JEE Main 2019 — 9 Jan Shift 1 (Previous Year Paper)

JEE Main · 2019 · with answers and explanations

questions
87
Total marks
348
Duration
180 minutes
Negative marking
−1

Subjects: Physics · Chemistry · Mathematics

Question 1

Physics · 4 marks · −1

A copper wire is stretched to make it 0.5% longer. The percentage change in its electrical resistance if its volume remains unchanged is:

  1. A.0.5 %
  2. B.1.0 %
  3. C.2.5 %
  4. D.2.0 %

Correct answer: B

Question 2

Physics · 4 marks · −1

A particle is moving with a velocity v⃗=K(yi^+xj^)\vec{v} = K(y\hat{i} + x\hat{j}), where K is a constant. The general equation for its path is:

  1. A.y2=x2+constanty^2 = x^2 + \text{constant}
  2. B.y=x2+constanty = x^2 + \text{constant}
  3. C.y2=x+constanty^2 = x + \text{constant}
  4. D.xy=constantxy = \text{constant}

Correct answer: A

Question 3

Physics · 4 marks · −1

A block of mass 10 kg is kept on a rough inclined plane as shown in the figure. A force of 3 N is applied on the block. The coefficient of static friction between the plane and the block is 0.6. What should be the minimum value of force P, such that the block does not move downward? (take g=10 m s−2g = 10\ \text{m s}^{-2})

Figure for question 3
  1. A.25 N
  2. B.32 N
  3. C.23 N
  4. D.18 N

Correct answer: B

Question 4

Physics · 4 marks · −1

Three blocks A, B and C are lying on a smooth horizontal surface, as shown in the figure. A and B have equal masses, m while C has mass M. Block A is given an initial speed vv towards B due to which it collides with B perfectly inelastically. The combined mass collides with C, also perfectly inelastically. 56\frac{5}{6}th of the initial kinetic energy is lost in the whole process. What is value of M/mM/m?

Figure for question 4
  1. A.3
  2. B.4
  3. C.2
  4. D.5

Correct answer: B

Question 5

Physics · 4 marks · −1

An L-shaped object, made of thin rods of uniform mass density, is suspended with a string as shown in figure. If AB = BC, and the angle made by AB with downward vertical is θ\theta, then:

Figure for question 5
  1. A.tan⁡θ=12\tan\theta = \frac{1}{2}
  2. B.tan⁡θ=13\tan\theta = \frac{1}{3}
  3. C.tan⁡θ=23\tan\theta = \frac{2}{\sqrt{3}}
  4. D.tan⁡θ=123\tan\theta = \frac{1}{2\sqrt{3}}

Correct answer: B

Question 6

Physics · 4 marks · −1

A block of mass m, lying on a smooth horizontal surface, is attached to a spring (of negligible mass) of spring constant k. The other end of the spring is fixed, as shown in the figure. The block is initially at rest in its equilibrium position. If now the block is pulled with a constant force F, the maximum speed of the block is:

Figure for question 6
  1. A.2Fmk\frac{2F}{\sqrt{mk}}
  2. B.Fπmk\frac{F}{\pi\sqrt{mk}}
  3. C.Fmk\frac{F}{\sqrt{mk}}
  4. D.πFmk\frac{\pi F}{\sqrt{mk}}

Correct answer: C

Question 7

Physics · 4 marks · −1

If the angular momentum of a planet of mass m, moving around the Sun in a circular orbit is L, about the center of the Sun, its areal velocity is:

  1. A.Lm\frac{L}{m}
  2. B.2Lm\frac{2L}{m}
  3. C.L2m\frac{L}{2m}
  4. D.4Lm\frac{4L}{m}

Correct answer: C

Question 8

Physics · 4 marks · −1

A rod, of length L at room temperature and uniform area of cross section A, is made of a metal having coefficient of linear expansion α/∘C\alpha/^\circ\text{C}. It is observed that an external compressive force F, is applied on each of its ends, prevents any change in the length of the rod, when its temperature rises by ΔT\Delta T K. Young's modulus, Y, for this metal is:

  1. A.FAα(ΔT−273)\frac{F}{A\alpha(\Delta T - 273)}
  2. B.FAαΔT\frac{F}{A\alpha\Delta T}
  3. C.F2AαΔT\frac{F}{2A\alpha\Delta T}
  4. D.2FAαΔT\frac{2F}{A\alpha\Delta T}

Correct answer: B

Question 9

Physics · 4 marks · −1

Temperature difference of 120°C is maintained between two ends of a uniform rod AB of length 2L. Another bent rod PQ, of same cross-section as AB and length 3L2\frac{3L}{2}, is connected across AB (See figure). In steady state, temperature difference between P and Q will be close to:

Figure for question 9
  1. A.60 °C
  2. B.75 °C
  3. C.35 °C
  4. D.45 °C

Correct answer: D

Question 10

Physics · 4 marks · −1

A gas can be taken from A to B via two different processes ACB and ADB. When path ACB is used 60 J of heat flows into the system and 30 J of work is done by the system. If path ADB is used work done by the system is 10 J. The heat flow into the system in path ADB is:

Figure for question 10
  1. A.100 J
  2. B.20 J
  3. C.80 J
  4. D.40 J

Correct answer: D

Question 11

Physics · 4 marks · −1

A mixture of 2 moles of helium gas (atomic mass = 4 u), and 1 mole of argon gas (atomic mass = 40 u) is kept at 300 K in a container. The ratio of their rms speeds [Vrms(helium)Vrms(argon)]\left[\frac{V_{rms}(\text{helium})}{V_{rms}(\text{argon})}\right], is close to:

  1. A.0.32
  2. B.0.45
  3. C.2.24
  4. D.3.16

Correct answer: D

Question 12

Physics · 4 marks · −1

Two masses m and m2\frac{m}{2} are connected at the two ends of a massless rigid rod of length ll. The rod is suspended by a thin wire of torsional constant kk at the centre of mass of the rod-mass system (see figure). Because of torsional constant kk, the restoring torque is τ=kθ\tau = k\theta for angular displacement θ\theta. If the rod is rotated by θ0\theta_0 and released, the tension in it when it passes through its mean position will be:

Figure for question 12
  1. A.kθ022l\frac{k\theta_0^2}{2l}
  2. B.kθ02l\frac{k\theta_0^2}{l}
  3. C.2kθ02l\frac{2k\theta_0^2}{l}
  4. D.3kθ02l\frac{3k\theta_0^2}{l}

Correct answer: B

Question 13

Physics · 4 marks · −1

A heavy ball of mass M is suspended from the ceiling of a car by a light string of mass m (m << M). When the car is at rest, the speed of transverse waves in the string is 60 m s−1^{-1}. When the car has acceleration a, the wave-speed increases to 60.5 m s−1^{-1}. The value of a, in terms of gravitational acceleration g, is closest to:

  1. A.g10\frac{g}{10}
  2. B.g5\frac{g}{5}
  3. C.g20\frac{g}{20}
  4. D.g30\frac{g}{30}

Correct answer: B

Question 14

Physics · 4 marks · −1

Three charges +Q, q, +Q are placed respectively, at distance, 0, d/2 and d from the origin, on the x-axis. If the net force experienced by +Q, placed at x = 0, is zero, then value of q is:

  1. A.+Q/4
  2. B.−Q/4
  3. C.+Q/2
  4. D.−Q/2

Correct answer: B

Question 15

Physics · 4 marks · −1

For a uniformly charged ring of radius R, the electric field on its axis has the largest magnitude at a distance h from its centre. Then value of h is:

  1. A.R
  2. B.R2R\sqrt{2}
  3. C.R2\frac{R}{\sqrt{2}}
  4. D.R5\frac{R}{\sqrt{5}}

Correct answer: C

Question 16

Physics · 4 marks · −1

A parallel plate capacitor is made of two square plates of side 'a', separated by a distance d (d << a). The lower triangular portion is filled with a dielectric of dielectric constant K, as shown in the figure. Capacitance of this capacitor is:

Figure for question 16
  1. A.12Kϵ0a2d\frac{1}{2}\frac{K\epsilon_0 a^2}{d}
  2. B.Kϵ0a2dln⁡K\frac{K\epsilon_0 a^2}{d}\ln K
  3. C.Kϵ0a22d(K+1)\frac{K\epsilon_0 a^2}{2d(K+1)}
  4. D.Kϵ0a2d(K−1)ln⁡K\frac{K\epsilon_0 a^2}{d(K-1)}\ln K

Correct answer: D

Question 17

Physics · 4 marks · −1

Drift speed of electrons, when 1.5 A of current flows in a copper wire of cross section 5 mm2^2, is vv. If the electron density in copper is 9×1028/m39 \times 10^{28}/\text{m}^3 the value of vv in mm/s is close to (Take charge of electron to be =1.6×10−19= 1.6 \times 10^{-19} C)

  1. A.3
  2. B.2
  3. C.0.2
  4. D.0.02

Correct answer: D

Question 18

Physics · 4 marks · −1

When the switch S, in the circuit shown, is closed, then the value of current ii will be:

Figure for question 18
  1. A.2 A
  2. B.3 A
  3. C.4 A
  4. D.5 A

Correct answer: D

Question 19

Physics · 4 marks · −1

A current loop, having two circular arcs joined by two radial lines is shown in the figure. It carries a current of 10 A. The magnetic field at point O will be close to:

Figure for question 19
  1. A.1.5×10−51.5 \times 10^{-5} T
  2. B.1.5×10−71.5 \times 10^{-7} T
  3. C.1.0×10−51.0 \times 10^{-5} T
  4. D.1.0×10−71.0 \times 10^{-7} T

Correct answer: C

Question 20

Physics · 4 marks · −1

An infinitely long current carrying wire and a small current carrying loop are in the plane of the paper as shown. The radius of the loop is a and distance of its centre from the wire is d (d >> a). If the loop applies a force F on the wire then:

Figure for question 20
  1. A.F=0F = 0
  2. B.F∝(ad)F \propto \left(\frac{a}{d}\right)
  3. C.F∝(ad)2F \propto \left(\frac{a}{d}\right)^2
  4. D.F∝(a2d3)F \propto \left(\frac{a^2}{d^3}\right)

Correct answer: C

Question 21

Physics · 4 marks · −1

A bar magnet is demagnetized by inserting it inside a solenoid of length 0.2 m, 100 turns, and carrying a current of 5.2 A. The coercivity of the bar magnet is:

  1. A.1200 A/m
  2. B.520 A/m
  3. C.285 A/m
  4. D.2600 A/m

Correct answer: D

Question 22

Physics · 4 marks · −1

A plane electromagnetic wave of frequency 50 MHz travels in free space along the positive x-direction. At a particular point in space and time, E⃗=6.3j^\vec{E} = 6.3\hat{j} V/m. The corresponding magnetic field B⃗\vec{B}, at that point will be:

  1. A.6.3×10−8 k^6.3 \times 10^{-8}\,\hat{k} T
  2. B.2.1×10−8 k^2.1 \times 10^{-8}\,\hat{k} T
  3. C.18.9×108 k^18.9 \times 10^{8}\,\hat{k} T
  4. D.18.9×10−8 k^18.9 \times 10^{-8}\,\hat{k} T

Correct answer: B

Question 23

Physics · 4 marks · −1

A convex lens is put 10 cm from a light source and it makes a sharp image on a screen, kept 10 cm from the lens. Now a glass block (refractive index 1.5) of 1.5 cm thickness is placed in contact with the light source. To get the sharp image again, the screen is shifted by a distance d. Then d is:

  1. A.0
  2. B.0.55 cm towards the lens
  3. C.0.55 cm away from the lens
  4. D.1.1 cm away from the lens

Correct answer: C

Question 24

Physics · 4 marks · −1

Two coherent sources produce waves of different intensities which interfere. After interference, the ratio of the maximum intensity to the minimum intensity is 16. The intensity of the waves are in the ratio:

  1. A.4 : 1
  2. B.16 : 9
  3. C.25 : 9
  4. D.5 : 3

Correct answer: C

Question 25

Physics · 4 marks · −1

Consider a tank made of glass (refractive index 1.5) with a thick bottom. It is filled with a liquid of refractive index μ\mu. A student finds that, irrespective of what the incident angle ii (see figure) is for a beam of light entering the liquid, the light reflected from the liquid glass interface is never completely polarized. For this to happen, the minimum value of μ\mu is:

Figure for question 25
  1. A.43\frac{4}{3}
  2. B.35\frac{3}{\sqrt{5}}
  3. C.53\frac{5}{\sqrt{3}}
  4. D.53\sqrt{\frac{5}{3}}

Correct answer: B

Question 26

Physics · 4 marks · −1

Surface of certain metal is first illuminated with light of wavelength λ1=350\lambda_1 = 350 nm and then, by light of wavelength λ2=540\lambda_2 = 540 nm. It is found that the maximum speed of the photo electrons in the two cases differ by a factor of 2. The work function of the metal (in eV) is close to: (Energy of photon =1240λ(in nm)= \frac{1240}{\lambda(\text{in nm})} eV)

  1. A.1.8
  2. B.5.6
  3. C.1.4
  4. D.2.5

Correct answer: A

Question 27

Physics · 4 marks · −1

A sample of radioactive material A, that has an activity of 10 mCi (1 Ci = 3.7×10103.7 \times 10^{10} decays/s), has twice the number of nuclei as another sample of a different radioactive material B which has an activity of 20 mCi. The correct choices for half-lives of A and B would then be respectively:

  1. A.20 days and 10 days
  2. B.20 days and 5 days
  3. C.5 days and 10 days
  4. D.10 days and 40 days

Correct answer: B

Question 28

Physics · 4 marks · −1

Mobility of electrons in a semiconductor is defined as the ratio of their drift velocity to the applied electric field. If, for an n-type semiconductor, the density of electrons is 101910^{19} m−3^{-3} and their mobility is 1.6 m2^2/(V.s) then the resistivity of the semiconductor (since it is an n-type semiconductor contribution of holes is ignored) is close to:

  1. A.0.2 Ωm
  2. B.2 Ωm
  3. C.4 Ωm
  4. D.0.4 Ωm

Correct answer: D

Question 29

Physics · 4 marks · −1

A resistance is shown in the figure. Its value and tolerance are given respectively by:

Figure for question 29
  1. A.270 Ω, 5 %
  2. B.27 kΩ, 10 %
  3. C.27 kΩ, 20 %
  4. D.270 Ω, 10 %

Correct answer: B

Question 30

Chemistry · 4 marks · −1

Major product of the following reaction is: 2-chloroprop-2-enoyl chloride (CH2=C(Cl)−COCl\text{CH}_2=\text{C(Cl)}-\text{COCl}) + H2N−CH2−CO−NH2\text{H}_2\text{N}-\text{CH}_2-\text{CO}-\text{NH}_2 →(1) Et3N, (2) Free radical polymerisation\xrightarrow{\text{(1) Et}_3\text{N},\ \text{(2) Free radical polymerisation}} ?

Figure for question 30
  1. A.Polymer −[CH2−C(Cl)]n−-[\text{CH}_2-\text{C(Cl)}]_n- whose side chain is −CO−NH−CH2−CH2−NH2-\text{CO}-\text{NH}-\text{CH}_2-\text{CH}_2-\text{NH}_2 (no carbonyl in the amine part)
  2. B.Polymer −[CH2−C(Cl)]n−-[\text{CH}_2-\text{C(Cl)}]_n- whose side chain is −CO−NH−CH2−CO−NH2-\text{CO}-\text{NH}-\text{CH}_2-\text{CO}-\text{NH}_2
  3. C.Polymer −[CH2−CH]n−-[\text{CH}_2-\text{CH}]_n- with a −COCl-\text{COCl} group on the chain and a side chain −NH−CH2−CO−NH2-\text{NH}-\text{CH}_2-\text{CO}-\text{NH}_2 attached through nitrogen
  4. D.Polymer with a −COCl-\text{COCl} group on the chain and a side chain −NH−CO−CH2−NH2-\text{NH}-\text{CO}-\text{CH}_2-\text{NH}_2 attached through nitrogen

Correct answer: B

Question 31

Chemistry · 4 marks · −1

The increasing order of pKa of the following amino acids in aqueous solution is: Gly Asp Lys Arg

  1. A.Gly < Asp < Arg < Lys
  2. B.Asp < Gly < Lys < Arg
  3. C.Arg < Lys < Gly < Asp
  4. D.Asp < Gly < Arg < Lys

Correct answer: B

Question 32

Chemistry · 4 marks · −1

Arrange the following amines in the decreasing order of basicity: I = pyridine, II = pyrrole, III = piperidine (see figure).

Figure for question 32
  1. A.III > II > I
  2. B.III > I > II
  3. C.I > III > II
  4. D.I > II > III

Correct answer: B

Question 33

Chemistry · 4 marks · −1

The major product of following reaction is: R−C≡N→(2) H2O(1) AlH(i-Bu)2\text{R}-\text{C}\equiv\text{N} \xrightarrow[\text{(2) H}_2\text{O}]{\text{(1) AlH(i-Bu)}_2} ?

  1. A.RCH2NH2\text{RCH}_2\text{NH}_2
  2. B.RCONH2\text{RCONH}_2
  3. C.RCOOH\text{RCOOH}
  4. D.RCHO\text{RCHO}

Correct answer: D

Question 34

Chemistry · 4 marks · −1

The correct decreasing order for acid strength is:

  1. A.NO2CH2COOH>NCCH2COOH>FCH2COOH>ClCH2COOH\text{NO}_2\text{CH}_2\text{COOH} > \text{NCCH}_2\text{COOH} > \text{FCH}_2\text{COOH} > \text{ClCH}_2\text{COOH}
  2. B.CNCH2COOH>O2NCH2COOH>FCH2COOH>ClCH2COOH\text{CNCH}_2\text{COOH} > \text{O}_2\text{NCH}_2\text{COOH} > \text{FCH}_2\text{COOH} > \text{ClCH}_2\text{COOH}
  3. C.NO2CH2COOH>FCH2COOH>CNCH2COOH>ClCH2COOH\text{NO}_2\text{CH}_2\text{COOH} > \text{FCH}_2\text{COOH} > \text{CNCH}_2\text{COOH} > \text{ClCH}_2\text{COOH}
  4. D.FCH2COOH>NCCH2COOH>NO2CH2COOH>ClCH2COOH\text{FCH}_2\text{COOH} > \text{NCCH}_2\text{COOH} > \text{NO}_2\text{CH}_2\text{COOH} > \text{ClCH}_2\text{COOH}

Correct answer: A

Question 35

Chemistry · 4 marks · −1

The compounds A and B in the following reaction are, respectively: Benzene →HCHO + HCl\xrightarrow{\text{HCHO + HCl}} A →AgCN\xrightarrow{\text{AgCN}} B

  1. A.A = Benzyl alcohol, B = Benzyl isocyanide
  2. B.A = Benzyl chloride, B = Benzyl isocyanide
  3. C.A = Benzyl chloride, B = Benzyl cyanide
  4. D.A = Benzyl alcohol, B = Benzyl cyanide

Correct answer: B

Question 36

Chemistry · 4 marks · −1

The major product of the following reaction is: 1-bromo-3-(3-bromopropyl)benzene (an aryl Br and a −CH2CH2CH2Br-\text{CH}_2\text{CH}_2\text{CH}_2\text{Br} chain meta to each other) →(1) KOH (aqueous); (2) CrO3/H+; (3) H2SO4/Δ\xrightarrow{\text{(1) KOH (aqueous); (2) CrO}_3\text{/H}^+\text{; (3) H}_2\text{SO}_4/\Delta} ?

Figure for question 36
  1. A.Bromo-1-indanone with the Br on the benzene ring para to the ring-fusion carbon bearing the CH2\text{CH}_2 (6-bromo-1-indanone as drawn: Br remote from the C=O)
  2. B.Bromo-1-indanone with the Br on the benzene ring ortho to the CH2\text{CH}_2 side, adjacent to the C=O region as drawn (Br next to ring fusion)
  3. C.Hydroxy-1-indanone: same skeleton as option 1 with OH in place of Br
  4. D.Hydroxy-1-indanone: same skeleton as option 2 with OH in place of Br

Correct answer: A

Explanation: Aqueous KOH hydrolyses only the alkyl C-Br to an alcohol (aryl C-Br survives); CrO3/H+ oxidises it to the propanoic acid; hot H2SO4 effects intramolecular Friedel-Crafts acylation to a bromo-indanone (NTA key: option 1).

Question 37

Chemistry · 4 marks · −1

Which amongst the following is the strongest acid?

  1. A.CHCl3\text{CHCl}_3
  2. B.CHBr3\text{CHBr}_3
  3. C.CHI3\text{CHI}_3
  4. D.CH(CN)3\text{CH(CN)}_3

Correct answer: D

Question 38

Chemistry · 4 marks · −1

The correct match between Item-I (drug) and Item-II (test) is: Item-I: (A) Chloroxylenol, (B) Norethindrone, (C) Sulphapyridine, (D) Penicillin. Item-II: (P) Carbylamine test, (Q) Sodium hydrogen carbonate test, (R) Ferric chloride test, (S) Bayer's test.

  1. A.A→R; B→P; C→S; D→Q
  2. B.A→Q; B→P; C→S; D→R
  3. C.A→Q; B→S; C→P; D→R
  4. D.A→R; B→S; C→P; D→Q

Correct answer: D

Question 39

Chemistry · 4 marks · −1

The major product of the following reaction is: 1,2-dihydronaphthalene →(i) Br2; (ii) EtOH\xrightarrow{\text{(i) Br}_2\text{; (ii) EtOH}} ?

Figure for question 39
  1. A.1-ethoxy-2-bromo-1,2,3,4-tetrahydronaphthalene (OEt on the benzylic carbon, Br on the adjacent carbon)
  2. B.1-bromo-2-ethoxy-1,2,3,4-tetrahydronaphthalene (Br on the benzylic carbon, OEt on the adjacent carbon)
  3. C.1,2-diethoxy-1,2,3,4-tetrahydronaphthalene
  4. D.1-ethoxy-1,4-dihydronaphthalene (OEt on the benzylic carbon, double bond retained in the ring)

Correct answer: A

Question 40

Chemistry · 4 marks · −1

In general, the properties that decrease and increase down a group in the periodic table, respectively, are:

  1. A.electronegativity and atomic radius.
  2. B.electronegativity and electron gain enthalpy.
  3. C.atomic radius and electronegativity.
  4. D.electron gain enthalpy and electronegativity.

Correct answer: A

Question 41

Chemistry · 4 marks · −1

The ore that contains both iron and copper is:

  1. A.malachite
  2. B.azurite
  3. C.dolomite
  4. D.copper pyrites

Correct answer: D

Question 42

Chemistry · 4 marks · −1

The isotopes of hydrogen are:

  1. A.Protium and deuterium only
  2. B.Tritium and protium only
  3. C.Protium, deuterium and tritium
  4. D.Deuterium and tritium only

Correct answer: C

Question 43

Chemistry · 4 marks · −1

The alkaline earth metal nitrate that does not crystallise with water molecules, is:

  1. A.Mg(NO3)2\text{Mg(NO}_3)_2
  2. B.Ca(NO3)2\text{Ca(NO}_3)_2
  3. C.Sr(NO3)2\text{Sr(NO}_3)_2
  4. D.Ba(NO3)2\text{Ba(NO}_3)_2

Correct answer: D

Question 44

Chemistry · 4 marks · −1

The one that is extensively used as a piezoelectric material is:

  1. A.quartz
  2. B.tridymite
  3. C.mica
  4. D.amorphous silica

Correct answer: A

Question 45

Chemistry · 4 marks · −1

Aluminium is usually found in +3 oxidation state. In contrast, thallium exists in +1 and +3 oxidation states. This is due to:

  1. A.lanthanoid contraction
  2. B.diagonal relationship
  3. C.lattice effect
  4. D.inert pair effect

Correct answer: D

Question 46

Chemistry · 4 marks · −1

Correct statements among a to d regarding silicones are: (a) They are polymers with hydrophobic character. (b) They are biocompatible. (c) In general, they have high thermal stability and low dielectric strength. (d) Usually, they are resistant to oxidation and used as greases.

  1. A.(a), (b) and (c) only
  2. B.(a), (b), (c) and (d)
  3. C.(a) and (b) only
  4. D.(a), (b) and (d) only

Correct answer: D

Question 47

Chemistry · 4 marks · −1

The highest value of the calculated spin-only magnetic moment (in BM) among all the transition metal complexes is:

  1. A.5.92
  2. B.4.90
  3. C.6.93
  4. D.3.87

Correct answer: A

Question 48

Chemistry · 4 marks · −1

Two complexes [Cr(H2O)6]Cl3[\text{Cr(H}_2\text{O)}_6]\text{Cl}_3 (A) and [Cr(NH3)6]Cl3[\text{Cr(NH}_3)_6]\text{Cl}_3 (B) are violet and yellow coloured, respectively. The incorrect statement regarding them is:

  1. A.both are paramagnetic with three unpaired electrons.
  2. B.Δ0\Delta_0 value for (A) is less than that of (B).
  3. C.both absorb energies corresponding to their complementary colors.
  4. D.Δ0\Delta_0 values of (A) and (B) are calculated from the energies of violet and yellow light, respectively.

Correct answer: D

Question 49

Chemistry · 4 marks · −1

A water sample has ppm level concentration of the following metals: Fe = 0.2; Mn = 5.0; Cu = 3.0; Zn = 5.0. The metal that makes the water sample unsuitable for drinking is:

  1. A.Fe
  2. B.Mn
  3. C.Cu
  4. D.Zn

Correct answer: B

Question 50

Chemistry · 4 marks · −1

A solution of sodium sulfate contains 92 g of Na+^+ ions per kilogram of water. The molality of Na+^+ ions in that solution in mol kg−1^{-1} is:

  1. A.4
  2. B.8
  3. C.12
  4. D.16

Correct answer: A

Question 51

Chemistry · 4 marks · −1

According to molecular orbital theory, which of the following is true with respect to Li2+_2^+ and Li2−_2^-?

  1. A.Both are unstable
  2. B.Li2+_2^+ is stable and Li2−_2^- is unstable
  3. C.Li2+_2^+ is unstable and Li2−_2^- is stable
  4. D.Both are stable

Correct answer: D

Question 52

Chemistry · 4 marks · −1

Consider the reversible isothermal expansion of an ideal gas in a closed system at two different temperatures T1T_1 and T2T_2 (T1<T2)(T_1 < T_2). The correct graphical depiction of the dependence of work done (w) on the final volume (V) is:

Figure for question 52
  1. A.Plot of |w| vs ln V: two straight lines starting from the same point on the |w| axis above the origin, the T2_2 line steeper than the T1_1 line
  2. B.Plot of |w| vs ln V: two straight lines starting from the origin O, the T2_2 line steeper than the T1_1 line
  3. C.Plot of |w| vs ln V: two straight lines crossing each other above the ln V axis (both with positive |w|-intercepts), the T2_2 line steeper
  4. D.Plot of |w| vs ln V: two straight lines meeting on the ln V axis (at |w| = 0, to the right of the origin), the T2_2 line steeper than the T1_1 line

Correct answer: D

Question 53

Chemistry · 4 marks · −1

Which one of the following statements regarding Henry's law is not correct?

  1. A.The partial pressure of the gas in vapour phase is proportional to the mole fraction of the gas in the solution.
  2. B.Different gases have different KHK_H (Henry's law constant) values at the same temperature.
  3. C.Higher the value of KHK_H at a given pressure, higher is the solubility of the gas in the liquids.
  4. D.The value of KHK_H increases with increase of temperature and KHK_H is function of the nature of the gas

Correct answer: C

Question 54

Chemistry · 4 marks · −1

20 mL of 0.1 M H2SO4\text{H}_2\text{SO}_4 solution is added to 30 mL of 0.2 M NH4OH\text{NH}_4\text{OH} solution. The pH of the resultant mixture is: [pKbK_b of NH4OH\text{NH}_4\text{OH} = 4.7].

  1. A.5.0
  2. B.5.2
  3. C.9.0
  4. D.9.4

Correct answer: C

Question 55

Chemistry · 4 marks · −1

The anodic half-cell of lead-acid battery is recharged using electricity of 0.05 Faraday. The amount of PbSO4\text{PbSO}_4 electrolyzed in g during the process is: (Molar mass of PbSO4\text{PbSO}_4 = 303 g mol−1^{-1})

  1. A.15.2
  2. B.7.6
  3. C.22.8
  4. D.11.4

Correct answer: B

Question 56

Chemistry · 4 marks · −1

The following results were obtained during kinetic studies of the reaction; 2A+B→Products2\text{A} + \text{B} \rightarrow \text{Products}\n\n| Experiment | [A] (in mol L−1^{-1}) | [B] (in mol L−1^{-1}) | Initial Rate of reaction (in mol L−1^{-1} min−1^{-1}) |\n|---|---|---|---|\n| I | 0.10 | 0.20 | 6.93×10−36.93 \times 10^{-3} |\n| II | 0.10 | 0.25 | 6.93×10−36.93 \times 10^{-3} |\n| III | 0.20 | 0.30 | 1.386×10−21.386 \times 10^{-2} |\n\nThe time (in minutes) required to consume half of A is:

  1. A.1
  2. B.5
  3. C.100
  4. D.10

Correct answer: B

Explanation: Rate is independent of [B] and first order in A, so rate =k[A]= k[A] with k=6.93×10−2k = 6.93\times10^{-2} min−1^{-1}. Since rate =−12d[A]dt= -\frac{1}{2}\frac{d[A]}{dt}, A is consumed with rate constant 2k2k: t1/2=0.6932k=5t_{1/2} = \frac{0.693}{2k} = 5 min.

Question 57

Chemistry · 4 marks · −1

Adsorption of a gas follows Freundlich adsorption isotherm. In the given plot, xx is the mass of the gas adsorbed on mass m of the adsorbent at pressure p. xm\frac{x}{m} is proportional to:

Figure for question 57
  1. A.p1/2p^{1/2}
  2. B.p2p^2
  3. C.pp
  4. D.p1/4p^{1/4}

Correct answer: A

Question 58

Mathematics · 4 marks · −1

For x∈R−{0,1}x \in \mathbb{R} - \{0, 1\}, let f1(x)=1xf_1(x) = \frac{1}{x}, f2(x)=1−xf_2(x) = 1 - x and f3(x)=11−xf_3(x) = \frac{1}{1-x} be three given functions. If a function, J(x)J(x) satisfies (f2∘J∘f1)(x)=f3(x)(f_2 \circ J \circ f_1)(x) = f_3(x) then J(x)J(x) is equal to:

  1. A.f1(x)f_1(x)
  2. B.f2(x)f_2(x)
  3. C.f3(x)f_3(x)
  4. D.1xf3(x)\frac{1}{x} f_3(x)

Correct answer: C

Question 59

Mathematics · 4 marks · −1

Let A={θ∈(−π2,π):3+2isin⁡θ1−2isin⁡θ is purely imaginary}A = \left\{\theta \in \left(-\frac{\pi}{2}, \pi\right) : \frac{3 + 2i\sin\theta}{1 - 2i\sin\theta} \text{ is purely imaginary}\right\}. Then the sum of the elements in A is:

  1. A.π\pi
  2. B.2π3\frac{2\pi}{3}
  3. C.3π4\frac{3\pi}{4}
  4. D.5π6\frac{5\pi}{6}

Correct answer: B

Question 60

Mathematics · 4 marks · −1

Let α\alpha and β\beta be two roots of the equation x2+2x+2=0x^2 + 2x + 2 = 0, then α15+β15\alpha^{15} + \beta^{15} is equal to:

  1. A.256
  2. B.−256
  3. C.512
  4. D.−512

Correct answer: B

Question 61

Mathematics · 4 marks · −1

If A=[cos⁡θ−sin⁡θsin⁡θcos⁡θ]A = \begin{bmatrix} \cos\theta & -\sin\theta \\ \sin\theta & \cos\theta \end{bmatrix}, then the matrix A−50A^{-50} when θ=π12\theta = \frac{\pi}{12}, is equal to:

  1. A.[3212−1232]\begin{bmatrix} \frac{\sqrt{3}}{2} & \frac{1}{2} \\ -\frac{1}{2} & \frac{\sqrt{3}}{2} \end{bmatrix}
  2. B.[32−121232]\begin{bmatrix} \frac{\sqrt{3}}{2} & -\frac{1}{2} \\ \frac{1}{2} & \frac{\sqrt{3}}{2} \end{bmatrix}
  3. C.[1232−3212]\begin{bmatrix} \frac{1}{2} & \frac{\sqrt{3}}{2} \\ -\frac{\sqrt{3}}{2} & \frac{1}{2} \end{bmatrix}
  4. D.[12−323212]\begin{bmatrix} \frac{1}{2} & -\frac{\sqrt{3}}{2} \\ \frac{\sqrt{3}}{2} & \frac{1}{2} \end{bmatrix}

Correct answer: A

Question 62

Mathematics · 4 marks · −1

The system of linear equations x+y+z=2x + y + z = 2, 2x+3y+2z=52x + 3y + 2z = 5, 2x+3y+(a2−1)z=a+12x + 3y + (a^2 - 1)z = a + 1

  1. A.is inconsistent when ∣a∣=3|a| = \sqrt{3}
  2. B.has infinitely many solutions for a=4a = 4
  3. C.is inconsistent when a=4a = 4
  4. D.has a unique solution for ∣a∣=3|a| = \sqrt{3}

Correct answer: A

Question 63

Mathematics · 4 marks · −1

Consider a class of 5 girls and 7 boys. The number of different teams consisting of 2 girls and 3 boys that can be formed from this class, if there are two specific boys A and B, who refuse to be the members of the same team, is:

  1. A.200
  2. B.300
  3. C.350
  4. D.500

Correct answer: B

Question 64

Mathematics · 4 marks · −1

If the fractional part of the number 240315\frac{2^{403}}{15} is k15\frac{k}{15}, then k is equal to:

  1. A.4
  2. B.8
  3. C.14
  4. D.6

Correct answer: B

Question 65

Mathematics · 4 marks · −1

Let a1,a2,…,a30a_1, a_2, \ldots, a_{30} be an A.P., S=∑i=130aiS = \sum_{i=1}^{30} a_i and T=∑i=115a(2i−1)T = \sum_{i=1}^{15} a_{(2i-1)}. If a5=27a_5 = 27 and S−2T=75S - 2T = 75, then a10a_{10} is equal to:

  1. A.42
  2. B.47
  3. C.57
  4. D.52

Correct answer: D

Question 66

Mathematics · 4 marks · −1

If a, b and c be three distinct real numbers in G.P. and a+b+c=xba + b + c = xb, then xx cannot be:

  1. A.−2
  2. B.−3
  3. C.2
  4. D.4

Correct answer: C

Question 67

Mathematics · 4 marks · −1

lim⁡y→01+1+y4−2y4\lim_{y \to 0} \frac{\sqrt{1 + \sqrt{1 + y^4}} - \sqrt{2}}{y^4}

  1. A.does not exist
  2. B.exists and equals 122\frac{1}{2\sqrt{2}}
  3. C.exists and equals 142\frac{1}{4\sqrt{2}}
  4. D.exists and equals 122(2+1)\frac{1}{2\sqrt{2}(\sqrt{2}+1)}

Correct answer: C

Question 68

Mathematics · 4 marks · −1

Let f:R→Rf: \mathbb{R} \rightarrow \mathbb{R} be a function defined as f(x)={5,if x≤1a+bx,if 1<x<3b+5x,if 3≤x<530,if x≥5f(x) = \begin{cases} 5, & \text{if } x \le 1 \\ a + bx, & \text{if } 1 < x < 3 \\ b + 5x, & \text{if } 3 \le x < 5 \\ 30, & \text{if } x \ge 5 \end{cases}. Then, ff is:

  1. A.continuous if a=−5a = -5 and b=10b = 10
  2. B.continuous if a=5a = 5 and b=5b = 5
  3. C.continuous if a=0a = 0 and b=5b = 5
  4. D.not continuous for any values of a and b

Correct answer: D

Question 69

Mathematics · 4 marks · −1

If θ\theta denotes the acute angle between the curves, y=10−x2y = 10 - x^2 and y=2+x2y = 2 + x^2 at a point of their intersection, then ∣tan⁡θ∣|\tan\theta| is equal to:

  1. A.817\frac{8}{17}
  2. B.815\frac{8}{15}
  3. C.49\frac{4}{9}
  4. D.717\frac{7}{17}

Correct answer: B

Question 70

Mathematics · 4 marks · −1

The maximum volume (in cu.m) of the right circular cone having slant height 3 m is:

  1. A.6π6\pi
  2. B.33π3\sqrt{3}\pi
  3. C.23π2\sqrt{3}\pi
  4. D.43π\frac{4}{3}\pi

Correct answer: C

Question 71

Mathematics · 4 marks · −1

For x2≠nπ+1x^2 \ne n\pi + 1, n∈Nn \in \mathbb{N} (the set of natural numbers), the integral ∫x2sin⁡(x2−1)−sin⁡2(x2−1)2sin⁡(x2−1)+sin⁡2(x2−1) dx\int x\sqrt{\frac{2\sin(x^2-1) - \sin 2(x^2-1)}{2\sin(x^2-1) + \sin 2(x^2-1)}}\,dx is equal to: (where c is a constant of integration)

  1. A.12log⁡e∣sec⁡(x2−1)∣+c\frac{1}{2}\log_e|\sec(x^2-1)| + c
  2. B.log⁡e∣sec⁡(x2−12)∣+c\log_e\left|\sec\left(\frac{x^2-1}{2}\right)\right| + c
  3. C.log⁡e∣12sec⁡2(x2−1)∣+c\log_e\left|\frac{1}{2}\sec^2(x^2-1)\right| + c
  4. D.12log⁡e∣sec⁡2(x2−12)∣+c\frac{1}{2}\log_e\left|\sec^2\left(\frac{x^2-1}{2}\right)\right| + c

Correct answer: B

Question 72

Mathematics · 4 marks · −1

The value of ∫0π∣cos⁡x∣3 dx\int_0^{\pi} |\cos x|^3\,dx is:

  1. A.0
  2. B.23\frac{2}{3}
  3. C.43\frac{4}{3}
  4. D.−43-\frac{4}{3}

Correct answer: C

Question 73

Mathematics · 4 marks · −1

The area (in sq. units) bounded by the parabola y=x2−1y = x^2 - 1, the tangent at the point (2, 3) to it and the yy-axis is:

  1. A.83\frac{8}{3}
  2. B.143\frac{14}{3}
  3. C.563\frac{56}{3}
  4. D.323\frac{32}{3}

Correct answer: A

Question 74

Mathematics · 4 marks · −1

If y=y(x)y = y(x) is the solution of the differential equation, xdydx+2y=x2x\frac{dy}{dx} + 2y = x^2 satisfying y(1)=1y(1) = 1, then y(12)y\left(\frac{1}{2}\right) is equal to:

  1. A.14\frac{1}{4}
  2. B.764\frac{7}{64}
  3. C.1316\frac{13}{16}
  4. D.4916\frac{49}{16}

Correct answer: D

Question 75

Mathematics · 4 marks · −1

Consider the set of all lines px+qy+r=0px + qy + r = 0 such that 3p+2q+4r=03p + 2q + 4r = 0. Which one of the following statements is true?

  1. A.The lines are all parallel.
  2. B.The lines are concurrent at the point (34,12)\left(\frac{3}{4}, \frac{1}{2}\right).
  3. C.The lines are not concurrent.
  4. D.Each line passes through the origin.

Correct answer: B

Question 76

Mathematics · 4 marks · −1

Equation of a common tangent to the circle, x2+y2−6x=0x^2 + y^2 - 6x = 0 and the parabola, y2=4xy^2 = 4x, is:

  1. A.23y=−x−122\sqrt{3}y = -x - 12
  2. B.23y=12x+12\sqrt{3}y = 12x + 1
  3. C.3y=3x+1\sqrt{3}y = 3x + 1
  4. D.3y=x+3\sqrt{3}y = x + 3

Correct answer: D

Question 77

Mathematics · 4 marks · −1

Three circles of radii a, b, c (a < b < c) touch each other externally. If they have xx-axis as a common tangent, then:

  1. A.a, b, c are in A.P.
  2. B.a,b,c\sqrt{a}, \sqrt{b}, \sqrt{c} are in A.P.
  3. C.1a=1b+1c\frac{1}{\sqrt{a}} = \frac{1}{\sqrt{b}} + \frac{1}{\sqrt{c}}
  4. D.1b=1a+1c\frac{1}{\sqrt{b}} = \frac{1}{\sqrt{a}} + \frac{1}{\sqrt{c}}

Correct answer: C

Question 78

Mathematics · 4 marks · −1

Axis of a parabola lies along xx-axis. If its vertex and focus are at distances 2 and 4 respectively from the origin, on the positive xx-axis then which of the following points does not lie on it?

  1. A.(4,−4)(4, -4)
  2. B.(6,42)(6, 4\sqrt{2})
  3. C.(5,26)(5, 2\sqrt{6})
  4. D.(8,6)(8, 6)

Correct answer: D

Question 79

Mathematics · 4 marks · −1

Let 0<θ<π20 < \theta < \frac{\pi}{2}. If the eccentricity of the hyperbola x2cos⁡2θ−y2sin⁡2θ=1\frac{x^2}{\cos^2\theta} - \frac{y^2}{\sin^2\theta} = 1 is greater than 2, then the length of its latus rectum lies in the interval:

  1. A.(1,3/2](1, 3/2]
  2. B.(3/2,2](3/2, 2]
  3. C.(2,3](2, 3]
  4. D.(3,∞)(3, \infty)

Correct answer: D

Question 80

Mathematics · 4 marks · −1

The plane through the intersection of the planes x+y+z=1x + y + z = 1 and 2x+3y−z+4=02x + 3y - z + 4 = 0 and parallel to yy-axis also passes through the point:

  1. A.(−3,0,−1)(-3, 0, -1)
  2. B.(−3,1,1)(-3, 1, 1)
  3. C.(3,2,1)(3, 2, 1)
  4. D.(3,3,−1)(3, 3, -1)

Correct answer: C

Question 81

Mathematics · 4 marks · −1

The equation of the line passing through (−4,3,1)(-4, 3, 1), parallel to the plane x+2y−z−5=0x + 2y - z - 5 = 0 and intersecting the line x+1−3=y−32=z−2−1\frac{x+1}{-3} = \frac{y-3}{2} = \frac{z-2}{-1} is:

  1. A.x+4−1=y−31=z−11\frac{x+4}{-1} = \frac{y-3}{1} = \frac{z-1}{1}
  2. B.x+41=y−31=z−13\frac{x+4}{1} = \frac{y-3}{1} = \frac{z-1}{3}
  3. C.x+43=y−3−1=z−11\frac{x+4}{3} = \frac{y-3}{-1} = \frac{z-1}{1}
  4. D.x−42=y+31=z+14\frac{x-4}{2} = \frac{y+3}{1} = \frac{z+1}{4}

Correct answer: C

Question 82

Mathematics · 4 marks · −1

Let a⃗=i^−j^\vec{a} = \hat{i} - \hat{j}, b⃗=i^+j^+k^\vec{b} = \hat{i} + \hat{j} + \hat{k} and c⃗\vec{c} be a vector such that a⃗×c⃗+b⃗=0⃗\vec{a} \times \vec{c} + \vec{b} = \vec{0} and a⃗⋅c⃗=4\vec{a} \cdot \vec{c} = 4, then ∣c⃗∣2|\vec{c}|^2 is equal to:

  1. A.192\frac{19}{2}
  2. B.172\frac{17}{2}
  3. C.9
  4. D.8

Correct answer: A

Question 83

Mathematics · 4 marks · −1

5 students of a class have an average height 150 cm and variance 18 cm2^2. A new student, whose height is 156 cm, joined them. The variance (in cm2^2) of the height of these six students is:

  1. A.20
  2. B.16
  3. C.18
  4. D.22

Correct answer: A

Question 84

Mathematics · 4 marks · −1

Two cards are drawn successively with replacement from a well-shuffled deck of 52 cards. Let X denote the random variable of number of aces obtained in the two drawn cards. Then P(X=1)+P(X=2)P(X = 1) + P(X = 2) equals:

  1. A.24/169
  2. B.25/169
  3. C.49/169
  4. D.52/169

Correct answer: B

Question 85

Mathematics · 4 marks · −1

For any θ∈(π4,π2)\theta \in \left(\frac{\pi}{4}, \frac{\pi}{2}\right), the expression 3(sin⁡θ−cos⁡θ)4+6(sin⁡θ+cos⁡θ)2+4sin⁡6θ3(\sin\theta - \cos\theta)^4 + 6(\sin\theta + \cos\theta)^2 + 4\sin^6\theta equals:

  1. A.13−4cos⁡2θ+6sin⁡2θcos⁡2θ13 - 4\cos^2\theta + 6\sin^2\theta\cos^2\theta
  2. B.13−4cos⁡2θ+6cos⁡4θ13 - 4\cos^2\theta + 6\cos^4\theta
  3. C.13−4cos⁡4θ+2sin⁡2θcos⁡2θ13 - 4\cos^4\theta + 2\sin^2\theta\cos^2\theta
  4. D.13−4cos⁡6θ13 - 4\cos^6\theta

Correct answer: D

Question 86

Mathematics · 4 marks · −1

If cos⁡−1(23x)+cos⁡−1(34x)=π2\cos^{-1}\left(\frac{2}{3x}\right) + \cos^{-1}\left(\frac{3}{4x}\right) = \frac{\pi}{2} (x>34)\left(x > \frac{3}{4}\right), then xx is equal to:

  1. A.14512\frac{\sqrt{145}}{12}
  2. B.14612\frac{\sqrt{146}}{12}
  3. C.14511\frac{\sqrt{145}}{11}
  4. D.14510\frac{\sqrt{145}}{10}

Correct answer: A

Question 87

Mathematics · 4 marks · −1

If the Boolean expression (p⊕q)∧(∼p⊙q)(p \oplus q) \wedge (\sim p \odot q) is equivalent to p∧qp \wedge q, where ⊕,⊙∈{∧,∨}\oplus, \odot \in \{\wedge, \vee\}, then the ordered pair (⊕,⊙)(\oplus, \odot) is:

  1. A.(∧,∧)(\wedge, \wedge)
  2. B.(∧,∨)(\wedge, \vee)
  3. C.(∨,∨)(\vee, \vee)
  4. D.(∨,∧)(\vee, \wedge)

Correct answer: B

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