (C)-(ii); (D)-(i)
  3. C.(A)-(iii); (B)-(iv); (C)-(i); (D)-(ii)
  4. D.(A)-(iii); (B)-(i); (C)-(ii); (D)-(iv)

Correct answer: D

Question 46

Chemistry · 4 marks · −1

The one that will show optical activity is: (en = ethane-1,2-diamine)

Figure for question 46
  1. A.[M(A)2(B)2(en)] with the two A ligands cis, the two B ligands cis and en spanning two cis positions
  2. B.[M(A)2(B)4] with the two A ligands trans (axial)
  3. C.[M(en)2(A)2] with the two A ligands trans (axial)
  4. D.[M(A)3(B)3]

Correct answer: A

Question 47

Chemistry · 4 marks · −1

The degenerate orbitals of [Cr(H2O)6]3+[Cr(H_2O)_6]^{3+} are:

  1. A.dx2−y2d_{x^2-y^2} and dxyd_{xy}
  2. B.dxzd_{xz} and dyzd_{yz}
  3. C.dz2d_{z^2} and dxzd_{xz}
  4. D.dyzd_{yz} and dz2d_{z^2}

Correct answer: B

Question 48

Chemistry · 4 marks · −1

Excessive release of CO2_2 into the atmosphere results in:

  1. A.depletion of ozone
  2. B.formation of smog
  3. C.global warming
  4. D.polar vortex

Correct answer: C

Question 49

Chemistry · 4 marks · −1

For a reaction, N2(g)+3H2(g)→2NH3(g)N_2(g) + 3H_2(g) \rightarrow 2NH_3(g); identify dihydrogen (H2_2) as a limiting reagent in the following reaction mixtures.

  1. A.14 g of N2N_2 + 4 g of H2H_2
  2. B.28 g of N2N_2 + 6 g of H2H_2
  3. C.35 g of N2N_2 + 8 g of H2H_2
  4. D.56 g of N2N_2 + 10 g of H2H_2

Correct answer: D

Question 50

Chemistry · 4 marks · −1

Consider the van der Waals constants, a and b, for the following gases. Gas: Ar, Ne, Kr, Xe; a/(atm dm6^6 mol−2^{-2}): 1.3, 0.2, 5.1, 4.1; b/(10−210^{-2} dm3^3 mol−1^{-1}): 3.2, 1.7, 1.0, 5.0. Which gas is expected to have the highest critical temperature?

  1. A.Ar
  2. B.Ne
  3. C.Kr
  4. D.Xe

Correct answer: C

Question 51

Chemistry · 4 marks · −1

For any given series of spectral lines of atomic hydrogen, let Δvˉ=vˉmax−vˉmin\Delta\bar{v} = \bar{v}_{max} - \bar{v}_{min} be the difference in maximum and minimum frequencies in cm−1^{-1}. The ratio ΔvˉLyman/ΔvˉBalmer\Delta\bar{v}_{Lyman}/\Delta\bar{v}_{Balmer} is:

  1. A.27 : 5
  2. B.4 : 1
  3. C.9 : 4
  4. D.5 : 4

Correct answer: C

Question 52

Chemistry · 4 marks · −1

Among the following, the molecule expected to be stabilized by anion formation is: C2C_2, O2O_2, NO, F2F_2

  1. A.O2O_2
  2. B.C2C_2
  3. C.NO
  4. D.F2F_2

Correct answer: B

Question 53

Chemistry · 4 marks · −1

Among the following, the set of parameters that represents path functions, is: (A) q + w (B) q (C) w (D) H − TS

  1. A.(A) and (D)
  2. B.(B) and (C)
  3. C.(B), (C) and (D)
  4. D.(A), (B) and (C)

Correct answer: B

Question 54

Chemistry · 4 marks · −1

Liquid 'M' and liquid 'N' form an ideal solution. The vapour pressures of pure liquids 'M' and 'N' are 450 and 700 mmHg, respectively, at the same temperature. Then correct statement is: (xMx_M = Mole fraction of 'M' in solution; xNx_N = Mole fraction of 'N' in solution; yMy_M = Mole fraction of 'M' in vapour phase; yNy_N = Mole fraction of 'N' in vapour phase)

  1. A.xMxN=yMyN\dfrac{x_M}{x_N} = \dfrac{y_M}{y_N}
  2. B.xMxN>yMyN\dfrac{x_M}{x_N} > \dfrac{y_M}{y_N}
  3. C.xMxN<yMyN\dfrac{x_M}{x_N} < \dfrac{y_M}{y_N}
  4. D.(xM−yM)<(xN−yN)(x_M - y_M) < (x_N - y_N)

Correct answer: B

Question 55

Chemistry · 4 marks · −1

The osmotic pressure of a dilute solution of an ionic compound XY in water is four times that of a solution of 0.01 M BaCl2_2 in water. Assuming complete dissociation of the given ionic compounds in water, the concentration of XY (in mol L−1^{-1}) in solution is:

  1. A.4×10−24\times10^{-2}
  2. B.16×10−416\times10^{-4}
  3. C.6×10−26\times10^{-2}
  4. D.4×10−44\times10^{-4}

Correct answer: C

Question 56

Chemistry · 4 marks · −1

The standard Gibbs energy for the given cell reaction in kJ mol−1^{-1} at 298 K is: Zn(s)+Cu2+(aq)→Zn2+(aq)+Cu(s)Zn(s) + Cu^{2+}(aq) \rightarrow Zn^{2+}(aq) + Cu(s), Eo=2E^o = 2 V at 298 K (Faraday's constant, F = 96000 C mol−1^{-1})

  1. A.192
  2. B.384
  3. C.−384
  4. D.−192

Correct answer: C

Question 57

Chemistry · 4 marks · −1

The given plots represent the variation of the concentration of a reactant R with time for two different reactions (i) and (ii). The respective orders of the reactions are:

Figure for question 57
  1. A.0, 1
  2. B.1, 0
  3. C.1, 1
  4. D.0, 2

Correct answer: B

Question 58

Chemistry · 4 marks · −1

The aerosol is a kind of colloid in which:

  1. A.liquid is dispersed in water
  2. B.gas is dispersed in liquid
  3. C.gas is dispersed in solid
  4. D.solid is dispersed in gas

Correct answer: D

Question 59

Mathematics · 4 marks · −1

If the function f:R−{1,−1}→Af: \mathbb{R} - \{1, -1\} \rightarrow A defined by f(x)=x21−x2f(x) = \dfrac{x^2}{1 - x^2}, is surjective, then A is equal to:

  1. A.R−[−1,0)\mathbb{R} - [-1, 0)
  2. B.R−{−1}\mathbb{R} - \{-1\}
  3. C.R−(−1,0)\mathbb{R} - (-1, 0)
  4. D.[0,∞)[0, \infty)

Correct answer: A

Question 60

Mathematics · 4 marks · −1

All the points in the set S={α+iα−i:α∈R}S = \left\{\dfrac{\alpha + i}{\alpha - i} : \alpha \in \mathbb{R}\right\} (i=−1)(i = \sqrt{-1}) lie on a:

  1. A.circle whose radius is 2\sqrt{2}.
  2. B.circle whose radius is 1.
  3. C.straight line whose slope is 1.
  4. D.straight line whose slope is −1.

Correct answer: B

Question 61

Mathematics · 4 marks · −1

Let p, q ∈R\in \mathbb{R}. If 2−32 - \sqrt{3} is a root of the quadratic equation, x2+px+q=0x^2 + px + q = 0, then:

  1. A.p2−4q+12=0p^2 - 4q + 12 = 0
  2. B.q2−4p−16=0q^2 - 4p - 16 = 0
  3. C.p2−4q−12=0p^2 - 4q - 12 = 0
  4. D.q2+4p+14=0q^2 + 4p + 14 = 0

Correct answer: D

Question 62

Mathematics · 4 marks · −1

Let α\alpha and β\beta be the roots of the equation x2+x+1=0x^2 + x + 1 = 0. Then for y≠0y \ne 0 in R\mathbb{R}, ∣y+1αβαy+β1β1y+α∣\begin{vmatrix} y+1 & \alpha & \beta \\ \alpha & y+\beta & 1 \\ \beta & 1 & y+\alpha \end{vmatrix} is equal to:

  1. A.y(y2−3)y(y^2 - 3)
  2. B.y3−1y^3 - 1
  3. C.y(y2−1)y(y^2 - 1)
  4. D.y3y^3

Correct answer: D

Question 63

Mathematics · 4 marks · −1

If [1101]⋅[1201]⋅[1301]⋯[1n−101]=[17801]\begin{bmatrix} 1 & 1 \\ 0 & 1 \end{bmatrix}\cdot\begin{bmatrix} 1 & 2 \\ 0 & 1 \end{bmatrix}\cdot\begin{bmatrix} 1 & 3 \\ 0 & 1 \end{bmatrix}\cdots\begin{bmatrix} 1 & n-1 \\ 0 & 1 \end{bmatrix} = \begin{bmatrix} 1 & 78 \\ 0 & 1 \end{bmatrix}, then the inverse of [1n01]\begin{bmatrix} 1 & n \\ 0 & 1 \end{bmatrix} is:

  1. A.[10121]\begin{bmatrix} 1 & 0 \\ 12 & 1 \end{bmatrix}
  2. B.[10131]\begin{bmatrix} 1 & 0 \\ 13 & 1 \end{bmatrix}
  3. C.[1−1301]\begin{bmatrix} 1 & -13 \\ 0 & 1 \end{bmatrix}
  4. D.[1−1201]\begin{bmatrix} 1 & -12 \\ 0 & 1 \end{bmatrix}

Correct answer: C

Question 64

Mathematics · 4 marks · −1

A committee of 11 members is to be formed from 8 males and 5 females. If m is the number of ways the committee is formed with at least 6 males and n is the number of ways the committee is formed with at least 3 females, then:

  1. A.n = m − 8
  2. B.m = n = 78
  3. C.m = n = 68
  4. D.m + n = 68

Correct answer: B

Question 65

Mathematics · 4 marks · −1

Let the sum of the first n terms of a non-constant A.P., a1,a2,a3,…a_1, a_2, a_3, \ldots be 50n+n(n−7)2A50n + \dfrac{n(n-7)}{2}A, where A is a constant. If d is the common difference of this A.P., then the ordered pair (d,a50)(d, a_{50}) is equal to:

  1. A.(50, 50 + 46A)
  2. B.(A, 50 + 46A)
  3. C.(A, 50 + 45A)
  4. D.(50, 50 + 45A)

Correct answer: B

Question 66

Mathematics · 4 marks · −1

Let ∑k=110f(a+k)=16(210−1)\displaystyle\sum_{k=1}^{10} f(a + k) = 16(2^{10} - 1), where the function f satisfies f(x+y)=f(x)f(y)f(x + y) = f(x)f(y) for all natural numbers x, y and f(1)=2f(1) = 2. Then the natural number 'a' is:

  1. A.2
  2. B.3
  3. C.4
  4. D.16

Correct answer: B

Question 67

Mathematics · 4 marks · −1

If the fourth term in the Binomial expansion of (2x+xlog⁡8x)6\left(\dfrac{2}{x} + x^{\log_8 x}\right)^6 (x>0)(x > 0) is 20×8720\times8^7, then a value of x is:

  1. A.828^2
  2. B.8
  3. C.838^3
  4. D.8−28^{-2}

Correct answer: A

Question 68

Mathematics · 4 marks · −1

If the function f defined on (π6,π3)\left(\dfrac{\pi}{6}, \dfrac{\pi}{3}\right) by f(x)={2cos⁡x−1cot⁡x−1,x≠π4k,x=π4f(x) = \begin{cases} \dfrac{\sqrt{2}\cos x - 1}{\cot x - 1}, & x \ne \dfrac{\pi}{4} \\ k, & x = \dfrac{\pi}{4} \end{cases} is continuous, then k is equal to:

  1. A.2
  2. B.12\dfrac{1}{2}
  3. C.1
  4. D.12\dfrac{1}{\sqrt{2}}

Correct answer: B

Question 69

Mathematics · 4 marks · −1

Let f(x)=15−∣x−10∣f(x) = 15 - |x - 10|; x∈Rx \in \mathbb{R}. Then the set of all values of x, at which the function, g(x)=f(f(x))g(x) = f(f(x)) is not differentiable, is:

  1. A.{10}\{10\}
  2. B.{10,15}\{10, 15\}
  3. C.{5,10,15}\{5, 10, 15\}
  4. D.{5,10,15,20}\{5, 10, 15, 20\}

Correct answer: C

Question 70

Mathematics · 4 marks · −1

Let S be the set of all values of x for which the tangent to the curve y=f(x)=x3−x2−2xy = f(x) = x^3 - x^2 - 2x at (x, y) is parallel to the line segment joining the points (1, f(1)) and (−1, f(−1)), then S is equal to:

  1. A.{13,1}\left\{\dfrac{1}{3}, 1\right\}
  2. B.{13,−1}\left\{\dfrac{1}{3}, -1\right\}
  3. C.{−13,−1}\left\{-\dfrac{1}{3}, -1\right\}
  4. D.{−13,1}\left\{-\dfrac{1}{3}, 1\right\}

Correct answer: D

Question 71

Mathematics · 4 marks · −1

If f(x) is a non-zero polynomial of degree four, having local extreme points at x = −1, 0, 1; then the set S={x∈R:f(x)=f(0)}S = \{x \in \mathbb{R} : f(x) = f(0)\} contains exactly:

  1. A.two irrational and two rational numbers.
  2. B.two irrational and one rational number.
  3. C.four rational numbers.
  4. D.four irrational numbers.

Correct answer: B

Question 72

Mathematics · 4 marks · −1

The integral ∫sec⁡2/3x cosec4/3x dx\displaystyle\int \sec^{2/3}x\,\text{cosec}^{4/3}x\,dx is equal to: (Here C is a constant of integration)

  1. A.−3cot⁡−1/3x+C-3\cot^{-1/3}x + C
  2. B.−3tan⁡−1/3x+C-3\tan^{-1/3}x + C
  3. C.−34tan⁡−4/3x+C-\dfrac{3}{4}\tan^{-4/3}x + C
  4. D.3tan⁡−1/3x+C3\tan^{-1/3}x + C

Correct answer: B

Question 73

Mathematics · 4 marks · −1

The value of ∫0π/2sin⁡3xsin⁡x+cos⁡x dx\displaystyle\int_0^{\pi/2} \frac{\sin^3 x}{\sin x + \cos x}\,dx is:

  1. A.π−12\dfrac{\pi - 1}{2}
  2. B.π−14\dfrac{\pi - 1}{4}
  3. C.π−28\dfrac{\pi - 2}{8}
  4. D.π−24\dfrac{\pi - 2}{4}

Correct answer: B

Question 74

Mathematics · 4 marks · −1

The area (in sq. units) of the region A={(x,y):x2≤y≤x+2}A = \{(x, y) : x^2 \le y \le x + 2\} is:

  1. A.316\dfrac{31}{6}
  2. B.103\dfrac{10}{3}
  3. C.136\dfrac{13}{6}
  4. D.92\dfrac{9}{2}

Correct answer: D

Question 75

Mathematics · 4 marks · −1

The solution of the differential equation xdydx+2y=x2x\dfrac{dy}{dx} + 2y = x^2 (x≠0)(x \ne 0) with y(1)=1y(1) = 1, is:

  1. A.y=34x2+14x2y = \dfrac{3}{4}x^2 + \dfrac{1}{4x^2}
  2. B.y=45x3+15x2y = \dfrac{4}{5}x^3 + \dfrac{1}{5x^2}
  3. C.y=x24+34x2y = \dfrac{x^2}{4} + \dfrac{3}{4x^2}
  4. D.y=x35+15x2y = \dfrac{x^3}{5} + \dfrac{1}{5x^2}

Correct answer: C

Question 76

Mathematics · 4 marks · −1

If the tangent to the curve, y=x3+ax−by = x^3 + ax - b at the point (1, −5) is perpendicular to the line, −x+y+4=0-x + y + 4 = 0, then which one of the following points lies on the curve?

  1. A.(2, −1)
  2. B.(2, −2)
  3. C.(−2, 1)
  4. D.(−2, 2)

Correct answer: B

Question 77

Mathematics · 4 marks · −1

Slope of a line passing through P(2, 3) and intersecting the line, x+y=7x + y = 7 at a distance of 4 units from P, is:

  1. A.5−15+1\dfrac{\sqrt{5} - 1}{\sqrt{5} + 1}
  2. B.1−51+5\dfrac{1 - \sqrt{5}}{1 + \sqrt{5}}
  3. C.7−17+1\dfrac{\sqrt{7} - 1}{\sqrt{7} + 1}
  4. D.1−71+7\dfrac{1 - \sqrt{7}}{1 + \sqrt{7}}

Correct answer: D

Question 78

Mathematics · 4 marks · −1

If a tangent to the circle x2+y2=1x^2 + y^2 = 1 intersects the coordinate axes at distinct points P and Q, then the locus of the mid-point of PQ is:

  1. A.x2+y2−2xy=0x^2 + y^2 - 2xy = 0
  2. B.x2+y2−2x2y2=0x^2 + y^2 - 2x^2y^2 = 0
  3. C.x2+y2−4x2y2=0x^2 + y^2 - 4x^2y^2 = 0
  4. D.x2+y2−16x2y2=0x^2 + y^2 - 16x^2y^2 = 0

Correct answer: C

Question 79

Mathematics · 4 marks · −1

If one end of a focal chord of the parabola, y2=16xy^2 = 16x is at (1, 4), then the length of this focal chord is:

  1. A.25
  2. B.24
  3. C.22
  4. D.20

Correct answer: A

Question 80

Mathematics · 4 marks · −1

If the line y=mx+73y = mx + 7\sqrt{3} is normal to the hyperbola x224−y218=1\dfrac{x^2}{24} - \dfrac{y^2}{18} = 1, then a value of m is:

  1. A.25\dfrac{2}{\sqrt{5}}
  2. B.52\dfrac{\sqrt{5}}{2}
  3. C.35\dfrac{3}{\sqrt{5}}
  4. D.152\dfrac{\sqrt{15}}{2}

Correct answer: A

Question 81

Mathematics · 4 marks · −1

If the line, x−12=y+13=z−24\dfrac{x-1}{2} = \dfrac{y+1}{3} = \dfrac{z-2}{4} meets the plane, x+2y+3z=15x + 2y + 3z = 15 at a point P, then the distance of P from the origin is:

  1. A.7/2
  2. B.9/2
  3. C.252\sqrt{5}
  4. D.5/2\sqrt{5}/2

Correct answer: B

Question 82

Mathematics · 4 marks · −1

A plane passing through the points (0, −1, 0) and (0, 0, 1) and making an angle π4\dfrac{\pi}{4} with the plane y−z+5=0y - z + 5 = 0, also passes through the point:

  1. A.(2,−1,4)(\sqrt{2}, -1, 4)
  2. B.(−2,−1,−4)(-\sqrt{2}, -1, -4)
  3. C.(−2,1,−4)(-\sqrt{2}, 1, -4)
  4. D.(2,1,4)(\sqrt{2}, 1, 4)

Correct answer: D

Question 83

Mathematics · 4 marks · −1

Let α⃗=3i^+j^\vec{\alpha} = 3\hat{i} + \hat{j} and β⃗=2i^−j^+3k^\vec{\beta} = 2\hat{i} - \hat{j} + 3\hat{k}. If β⃗=β⃗1−β⃗2\vec{\beta} = \vec{\beta}_1 - \vec{\beta}_2, where β⃗1\vec{\beta}_1 is parallel to α⃗\vec{\alpha} and β⃗2\vec{\beta}_2 is perpendicular to α⃗\vec{\alpha}, then β⃗1×β⃗2\vec{\beta}_1 \times \vec{\beta}_2 is equal to:

  1. A.12(−3i^+9j^+5k^)\dfrac{1}{2}(-3\hat{i} + 9\hat{j} + 5\hat{k})
  2. B.12(3i^−9j^+5k^)\dfrac{1}{2}(3\hat{i} - 9\hat{j} + 5\hat{k})
  3. C.−3i^+9j^+5k^-3\hat{i} + 9\hat{j} + 5\hat{k}
  4. D.3i^−9j^−5k^3\hat{i} - 9\hat{j} - 5\hat{k}

Correct answer: A

Question 84

Mathematics · 4 marks · −1

Four persons can hit a target correctly with probabilities 12,13,14\dfrac{1}{2}, \dfrac{1}{3}, \dfrac{1}{4} and 18\dfrac{1}{8} respectively. If all hit at the target independently, then the probability that the target would be hit, is:

  1. A.2532\dfrac{25}{32}
  2. B.1192\dfrac{1}{192}
  3. C.732\dfrac{7}{32}
  4. D.25192\dfrac{25}{192}

Correct answer: A

Question 85

Mathematics · 4 marks · −1

If the standard deviation of the numbers −1, 0, 1, k is 5\sqrt{5} where k > 0, then k is equal to:

  1. A.6\sqrt{6}
  2. B.21032\sqrt{\dfrac{10}{3}}
  3. C.262\sqrt{6}
  4. D.4534\sqrt{\dfrac{5}{3}}

Correct answer: C

Question 86

Mathematics · 4 marks · −1

The value of cos⁡210°−cos⁡10°cos⁡50°+cos⁡250°\cos^2 10° - \cos 10°\cos 50° + \cos^2 50° is:

  1. A.34+cos⁡20°\dfrac{3}{4} + \cos 20°
  2. B.3/4
  3. C.32(1+cos⁡20°)\dfrac{3}{2}(1 + \cos 20°)
  4. D.3/2

Correct answer: B

Question 87

Mathematics · 4 marks · −1

Let S={θ∈[−2π,2π]:2cos⁡2θ+3sin⁡θ=0}S = \{\theta \in [-2\pi, 2\pi] : 2\cos^2\theta + 3\sin\theta = 0\}. Then the sum of the elements of S is:

  1. A.13π6\dfrac{13\pi}{6}
  2. B.5π3\dfrac{5\pi}{3}
  3. C.2π2\pi
  4. D.π\pi

Correct answer: C

Question 88

Mathematics · 4 marks · −1

For any two statements p and q, the negation of the expression p∨(∼p∧q)p \vee (\sim p \wedge q) is:

  1. A.∼p∧∼q\sim p \wedge \sim q
  2. B.∼p∨∼q\sim p \vee \sim q
  3. C.p∧qp \wedge q
  4. D.p↔qp \leftrightarrow q

Correct answer: A

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